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催化极谱法测定水中Cu~(2+)
引用本文:贾雨.催化极谱法测定水中Cu~(2+)[J].惠州学院学报,1995(4).
作者姓名:贾雨
摘    要:在HCl-H3PO4介质中,铜与硫氰酸钾形成络合物吸附在滴汞电机上,在0.55V(VS.SCE)产生灵敏的络合物吸附催化波。铜在0.05~1.00mg·L-1范围内,其二阶导数峰高IPCu与浓度成正比。本方法可测定井水、矿泉水、自来水中微量Cu~(2+)。

关 键 词:示波极谱    测定

Determiination of Copper in Water by Oscillopolarograph
Jia Yu.Determiination of Copper in Water by Oscillopolarograph[J].Journal of Huizhou University,1995(4).
Authors:Jia Yu
Affiliation:Dept. of Chemistry
Abstract:In the medium of HCl-H3PO4, complex compound of copper and potassium thiocyamate is formed being adsorbed at mercury electrode producing the acumivous complex adsorbed catalytic wave at- 0. 55 V. The second order derivative peak height is proportional to the concentration in the range of 0. 55~1.00 mg. L-1 for Cu2+ . This method can be used for the determination of Cu2+ in well water, mineral water and drinking water.
Keywords:oscillopolarograph  copper  determination
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