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1.
The analysis of 42 glass fragments, excavated in the Italian archaeological site of San Martino di Ovaro, that includes a palaeochristian church dated from the V–VI century, has been done using the PIXE technique in a fully non-destructive way without any sample preparation. The results have been validated with a set of standards and using PIGE data acquired in parallel. The data of 29 of the 42 glasses indicate that an earlier group of samples (window sheets and sacred vessels, dated from the V–VI century) is typical of the Roman technology and can be associated to a Levantine production of natron glass. The blue glasses of this group are all window sheets coloured with cobalt, probably from the Near-East. The remaining heterogeneous samples (lamps, necklaces, cups) are related by their type and function and by the different compositions, to the later use of the site as a market place. The natron glasses of San Martino di Ovaro provide new data for the understanding of the changes in the glass industry in North-eastern Italy and nearby regions across the fall of the Western Roman Empire.  相似文献   

2.
Various types of Late Neolithic decorated pottery excavated in Polyplatanos (Imathia, Greece) such as Crusted (C), Classical Dimini (CD), Black-on-Red (BoR), Cream-on-Red (CoR) and Graphite (G) were archaeometrically studied in order to investigate their provenance and to clarify specific technological features. The clay bodies, the paints and the slips were stereoscopically analyzed, while their elemental composition was determined, using non-destructive multi-elemental micro X-ray fluorescence spectroscopy. Furthermore, the analytical data were statistically treated using multivariate exploratory techniques (Principal Component Analysis, PCA). As a result, novel technological information was derived especially concerning the Crusted type ceramics, which have not been widely examined by archaeometric means up to now, while useful provenance associations were also derived from the statistical combination of the studied groups.  相似文献   

3.
A group of 51 shards of medieval polychrome glazed pottery, coming from Canosa castle archaeological site (Bari, Italy), has been investigated through surface analytical techniques, such as Scanning Electron Microscopy (SEM) with Energy Dispersive X-ray Spectroscopy (EDS) and elemental ones, such as Inductively Coupled Plasma–Optical Emission Spectroscopy (ICP–OES) and Absorption Atomic Spectroscopy (AAS) by flame and electro-thermal atomisation. The investigation was aimed at defining the elemental composition of pottery findings, identifying pigments and clarifying glaze types. The results of the analytical characterization allowed the identification of materials and technological expedients used for pottery manufacturing, highlighting original features in the production of the investigated pottery.The quantitative analysis performed on ceramic paste, glaze and painted decorations provided a significant number of results, thus enabling their effective exploitation for multivariate statistical techniques, in order to find out possible groups of pottery items with defined similarity within the samples.  相似文献   

4.
The presence of a diffuse biodeterioration phenomena can be observed across large areas of the outer surface of the limestone walls of the Church of the Virgin in Martvili. A differential erosion phenomenon was detected, suggesting a possible association with biological colonization. The erosion phenomenon is characterized by a circular discoloration leading progressively to the detachment of flakes of limestone at its center. Since the aforementioned process has not been described in the literature until now, the present study was focused on the interpretation of its origin and evolution. Three sides of the Church are affected by a variety of occurrences of circular differential erosion which display different stages of the process, whereas the western side is affected by epilithic growths across its entire surface. Surveys of the petrographic, mineralogical and physical features of the stone were made, and parameters such as density and porosity were recorded. Samples were analyzed by optical microscopy and SEM analysis in order to detected the presence of microorganisms whose species were then identified by means of morphological and molecular examinations. The study of cross-sections stained using the PAS method has confirmed the causal connection between microorganisms and the deterioration phenomena, providing information about their spread of penetration into the substrate and their substantial potential for causing damage. Dryness appears to be the main ecological condition favoring endolithic rather than epilithic growth. The most common isolated microorganisms were cyanobacteria (Chroococcales) and, to a lesser extent, meristematic fungi. The characteristics of the stone, and especially some endogenous discontinuities related to the accumulation of sedimentary layers and to the action of stone carving tools, might explain why the same differential erosion phenomenon occurs in specific areas of the block stones. The development of the differential erosion phenomenon shows a variety of stages of biological colonization. The progressive evolution of the deterioration process has been observed in detail: (a) firstly, white circular discolorations appear on the stone, which darken over time eventually becoming almost black; (b) circular perforations appear around the perimeter; (c) and finally a flake detaches from the center, leaving a deep depression in the stone.  相似文献   

5.
This study explores an under-researched phenomenon of how African Americans communicate about patriotism via ordinary political conversation. We conducted two studies that offer a critical-qualitative analysis of how patriotism is colloquially articulated among African Americans. In study one, focus group interviews were conducted, transcribed, and analyzed using constant comparative method. In study two, we conducted a quantitative content analysis. The findings from study one revealed that there are three relational conceptualizations that help characterize one’s orientation to their nation (i.e., community: subordinate, guardian, and tumultuous). Participants expressed having an attachment to, identification with, and commitment to their communities.  相似文献   

