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1.
《Journal of Cultural Heritage》2014,15(3):258-265
Lasers have served as cleaning tools for historical objects and artworks for about 40 years. In many cases, superior results of laser cleaning were achieved with respect to traditional methods. In this technique, contaminations on the surface of the object are ablated by laser irradiation. In order to apply laser cleaning method to fragile materials such as paper made of cellulose or parchment, heat deposition to the bulk should be minimal, to prevent damage. In this work, it is demonstrated that laser pulses with femtosecond (fs) duration can exhibit non-thermal ablation of contaminants on paper samples. In particular, laser cleaning studies are concentrated on paper samples with sizing. Fs laser cleaning is performed on artificially soiled and aged samples, as well as on historical ones. The laser used in the experiments has pulse duration of 550 fs and 1030 nm center wavelength. The fluence of the laser is varied and the post-cleaning statuses of samples are investigated. The analyses are color changes, fiber integrity, chemical composition changes and mechanical strengths. These results show that fs lasers can be very efficient in cleaning paper samples, yielding minimal discoloration and no damage to fibers distinguishable on microscopic examination. The presence of sizing also provides further protection against possible side effects. 相似文献
2.
Potentials and limitations of the near-UV pulsed laser cleaning of parchment (wavelength 308 nm, pulse duration 17 ns) are demonstrated by the application of scanning electron microscopy (SEM), colour metrics and diffuse reflectance infrared Fourier transform spectroscopy (DRIFT) at model contamination/pigment/parchment systems. Pigment-binder systems stable and unstable against near-UV laser treatment could be identified. A chemical degradation threshold fluence of a goat parchment model substrate was determined which practically coincided with its ablation threshold fluence. This indicates that the fluence range of destructionless laser cleaning at 308 nm is almost not impaired by chemical modfications below the ablation limit. Nevertheless, spectroscopic diagnostics are necessary to guarantee destructionless cleaning for practical cases where the chemical conversion threshold fluence deviates from the ablation threshold to lower values. 相似文献
3.
Within the conservation programme of the mausoleum of Theodoric, located in Ravenna, Italy, we applied a new cleaning procedure based on the use of a recently developed Nd:YAG laser system, suitably equipped in this case with long optical fibre cables for the transmission of laser radiation to work sites on the façade. The intervention of the laser technique was required to complete the cleaning of a decoration surrounding the monolithic dome, after conventional cleaning methods had been applied with unsatisfactory results. Preliminary laboratory analyses on stone samples collected from the dome and subjected to laser treatment indicated that this technique was effective and could fully preserve the lime–Ca oxalate film existing below the thick layer of black crusts. Before starting the operative phase on the mausoleum, it was necessary to solve the practical problem of keeping free access to the monument during cleaning operations, which hindered the location of the laser in close proximity to the sites to be cleaned. This was achieved by preparing long fibre cables (up to 50 m) which permitted the successful completion of the cleaning while leaving the laser body far away from the dome. 相似文献
4.
A fast and reliable surface monitoring and diagnostic technique is essential to develop a real-time automatic control system for laser cleaning of artworks. In this paper, an in-line surface monitoring and diagnostic system based on chromatic modulation using tristimulus detectors and fibre optics is presented. The system produces measurements that are dependent on the spectral signature of the incident light but are independent of intensity. In order to demonstrate its usefulness and versatility, the technique was applied to surface monitoring in the laser cleaning of metal and stone. Results show that the spectral parameters derived from chromatic detection not only provide a clear indication of the surface cleanliness and surface damage but also much surface chromatic information from its versatility. It is also shown in this paper how a chromatic modulation technique may be utilised as a robust method for monitoring and diagnosing the surface during laser cleaning. 相似文献
5.
Renzo Salimbeni Roberto Pini Salvatore Siano Giancarlo Calcagno 《Journal of Cultural Heritage》2000,1(4):2215
The utilization of laser light to produce fine and selective cleaning of superficial deposits and encrustation from stones was originally proposed more than 20 years ago by John Asmus who performed pioneering trials of laser cleaning on stone façades in Venice, Cremona and Padua. The opportunity to collect stone samples from these sites allowed us to carry out an original study aimed at evaluating the conservation state of stone surfaces cleaned 10–20 years ago by means of three different techniques: Nd:YAG laser radiation, micron sandblasting and chemical pads. Samples of various stone types, as Istria limestone, Botticino limestone and Nanto sandstone were collected and examined by means of optical and SEM microscopy, FT/IR, and EDAX analyses. The results provided preliminary indications that the state of conservation of stone surfaces previously subjected to laser cleaning is generally better in comparison with those which concurrently underwent mechanical and chemical cleaning. 相似文献
6.
