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1.
A life-size whitish marble statue of a “Virgin with Child” has been recently rediscovered in the St. Rosario church located in Ottaviano, a small town near Naples (southern Italy). This artwork shows stylistic features of the Tuscan-Roman school of the 16th century, and is framed in an intriguing historical context. Historical documents testify that the sculpture was a property of the cadet branch of noble Tuscan family of the Medici, the Medici of Ottaviano. A multianalytical approach has been used to try to indicate the supply area of the white marble of the studied sculpture. Considering the whole mineralogical, petrographic and geochemical data, the source rock can be possibly limited to the main classical white marbles of the Mediterranean district, as the classical marble of Aphrodisias. A reuse practice of a former artwork can be also hypothesized.  相似文献   

2.
The “marble” Portasanta from Caldana (Grosseto, Italy) takes its name from the strict resemblance to the ancient Marmor Chium (also this called Portasanta) coming from the island of Chios in Greece. In this work, a complete characterization of the Italian Portasanta was made: chemical (X-ray fluorescence and isotopic analyses), mineralogical (X-ray diffraction on the bulk sample and on insoluble residue after acid attack), physical (water accessible porosity and imbibition coefficients), petrographical (optical microscopy) and mechanical (compressive strength test) analyses have been carried out in order to obtain a better distinction between Italian and Greek “marble”, sometimes mistaken. The Portasanta from Caldana (Italy) was quarried surely in the sixteenth century, but a possible use of this material during Roman time is still in doubt. The study of samples from some Tuscan archaeological sites (Torraccia di Chiusi, Siena and Roselle, Grosseto) allows us to confirm the use of Portasanta from Chios for the Torraccia site and that of Caldana for Roselle.  相似文献   

3.
57Fe Mössbauer spectroscopy permits an explanation of the formation of the iron-bearing species present in three types of coloured marbles, known as cipollino mandolato, rosso antico and fior di pesco. Structural Fe2+ and Fe3+ located in silicates, together with the remains of weakly ferromagnetic hematite, arise from primary sediments. Fe2+ located in carbonates and anti-ferromagnetic hematite are formed by redox processes during marble formation. The relative contents of the iron species in the three types of marbles depend on the composition of the primary sediments and on local conditions during metamorphism. Knowledge of the type and amount of the iron species in marbles may help in the reconstruction of the redox processes, which took place during marble formation. The deviations of the Morin transition of the hematites play the role of genetic indicator because purity, crystallinity and the red hues of hematites in marbles can be related to the environment of formation.  相似文献   

4.
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5.
The mosaics covering the floors of the rooms of the domus dei Coiedii at Suasa (Ancona, Italy) may be dated archaeologically and artistically between the late republican-Augustan age (end of the first century B.C.-beginning of first century A.D.) and the second century A.D.-first half of third century A.D. The floors were made mostly in opus tessellatum, only one in opus sectile. Tesserae used in opus tessellatum are made mainly of local stones, belonging to the so-called Umbro-Marchigiana Sedimentary Sequence: the white to pinkish and reddish tesserae consist prevalently of limestones belonging to the ‘Scaglia Rosata’ Formation (Late Turonian-Middle Eocene), and subordinately to the ‘Calcare Massiccio del Burano’, which is part of the ‘Calcare Massiccio s.l.’ Formation (Late Triassic-Early Lias). Most dark to black tesserae are composed of not fossiliferous marls and marly clays, which probably derive from the local ‘Marne a Fucoidi’ Formation; a number of them are made of very fine grained sandstones, which are found as pebbles in the alluvial sediments of the Cesano river close to Suasa, and, some, of aphyric leucite-bearing basanites from the potassic Quaternary magmatic province of central-southern Italy. Artificial glasses (red and green, rich in Pb and low in Sb; light blue, low in Pb and high in Sb), containing microliths of Pb-rich phase(s) and of wollastonite, were also used in some floors. The stones used in opus sectile are (1) sedimentary: nodular limestones belonging to the ‘Rosso Ammonitico’, which occurs in the Umbro-Marchigiana Sedimentary Succession; black marls and marly clays similar to those used in opus tessellatum; onyx marble; (2) magmatic: porphyrites (‘porfido verde antico’) and gabbros (ophite); (3) marbles: different kinds of coloured marbles, comprising ‘marmo cipollino’, ‘rosso antico’, ‘pavonazzetto’, ‘portasanta’, ‘giallo antico’, ‘bigio antico’, ‘brecce coralline’. White marbles from Marmara and Carrara were also employed.  相似文献   