6.
In the cultural heritage area, it is of fundamental importance to characterize and classify the conservation state of the materials constituting ancient monuments, in order to study and monitor their decay. Generally, the decay diagnosis is provided by “naked eye” analysis done by expert scientists “walking around” the artifact and recording the conservation state of each individual element they observe. In this paper, a color image segmentation approach, based on histogram threshold and edge detection techniques is presented, to extract degradation regions, characterized by holes or cavities, from color images of stone-materials. The goal is to provide an aid to the decay diagnosis by segmenting degraded regions from color images, computing quantitative data, such as the area and perimeter of the extracted zones, and processing qualitative information, such as various levels of depth detected into the same zones. Since color is a powerful tool in the distinction between objects, a segmentation technique based on color, instead of intensity only, has been used to provide a clearer discrimination between regions. The study case concerns the impressive remains of the Roman Theatre in the city of Aosta (Italy). In particular, we have processed and analyzed some color images of the theatre puddingstones, acquired by a camera.  相似文献   

7.
Using inductively coupled plasma–atomic emission spectrometry (ICP-AES), atomic absorption spectrometry (AAS) and instrumental neutron activation analysis (INAA) the concentration of Ag, As, Au, Bi, Cu, Fe, Ga, In, Ni, Sb, Sn, and Zn in 53 samples taken from archaeological finds dated to 4th–2nd century BC and found in the territory of ancient Thracia was determined. Additionally using inductively coupled plasma–mass spectrometry (ICP-MS) and MS for determination of the lead isotope ratios in the samples was carried out. On the basis of these analytical results using cluster analysis for grouping the samples on the bases of the similarity in chemical and isotopic content and the available data from the literature for lead ore deposits in the Balkan Peninsula, the geological origin of the investigated archaeological finds was evaluated. That confirms the expectation that sources of lead might be almost all possible deposits of lead ores on the Balkan Peninsula—from Lavrion through Chalkidiki to the Rhodope mountain. The result indicates that the Thrace did not utilize one single lead source continuously but that lead was provided according to availability from different production centers.  相似文献   

8.
Lava columns from the cathedral St Maria of Randazzo (Catania, Italy), were studied in order to establish the classification of these rocks and to investigate their origin. At the beginning of the XIX century, some columns of the old frame of the nave were removed to build the dome and stored in a fornix beneath the cathedral. Samples were taken directly from these columns. The specimens underwent petrographic investigation through optical microscopy, X-ray diffraction analysis (XRD) and Fourier transform infrared spectroscopy (FTIR) and chemical analyses of major and trace elements through X-ray fluorescence (XRF). Some trace element (Sr, Rb, Y, Zr and Nb) concentrations were assessed through non-destructive analyses, performed with a portable X-ray device which can detect homogeneous concentrations of such elements on the columns of the cathedral. According to chemical data, these rocks can be classified as mugeariites whose mineral assemblage is given by plagioclase (mostly andesinic), augitic pyroxene, olivine, magnetite and, occasionally, apatite. In order to investigate the origin of the material used for the columns, a comparative examination was conducted between the column samples and specimens collected from quarries in the surrounding area of the town of Randazzo (Randazzo and Maniace quarries and the 1536 lava flow). The correlation with the Randazzo quarry proved to be excellent.  相似文献   

9.
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10.
The chemical composition of 11 glass panes originating from two 13th century non-figurative windows were analyzed by means of Scanning Electron Microscopy–Energy Dispersive X-ray system (SEM-EDX). The windows were discovered in the back-wall of the triforium during the restoration of the choir of the cathedral St. Michael and St. Gudule in Brussels (Belgium). In order to determine if these windows were fabricated with glass of different origin or not, the compositional difference between the panes were compared with the variation in composition as a result of the following causes: (1) compositional fluctuation between panes cut from the same sheet of glass, (2) compositional fluctuation caused when panes are cut from different sheets that were made with the same batch, (3) compositional fluctuation caused when the glass is made from different batches at the same production center, and (4) compositional fluctuation as a result of glass produced at different fabrication centers.  相似文献   

11.
From 18 archaeological sites of the Lagoon of Venice 75 bricks belonging to Roman and medieval building levels have been analysed. Chemical composition and geometric measures allow the characterization of a group of 24 Roman bricks of Imperial age. The group formed by means of fuzzy c-means cluster analysis applied on chemical data have been tested by principal component analysis and finally subjected to discriminant analysis to estimate the relative weights of original variables and classify new elements. Correlations among the data of the major chemical elements confirm the reliability of the complex of chemical data. The aim of this research was to obtain a chemical characterization of Roman bricks (and later, of the medieval ones) coming from the lagoon of Venice thus making it possible: 1) to recognize the age of a brick by means of its chemical analysis; 2) to date the layers of archaeological excavations or the ground where there are medieval building foundations by means of membership bricks; 3) to calculate the rate of local ground lowering in the elapsed years by the difference in level from one layer to another; 4) to estimate local rates of land subsidence by comparison with mean values already known.  相似文献   

