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1.
用折光率法测定了45℃、52℃、60℃三种温度下,对苯二酚在乙醇、正丁醇、正戊醇、异丙醚中浓度与折光率的关系以及饱和溶解度。首先进行了实验方法可靠性的验证,试验表明回收率在94.5%-102.4%之间,因而方法的可信度较高。最大溶解度平衡时间的测量表明:对于不饱和体系,振荡2小时,静置0.5小时,误差已小于0.1%;对于饱和溶解度,则必须振荡6-9小时,才能达到最大溶解度,这时误差小于0.02%。工作曲线表明,在这些溶剂中,对苯二酚的溶解度可大到接近23%,其折光率与浓度关系是一条较好的直线。与同一溶剂的苯酚工作曲线相比,相同浓度时对苯二酚的折射率较大,但相差不是很大,因而用平均工作曲线可以测量混合酚类的浓度,误差不大于2%。对于在线估计混合酚类的浓度,这是一个快速而有意义的方法。如果利用气相色谱估计得到对苯二酚与苯酚的比例,则利用内插工作曲线,用本方法测定的混合酚类的浓度误差可小到0.1%。对苯二酚在几种溶剂中的饱和溶解度是有用的热力学数据,尚未见过何处公开发表。  相似文献   

2.
在50℃、46℃和常压下实验测定了对苯二酚在二异丙基醚和苯酚中的饱和溶解度。把它与水-二异丙醚-苯酚-对苯二酚四元系中的对苯二酚浓度作比较,其最大溶解度既小于醚相也小于水相中对苯二酚的最大浓度,这一结果可能意味着水有增溶作用。  相似文献   

3.
用气相色谱法实验测定了水—异丙醚—苯酚的三元系在46℃的等温截面相图。柯图上呈现两个两相共存区域和一个单相区域。在46℃水和异丙醚存在两相,当逐渐溶入苯酚后,水富端很小,而醚相中异丙醚摩尔分数逐渐减小到25.4%,苯酚逐渐增加到29.0%,这表明在醚相中苯酚可达到较大溶解度。在46℃水和苯酚也存在两相,在三元系中异丙醚在水相和苯酚相中的溶解度都不大。该相图为工业上萃取提供了一定的基础工作。  相似文献   

4.
1苯酚的溶解度大小问题人教社《化学》教材上说苯酚“在水中的溶解度不大,当温度高于℃时,则能与水混溶。”这句话让许多人误认为苯酚在常温时在水中的溶解度很小微溶或难溶,由此导致《化学》教材和有关资料上的相关题目的参考答案的错误。据《化学用表》知,在℃时,苯酚的溶解度为,属可溶物质,温度稍高,则变成了易溶物质。也就是说,教材中的苯酚“在水中的溶解度不大”并不是说苯酚的溶解度很小,而是相对于“温度高于℃时,则能与水混溶”而言的。有关的洗涤问题“盛放过苯酚的试管可以用酒精进行清洗”,“苯酚有毒,浓溶液沾到皮肤上,应立即…  相似文献   

5.
人教社《化学》教材上说苯酚“在水中的溶解度不大,当温度高于65℃时,则能与水混溶。”这句话让许多人误认为苯酚在常温时在水中的溶解度很小(微溶或难溶),由此导致《化学》教材和有关资料上的相关题目的参考答案的错误。据《化学用表》知,在15℃时,苯酚的溶解度为8.2g,属可溶物质,温度稍高,则变成了易溶物质。也就是说,  相似文献   

6.
溶液的百分比浓度的计算,是初中化学计算的重点和难点,在有关的计算过程中,有的同学由于概念不清或基础知识不牢固,对于某些题目缺乏正确的分析和理解,以致步入“误区”。现例举几种同学们最易忽视的题型,以希望有所启示。一、忽视溶解度的影响例1 (94年辽宁竞赛题)20℃时食盐的溶解度为36克。20℃时将20克食盐放入50克水中,所得溶液的质量百分比浓度是()。(A)70%(B)40%(C)28.6%(D)26.5%解析题目已结出了20℃时食盐的溶解度,由此暗示了解题时必须注意所加20克食盐是否能完全溶解于50克水中。经计算,20℃时50…  相似文献   

7.
建立了水中苯酚、邻苯二酚、间苯二酚、对苯二酚的高效液相色谱-荧光分析方法。样品过0.45μm滤膜后直接进样,以甲醇-水(体积比30:70)为流动相经反相色谱柱分离后.采用荧光检测器检测。通过时间分组改变检测器的激发和发射波长,从而实现同时检测苯酚、邻苯二酚、间苯二酚、对苯二酚。外标法定量。空白样品及其添加实验结果表明.特征激发和发射波长基线稳定,无基质干扰,结合保留时间可实现准确的定性定量。苯酚、邻苯二酚、间苯二酚的方法检出限为5μg/L(S/N=3),对苯二酚的方法检出限为10μg/L(S/N=3)。空白样本添加水平在10-50μg/L时,平均回收率为83.5%-93.6%,相对偏差(n=6)为4.3%~7.3%。  相似文献   

8.
一、关于苯酚在水中的溶解性1.苯酚在水中的溶解性表述不一文献名对苯酚的溶解性表述《高中化学》第二册常温下苯酚在水中的溶解性不大。顾翼东主编《化学词典》491页( 1989年版) 在室温下稍溶于水。王箴编《化工辞典》3 6页( 2 0 0 2年第四版) 室温时稍溶于水。B .N .库茨涅佐夫著《化学试剂与制剂》手册64 9页在10 0g水中15℃时的溶解度为8.2 g。齐齐巴宾著《有机化学基本原理》2 84页在水中的溶解度达8%。曾昭琼主编《有机化学》上册2 94页苯酚微溶于水,2 5℃时溶解度为8g。《高中化学教学参考》甲种本第三册2 5 3页往水中加入少量苯酚,…  相似文献   