6.
Adobe is a construction technique that uses raw clayey earth mixed and moulded to form blocks to realize a bearing wall. Romans were also used to add sand or coarse sand into the mixture to “degrease” clay and to allow to make it into a mixture. Fibres such as straw were often added into the mixture. Anyway, ancient home brick-makers have not had a chance to do scientific experimental investigation on the balance of ingredients and the optimisation of this production. This paper elaborates on how workability and mechanical properties of Roman ancient adobe earthen bricks change by varying the percentage of an on situ soil, straw and coarse sand into the mixture to produce them. The comparisons were also made with the only-earth samples. Breaking manners of all the samples were also compared.  相似文献   

7.
Roman funerary artefacts belonging to the archaeological collections in Modena and Reggio Emilia, two important Roman colonies (Mutina and Regium Lepidi, respectively) in the Cispadane region (Northern Italy), are made of trachytes from the Euganean Hills, close to Padua. In particular, the petrographic and chemical parameters, besides magnetic susceptibility of archaeological trachytes, suggest Monte Oliveto as their main source; very few of them, however, come from Monte Rosso and Monte Merlo. Surprisingly the trachytes from Monselice, which were used extensively to get flagstones for paving the Roman roads of the Po plain, were not implied in funerary art. Possibly the porosity of stones was determinant in addressing the use of the Euganean trachytes: the stones from Monte Oliveto (and also from Monte Rosso and Monte Merlo), which contain frequent cavities and voids, are porous and might favour body decomposition, like important stones used in antiquity for sarcophagi (e.g. lapis sarcophagus). By contrast, the trachytes from Monselice are dense, not porous, hence harder and more resistant to abrasion, therefore suitable for flagstones.  相似文献   

8.
This work faces the problem of detecting decay zones from color images of stone materials. In Cultural Heritage, the extraction of degradation regions from images of ancient monuments represents an important step forward in studying and analyzing the state of preservation of historical buildings. Generally the decay diagnosis is provided by “naked eye” analysis done by expert scientists “walking around” the artifact and recording the conservation state of each individual element they observe. In addition to this kind of investigation, the application of an image segmentation strategy to color images of stony materials can be used in order to extract regions characterized by a visible chromatic alteration, changes in color, for example, as oxidation or concretion. This paper features a color image segmentation approach founded on the fast marching numerical method. We have applied this technique for its possibility to work locally, that is, only the contour of the region under study is processed. In addition to this method, we present a global approach, that is, the possibility to extract decay regions from the entire image; these regions are spatially disconnected but with similar colorimeter value. The main aim of the present work is to provide a tool that helps the expert to contour the degraded regions. In this sense even if the results of the proposed procedure depend on the expert evaluation, the approach can be a contribution to improve the efficiency of the boundary detection process. The study case concerns the impressive remains of the Roman Theatre in the city of Aosta (Italy). In the image segmentation process the color space L*a*b* is utilized.  相似文献   

9.
Spectrophotometric and colorimetric data obtained during a measurement campaign aimed at supporting the Roman “Villa del Casale” (Piazza Armerina, Sicily, Italy) conservation activities, are presented. Special attention was paid to the possible variation of the chromatic coordinates, possibly due to the interventions of cleaning, consolidation, and protection. Data have been analyzed by the Principal Component Analysis (PCA) statistical technique, with the attempt to investigate its role in data variability reduction and verify its effectiveness in interpreting the phenomena occurring on the mosaic surface of the Villa, through grouping the observations into homogenous clusters. Effectiveness in the use of the information provided by the spectrophotometric and colorimetric analyses is strongly related to the immediacy and ease of data reading by the restoration operators for whom the issues concerning the color measurement and its representation are often unfamiliar. This paper analyses data of different mosaic tesserae before/after the cleaning intervention and presents data clustering with PCA. This statistical technique has provided a synoptic scheme capable of improving data interpretation concerning the chromatic behavior of the materials. Moreover, the cluster distribution highlighted by the multivariate analysis made it possible to identify, more clearly, the parameters that mostly contribute to the chromatic shift and to monitor the behavior of variously colored tesserae.  相似文献   