12.
Hyperspectral data were exploited to test their effectiveness as a tool for archaeological prospection, envisaging their potential for detecting spectral anomalies related to buried archaeological structures. For this purpose the airborne Multispectral Infrared and Visible Imaging Spectrometer images were analysed. Each single band of the entire data set and different processing technique products were interpreted to identify any tonal anomalies. Since every analysed image exhibited marks different in terms of size and intensity, two indexes were defined for assessing the potential of anomalies detection of each image. Such parameters were: the Detection Index, used for counting the number of pixels related in each image to marks, and the Separability Index, applied for measuring the tonal difference of the marks with respect to the background. These indexes were tested on two areas within the Selinunte Archaeological Park where the presence of remains, not yet excavated, was supposed by archaeologists. For the test sites any extracted anomalies were evaluated by an expert in order to determine their archaeological relevance. The comparison among the index values, derived from each single band of the spectrometer and from different image processing by-products, allowed to determine which spectral range and which processing method are the most valuable to quickly highlight the anomalies. The analysis pointed out that, where vegetation cover is dominant, the Visible near infrared is the spectral region more sensitive to variations of spectral properties related to buried structures, while, where soil cover becomes relevant, the Short-wave infrared and the Thermal-infrared regions resulted more sensitive. As far as the applied processing methods are concerned, the Spectral Angle Mapper classifier and, secondly, the Minimum Distance algorithm stressed the highest archaeological information content. The results of this work showed that the archaeological information content derived by analysing the outputs of the applied image processing techniques is more significant than the information obtained by interpreting each single band and the available historical aerial photos. As a final remark, the data processing flow chart, applied to the entire remote hyperspectral data set over Selinunte Archaeological Park, appeared encouraging for detection of anomalies related to the presence of the buried archaeological structures.  相似文献   

13.
Out of the staters collection of the National Archaeological Museum of Taranto, during the full examination of about one hundred coins minted by the Greek colony of Taras between the V century BC and the III century BC, our attention has been devoted to a lead coin, which has been regarded for many years as a genuine silver coin. This artifact, entry number 13 in the inventory list for the Parabita hoard, has been studied with the combined use of surface and micro-analytical techniques (SEM, EDX, PIXE, XRD). The joint use of different analytical techniques allowed us to obtain information about the morphology, the structure and the chemical composition of the analysed coin, that revealed a lead core coated with a bi-layer of copper and silver.  相似文献   

14.
Within the framework of an excavation project aimed to systematically characterize the various aspects of settlement and activities in Northern Jordan, a considerable collection of slag lumps and iron artifacts of different forms and typologies excavated from the archaeological site of Barsinia were collected. Excavations have revealed other metallurgical materials such as pottery tuyeres and furnace-like structure. Studying those finds was important because of their archaeological and technological interests. For the analytical and metallurgical study, X-ray diffraction was used to identify the mineralogical composition of samples. Inductively coupled plasma-optical emission spectrometer, energy dispersive X-ray and X-ray fluorescence spectrometer were used to determine the accurate elemental composition of these finds. Furthermore examinations by using metallographic, polarizing microscope and scanning electron microscopy were employed to diagnose the characteristic morphology and environmental effects of these archaeometallurgical finds. Microstructural investigations emphasized that iron production processes were performed locally at the archaeological site of Barsinia even if the iron ores were imported from other mining location in Jordan. Direct or “bloomer” was the main method used for smelting iron ores followed by smithing methods to locally produce iron artifacts. This, most probably, was the state of technology from the Bronze Age to the Byzantine period. To ensure the stability of these deteriorated finds for future research, required treatment and conservation processes were successfully carried out.  相似文献   

15.
Leaves of common deciduous trees: the horse chestnut (Aesculus hippocastanum) and linden (Tilia spp.) from the park, near one of the most important cultural institutions, the National Library of Serbia, were studied as bioaccumulators of heavy metal (Cr, Fe, Ni, Zn, Pb, Cu, V, As and Cd) air pollution. The leaf samples were collected from the urban park exposed to the exhaust of heavy traffic. The May–September heavy metal accumulation in the leaves, and their temporal trends, were assayed in a multi-year period (2002–2006). Comparing the obtained concentration of the investigated elements from the beginning to the end of growing seasons, a significant rate of accumulation was determined for a majority of measured elements, and it was concluded that these tree species (horse chestnut and linden) can be used as bioaccumulators of the investigated heavy metals. The SEM-EDAX analysis of individual particles deposited on the leaves showed that the 50–60% belong to a class of fine particles (D < 2 μm), mainly of anthropogenic origin. Thus, the investigated tree species could be grown as a natural barrier against urban air pollution in the vicinity of libraries, museums and other buildings for cultural heritage storage.  相似文献   

