Effective synergy of supply and demand in regional industrial technologies is an important driver to accelerate the transformation of technological achievements, improve the level of regional science and technology innovation, optimize the allocation of regional industrial science and technology resources. This paper set up the sequential parameter indicator system of supply and demand of the high technology industrial technologies, studied the supply and demand synergy level of the high technology industrial technologies in Beijing-Tianjin-Hebei based on distance collaborative model and entropy theory. Through empirical study of the relevant data from 2005 to 2014, the results showed that the synergy level of supply and demand of the high technology industrial technologies in Beijing-Tianjin-Hebei roseSwithSfluctuations and transited from weak synergy to basic synergy. The regional coordinated development strategy has played an important role in promoting the synergy level of technology supply and demand. Due to the heterogeneity of technology resources in every region, the synergy level of technology supply elements with demand and technology demand elements with supply are different, and the synergy of patent technology and demand is facing great challenge. Based on these, this paper proposes suggestions to promote the synergy development of technology supply and demand in the aspect of promoting to establish the system of technology demand-driven technology trading market, improving effective technology assessment, screening and supply, completing the docking mechanism of regional technology supply and demand, and promoting the construction of technology intermediary service system.