10.
Along the Umbria-Marche stretch of the Flaminia Consular Road (220 B.C.) several archaeological finds of the most important monumental works, are well preserved. The stones, employed to build many bridges, substructions and sewerages, are represented by carbonatic breccias whose geological environment of formation and source areas had never been established. On the basis of mineralogical, petrographic and micropalaeontological analyses, two groups of these lithotypes employed in Roman age were distinguished: “monogenic carbonatic breccias” only constituted by clasts of the Maiolica Unit (Late Jurassic – Early Cretaceous) and “polygenic carbonatic breccias” made of fragments (in different proportions) of Calcare Massiccio (Early Jurassic), Corniola (Early Jurassic), Maiolica (Late Jurassic – Early Cretaceous) and Scaglia Rossa (Late Cretaceous – Early Paleogene) Units. The possible source areas of the breccias are compatible with stratified slope-waste to scarp-base deposits of periglacial origin belonging to the Upper Pleistocene. In particular, among the seven investigated areas, we pointed out the most probable provenances (Monte Faeto-Colle, Costacciaro, Scirca, Foci, Secchiano) along the flanks of the Apennine Mesozoic chain of the Umbria and Marche regions. Although the Romans could have exploited the whole thickness of some outcrops (now disappeared) of these carbonatic lithotypes at the deepest part of the valleys, we have constrained a local provenance of the breccias so commonly used in the monumental works of the Flaminia.  相似文献   

11.
Roman cements, one of the most extensively produced types of hydraulic binders of the second half of the 19th century, played an important role in the architecture of many European countries. This paper deals with the chemical-mineralogical and microstructural characterisation of historic Roman cement renders from Budapest, Hungary. Different microscopic techniques were used on polished thin sections and fracture surfaces in order to understand the method of producing these renders and the effect of urban pollution on them. The renders exhibited characteristics typical to a Roman cement mortar, such as high binder to aggregate ratios (b/a), mostly fine-grained aggregates and high capillary porosity, but without the shrinkage cracks that are also normally present. This research suggests that coarse residual cement grains may have acted in a manner similar to aggregates by absorbing stress and thereby reducing the formation of shrinkage cracks. Based on the mineral characteristics of residual cement grains, the samples could be divided into two groups, which correspond to either a higher or lower temperature of calcination of the original source material of the cement. Chemical characteristics of the binders suggest the presence of intermixed CaCO3 originating from the carbonation of hydration products and partly from residual calcium carbonate of the raw material. Despite dense and often impermeable coats applied in later renovations and exposure to a polluted urban environment, which resulted in formation of gypsum on the surface of the renders, the samples show good to excellent state of preservation after more than a century. The strong “house of cards”-like arrangement of the complex C-(A)-S-H-type phases is responsible for both the high capillary porosity and the good resistance of Roman cement renders to atmospheric pollution and potentially damaging salts such as Na- and K-chlorides which are found near the base of the building due to sidewalk de-icing. These results help to better understand the behaviour of historic Roman cement renders, which in turn assists in making good decisions in choosing a repair material to future restorations of 19th century façades built with this material.  相似文献   