16.
The sculptural polychromy in the Zhongshan Grottoes, sited in northwest China, has been investigated in terms of chemical composition of employed materials and pigments, state of conservation and painting technique. Raman analysis, Fourier-transform infrared analysis, analysis through energy-dispersive X-ray spectrometry coupled to scanning electron microscopy and pyrolysis coupled to gas chromatography and mass spectrometry were applied. Six analyzed samples showed silicates and kaolin as main components of the ground layers. Also lead white has been found in these layers. Minium, red-earth and mercury sulfide are the red pigments detected in the polychromy. A mixed use of malachite and atacamite has been detected in three green samples. Optical characteristics of atacamite and malachite found in the samples indicate a synthetic origin. The presence of a synthetic organic pigment such as phthalocyanine chlorinated pigment was also revealed. Ultramarine blue pigment, obtained by purification of lapis lazuli, has been detected in the blue sample. As for the binders used, fatty materials and siccative oil were found.  相似文献   

17.
This qualitative study explores the narratives of 12, first-generation, queer, Iranian-American women to understand (a) how Iranian cultural, familial, and relational discourses influence feelings of “belonging” for queer Iranian-American women, and (b) how queer Iranian-American women cope with the challenges of being both LGBTQ and Iranian-American. Online interviews were analyzed using grounded theory analysis, revealing that queer Iranian-American women experience feelings of cultural isolation as a result of the homosexual identity delegitimization that is often perpetuated within the Iranian community. Participants cope by creating cultural distance between themselves and the Iranian community when they experience this isolation.  相似文献   

18.
Various studies have built models, using aggregate box-office data, to predict the contribution of a motion picture’s features to its theatrical demand. But such an approach fails to represent the heterogeneous influence of movie features on demographic groups and is unable to assist market-segmentation decisions. We propose and illustrate a new approach for modeling the appeal of movie features to market segments via the use of appropriate individual-specific data and canonical correlation analysis. Specifically, through demographically detailed movie-attendance data available in Spain, we build a model of how movie features influence the demographic composition of audiences. Via a canonical correlation analysis, we identify four dimensions underlying the relationships between several movie features (country of origin, genre, objectionable content, stars, promotional effort, and critical evaluations) and audience demographics (gender, age range, presence of children, education, social class, and size of municipality). These dimensions represent the strong pairings between four moviegoer demographic profiles and four movie-feature profiles. Our approach can potentially aid in segmentation and green-lighting decisions by matching movie features with the most relevant segment-specific preferences.  相似文献   

19.
The most popular photographic technique in the USA between 1856 and 1900 was the tintype, with millions of these objects created by photographers in established studios, by itinerant artists in portable workshops, and by amateurs working from ‘how-to’ manuals and journal articles. Whereas the fundamentals for this photographic process (collodion binder on a japanned metal support) were largely invariant, historical documents recommended a wide variety of protective varnish materials. A collection of 221 tintypes was analyzed using pyrolysis gas chromatography-mass spectrometry (py-GC-MS) to compare the components of actual tintype varnishes with recipes from the historical literature. Several resins in published tintype varnish recipes, including mastic, copal, and amber, are entirely absent from this collection and only five constituents – shellac, Pinaceae resin (Canada balsam or colophony), dammar, sandarac, and camphor – are detected alone or in combination. Each detected resin appears in historical recipes, but just 24% of the samples have varnish layer constituents consistent with published tintype varnish recipes. Forty-four percent of the tintypes have varnish constituents consistent with formulations recommended for other collodion images, but the varnishes of the remaining samples have no direct literature equivalents. The preponderance of shellac- and Pinaceae-based varnishes suggests that these correspond to inexpensive commercial varnishes, but tintypists may have developed their own preferred mixtures or simply used what was at hand. This first in-depth technical analysis of tintype materials suggests that the cheapest and most readily available materials were employed in the varnishing process and that the artists were not bound by literature recommendations.  相似文献   

20.
The kilns identification of the Qingbai wares has caught the attention of many archaeological experts. Using ICP-AES method, the major and minor/trace composition of 28 Qingbai wares excavated from different districts were determined. The experimental results show that wares produced in the same location have a great similarity in the content of trance elements; meanwhile the major element K2O, and 12 of all trance elements including Li, Rb, Cs, B, Ti, Hf, V, Sr, Zr, Pb, Nb, Ta, etc., have a remarkable provenance characteristics, which demonstrates a great potential in chemical discrimination of the Qingbai wares from different kilns.  相似文献   

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