9.
溶质质量分数的计算,是初中化学计算的重点和难点。计算时要注意以下几类情况:一、受溶解度影响的情况例至已知40℃时物质A的溶解度是3O克。此温度下,将26克该物质投入65克水中,充分搅拌,所得溶液中溶质质量分数是()。(A)30%(B)50Wh(C)ll.sop(D)23.ide解析本题说明了40T时物质A的溶解度,由此暗示同学们在计算时,必须注意所加入的物质A26克是否完全溶于65克水中。经计算,40℃时65克水中最多能溶解物质A195克,因此,所得溶液中溶质质量分数应是:一X100%=23.1%。故选(D)。二、氧化物溶于水的情况例224.8克…  相似文献   

10.
一、填空题(每空2分,共38分)1.1%的碘酒中的溶剂是。三氧化硫溶于水后所得浴液中的溶质是。2.农田施肥需氮元素0.7吨,计算:施用尿素[CO(NH2)2]需要吨。3.60℃时,22克硝酸钾溶解在20克水中,形成饱和溶液,则60℃时硝酸钾的溶解度是克,该溶液百分比浓度为。4.在氧化铁里铁元素和氧元素的质量比是,铁元素的百分含量是。5.有密度为d克/厘米3,质量百分比浓度为a%的某溶液V毫升,其中溶质的质量(克)为。6.在一定温度时,食盐饱和溶液的体积是10毫升(密度为1.2克/厘米3),把它蒸干后,得食盐3.2克,这一温度下食盐…  相似文献   

11.
《海外英语》2007,(5):44-45
It is worthy of noting that, whilst Crookston Castle witnessed the earlier and happier portion of Mary's variegated life,  相似文献   

12.
《海外英语》2007,(4):36
There are numbers of crossroads on our long and unpredictable life journey where we totally have no idea about which direction to choose. No matter what our decision is, we should not turn back, but face the music and go ahead instead. I am this kind of girl who always does try without regretting, one example is how I dealt with my love.  相似文献   

13.
王菲 《华章》2007,(12):273-273
Migration occurs behind a variety of reasons and has a great effect on the whole world. People may migrate in order to improve their economic situation, or in order to escape civil strife, persecution, and environmental disasters. The impact of migration is complex, bringing both benefits anddisadvantages. This paper briefly talks about the causes of migration, the allocation of benefits, and the ways in which individual countries and the international community deal with this important subject.  相似文献   

14.
裴水妹 《华章》2007,(11):196
Sister Carrie is one of the most controversial characters in American literature.Thought as a "fallen woman" firstly,she was defined as a "new woman" by some critics later. However, by digging into the motivaton behind the whole process of Carrie's "success", the relationship between Carrie and her creator (the author), the social conditions of then American, it can be found that Carrie has never been free-standing on her thought and she has never found her real-sdf even after becoming a famous actress. In a society dominated by mass consumerism Carrie is only an adherent of her own desires. She also is a representative of all those country girls flooded into cities, a symbol and a sacrifice of the urbanization of America in a time countryside was overcome by cities.  相似文献   

15.
16.
1.IntroductionOne-cyclecontrolmethod,whichwasproposedaboutonedecadeago[1],hasbecomeanattractivemethodinspecialfieldssuchaspowerfactorcorrection[2-6],switchingamplifiers[7,8],etc.Themainideaofthiscontrollerisbasedonintegrationofdiodevoltageinone-cycleandforcesittobeexactlyequaltothereferencevalue.Themainadvantageofthiscontrollerisitsrealtimeabilitytorejectthevariationofinputvoltage[1].Despitethisgreatability,ithasnogoodperformancesinrejectingofloaddisturbanceandfollowingreferencecommands.Espec…  相似文献   

17.
Today, Sunday morning, I sit thinking and typing at my computer. My thoughts are in my homeland, India and my body is in China. The body is here and mind there for a good reason. Mr. Hu is president and I am resident and both are in each other's countries (what a difference the absence of one small letter makes!). Mr. Hu will return in a few days and I will stay on longer.  相似文献   

18.
STORIES     
正A One day a pig went to the stable(马棚)to see his good friend,an oldhorse,and was going to stay there forthenight.Night came and it was time forsleep.The pig went into the straw heap(稻草堆)and lay comfortably.A longtime passed,but the horse was stillstanding there and did not move.Thepig asked the horse why he did not go tosleep."Standing like this is the begin-ning ofsleeping,"answered the horse.  相似文献   

19.
正1.Any fool can count the seeds in an apple.Only God can count all the apples in one seed.2.Happy families are all alike;every unhappy family is unhappy in its own way.3.Memories are the key not to the past,but to the future.4.Sometimes in the dark you see what you want to see.5.There is a great difference between  相似文献   

20.
正Scope and Policy The Journal of Chongqing University-English Edition(JCQU-E)is a peerreviewed journal publishing research articles in multiple disciplines of science and technology,covering civil and environmental engineering,chemical engineering,biotechnology,mechanical and electrical engineering,computer and data processing,mining,metallurgy,materials science,and interdisciplines thereof.  相似文献   

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