12.
Xuan paper is a type of Chinese handmade paper produced for traditional calligraphy and painting in China since the Tang Dynasty (618–907 AD), and is therefore an important cultural heritage material. In this study, the fluorescence and photochemical properties of Xuan paper were investigated. Xuan paper exhibits auto-fluorescence in the blue spectral range (450–500 nm) and UVA photolysis of the paper resulted in a substantial reduction in the blue fluorescence together with the formation of chromophores absorbing in the visible spectrum, resulting in photoyellowing of the paper. A more significant yellowing of paper was observed when irradiated in the dry state than under wet conditions. The associated photogeneration of hydrogen peroxide and superoxide from three types of Xuan paper samples during irradiation showed a correlation between the yields of reactive oxygen species and their relative yellowing rates. The results are interpreted in terms of sensitised photooxidation via a mechanism of electron transfer involving the fluorophores in their excited singlet states being responsible for the photodegradation of Xuan paper. SEM/EDS analyses were performed on the Xuan paper samples to investigate their morphological and elemental characteristics. Silica-containing fibres characteristic of a special rice straw that grows in siliceous soil were observed in all types of Xuan paper. Micron-sized calcium precipitates possibly formed from the “lime-steaming” manufacture process were shown to protect against the acidification of paper during accelerated thermal ageing.  相似文献   

13.
Landscapes, Heritage and Culture interact in accordance with two directions: the Heritage Landscapes and the Landscape's Cultures. This paper introduces a model of the complex system of such interactions occurring along these two directions and within two co-evolving frameworks:
  • -the “knowledge framework” corresponding to the space-time associated to the requirements, creation and utilisation of the cultural objects under consideration;
  • -the “valorization framework” corresponding to the space-time associated to the monitoring, conservation and fruition of the cultural objects as emerging from the knowledge framework.
Main methodologies concerning the management of the interactions systems of Landscapes, Heritage and Culture are also proposed.  相似文献   

14.
Orchids have fascinated humans since ancient times. Not only the particular morphology of their flowers and hypogean organs, but also their reproductive biology have inspired myths, legends and popular traditions in many cultures, all around the world. Despite these facts, their representations on ancient artefacts have never been described in the scientific literature. No clear data exist for Eastern culture, and in Western countries, the first certain representations of orchids in art date back to the XV-XVI century CE. This paper documents different identifications of orchids on Roman monuments changing the common belief that these plants first appeared in art more recently. Floral elements of Cephalanthera spp., Spiranthes spiralis (L.) Chevall, of Orchis tridentata Scop., and of other orchids were observed in different architectonical elements (cornices and ceilings) throughout the Roman period, and in the external frieze of the Ara Pacis monument (I century CE). These representations seem to refer to a symbolism of fertility and sexuality, and their absence in medieval time can be explained only considering religion influences.  相似文献   

15.
Via Appia, built around 312 BC, is an engineering masterpiece, its most striking feature being the segment between Colle Pardo and Terracina, which goes “straight” for about 61 km. We investigate this segment by GPS techniques: results lead to uncover that the original project of the road was based on a complex interplay between geometry and astronomy. The project was indeed carried out with the help of an orthogonal centuriation grid, with all probabilities starting from a node located at the south easternmost point of the grid itself. The road however does not run along the grid's diagonal: it was orientated astronomically to the setting of the star Castor at the time of construction. Since the Gemini twins were patrons of the Roman army, the project turns out to be a work entertained for both practical and symbolic reasons, during a key moment of the Roman history.  相似文献   

16.
This paper reports petrographic and chemical data and magnetic susceptibility values for trachytes of quarries recognizable within the Euganean Hills and sets out diagnostic parameters for these rocks. The diagnostic scheme proposed is basic for the definition of provenance of trachytes used in ancient artefacts spread over northern Italy. Trachytes were extensively used by the Romans for paving Via Aemilia, the most important road in the Po Plains connecting Ariminum (present-day Rimini on the Adriatic sea) to Placentia (present-day Piacenza on the Po river). Remains of the trachytic flagstones (basoli) used for paving segments of Via Aemilia crossing Regium Lepidi (present-day Reggio Emilia) and Bononia (present-day Bologna) have been characterised petrographically, chemically and also using magnetic susceptibility data. The discriminating scheme proposed here for the Euganean trachytes has been applied to the data obtained for basoli and thus the provenance of each investigated block has been inferred. The rocks sampled at Regium Lepidi mostly come from Monselice (only a few blocks from Monte Oliveto and Monte Merlo) and those of Bononia come mostly from Monte Merlo and, subordinately, from Monte Oliveto and Monselice (only one sample from Monte San Daniele). The dominant provenance of blocks, which is different in the two colonies distant by less than 50 km, suggests that the two segments of Via Aemilia were not built simultaneously.  相似文献   

17.
Microbial corrosion of glass causes problems on delicates antique glass samples. Until now, the effect of microbial activity on corrosion phenomena has not been well documented. Only a few studies have been published concerning the microflora growing on glass surfaces.The present study deals with the characterization of cultivable aerobic bacteria isolated from the historical glass window “Natività” in the Florence Cathedral, designed by Paolo Uccello and realized by Angelo Lippi between 1443 and 1444. Microbial strains were sampled from four of the 25 panels of the “Natività” in the occasion of a recent conservation treatment, due to the presence of various kinds of crusts. One hundred microorganisms were isolated, about 50% bacteria and 50% fungi. Bacteria were submitted to morphological characterization and classified in the Gram group. For twenty strains, from different glass panels, the 16S rDNA gene was amplified and sequenced. Sequence analysis showed genus Bacillus, Arthrobacter and Paenibacillus as the most representative. In particular Bacillus and Paenibacillus are crusts associated. Phylogenetic relationship among isolates was determined. Chemical analysis of the glass and crusts completed the study.  相似文献   

18.
Adobe is a construction technique that uses raw earth mixed and moulded to form sun-dried blocks to realize a bearing wall. The recent discovery of adobe walls belonging to a Republican domus sited in Suasa (Ancona, Italy) was the starting point of the present work. The research was developed through an experimental approach, in order to characterize the mechanical behavior of this type of walls: firstly some adobe blocks similar to the original ones were reproduced by using the soil directly came from the archaeological site near the adobe walls and adding straw to reduce hygrometric shrinkage and coarse sand, taken from a local quarry, as a stabilizer, as Romans were used to do. Then, after a seasoning period of 4 months, four adobe walls were produced to be tested by compression and shear. From compression tests, maximum strength, first cracking compression stress, Young modulus and breaking manner were evaluated. As well, compression results show a possible two-storey structure of the earthen Republican domus. In fact, it appears that the stress from the two-storey load analysis is lower than the first cracking compression stress. From the shear tests, a proportional law seems to regulate the relation between the maximum value of the mean tangential tensions and the vertical compression the sample is subjected to. This could be the starting point for a future seismic analysis.  相似文献   

19.
Paintings are in essence about visual features of varying significance from which differences in their market prices originate. Studies normally investigate derivative sources of painting price determinants, which is reasonably understandable because the appreciation of an image is quite subjective. This paper provides an operational solution to the quantification of paintings based on a new concept termed as “visual autocorrelation” of prices (VAP). Considering the current empirical framework of spatial and temporal autocorrelation of prices, and using data on the paintings of two abstract expressionist artists, empirical results support the coherence of the VAP concept.  相似文献   

20.
Thirteen samples of an efflorescence collected from the surface of beeswax seals or from beeswax used for their restoration were analysed in detail. The samples were of different origin, age and storage history. The composition and the incidence of the efflorescence was correlated with a chemical composition of historical and recent beeswax samples. The composition of the crystalline layer was found to be very similar in all the samples. Linear monounsaturated alkenes containing 31 and 33 carbon atoms, more precisely (Z)-hentriacont-10-ene and (Z)-tritriacont-10-ene, were identified as main components. The analyses of beeswax have revealed that all compounds identified in “wax bloom” naturally occur in recent beeswax. However, the historical beeswaxes contained only traces of unsaturated hydrocarbons, if anything. The efflorescence was observed primarily on the surfaces of those samples which contained larger proportion of alkenes. The presented results could be of particular importance not only for better understanding of the described phenomenon, but also for the development of new beeswax-based materials, which would be “bloom resistant” and useful for conservation purposes.  相似文献   

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