《Journal of Cultural Heritage》2009,10(1):48-52
The paper presents the use of laser radiation for cleaning of beeswax treated granite stone. In the early sixties, prestigious restorers decided to apply molten beeswax on the granite surface of valuable monuments with the aim of preventing the erosive action of atmospheric agents. An interesting example of this treatment is the Renaissance Frieze in the Cloister of the Cathedral of Santiago de Compostela in Galicia (Northwest Spain). With time, salt accumulation beneath the beeswax layer has caused an intense surface disintegration of granite. Conventional cleaning methods can destroy sculptured details of these emblematic monuments. For this reason, excimer laser cleaning has been chosen as a promising non contact, selective and environmentally friendly cleaning technique to be studied.The cleaning tests have been carried out using an excimer laser (ArF, 193 nm), with fluences between 0.5 and 2 J cm−2 pulse−1 and a spot area of 0.025 cm2. Samples representing beeswax films over Roan granite have been irradiated and their degree of cleaning has been studied as a function of the number of pulses and the laser fluence.Cleaning efficiency has been evaluated by FT-Raman Spectroscopy, allowing to establish the beeswax ablation threshold and the ablation rate.Excimer laser cleaning allows a progressive and controlled removal of a few tenths of micrometers of beeswax per pulse without damaging the underlying granite stone. 相似文献
7.
The development of laser cleaning as a conservation treatment has imposed a need for the evaluation and assessment of other cleaning techniques. The use of more traditional methods like abrasive cleaning, steam cleaning and chemical cleaning has relied so far on visual assessment, unlike much of the research applied to laser cleaning. A conscientious use of these cleaning methods requires their assessment as well as the need for a comparison based on a common methodology. A topographical assessment of laser cleaning, abrasive cleaning, steam cleaning and chemical cleaning (using hydrofluoric acid, ammonium carbonate and EDTA) is presented. Topographical variations induced on marble, oolitic limestone and architectural terracotta surfaces are assessed by means of light interferometry, showing the potential of this non-contact and non-destructive technique for surface studies in conservation. The comparison between cleaning treatments is based upon key parameters associated with cleaning surfaces. The aesthetic impact of these treatments is verified by means of optical microscopy and quantified by colour measurement. Chemical analysis of the cleaned surface (EDS) is performed to investigate the removal of surface pollutants and the presence of residues. Finally, petrographical analysis was used to investigate the removal of pollutant layers and its effect on surface texture. 相似文献
8.
An innovative laser restoration tool for non-contact cleaning of painted artworks is developed. Accurate beam manipulation techniques in combination with on-line detection make the system suitable for selective cleaning of delicate surfaces. The utilisation of lasers obviates the use of various chemicals, and provides a method to remove layers that are untreatable using conventional methods. The first professional laser cleaning station for paintings is equipped with a modern mechatronic engineering tool for accurate beam manipulation (‘optical arm’). An intelligent combination of software and hardware enables accurate control, necessary to deal with the variable properties of the artworks to be treated. An on-line monitoring system is incorporated, using laser-induced breakdown spectroscopy. The user interface plays an important role in simulating the ‘hands-on’ treatment. In January 1999, the 2-year European co-operative research project ‘Advanced workstations for controlled laser cleaning of artworks’ started. The research objective is to define the boundary conditions in which laser cleaning with the present technology can be safely applied. 相似文献
9.
Laser cleaning of ancient marble and stone monuments is nowadays a well-accepted procedure in conservation. Operators and specialists are presently divided between those giving maximum confidence to this method of cleaning and others who, in contrast, are strongly critical and emphasise possible drawbacks and damages caused by laser. As any other method of cleaning, laser also offers advantages but at the same time is limited by drawbacks. Most conveniently, it should be integrated with the other methods. On the basis of the above considerations, the authors are proposing a combined procedure using laser cleaning as a first step – in this way removing the relevant part of black gypsum encrustation – followed by chemical methods as a final step. The latter, conveniently, could be accomplished by means of anion exchange resins, better than ammonium carbonate. An experimental check-up was made of four different methods applied on three different lithotypes on the façade of the Florentine Cathedral. Laser, micro-sandblasting, ammonium carbonate and sodium EDTA were the cleaning methods compared, whilst Carrara marble, green Serpentine (Verde di Prato) and a red limestone were the three lithotypes. Results are commented by showing differences in the advantages and drawbacks among the different methods on the various lithotypes. 相似文献
10.
Laser cleaning was applied to remove aged and soiled oil paints of the 19th century from weathered, brittle sandstone surfaces. In contrast to other tested cleaning methods, the laser technique allows the removal of the oil paint layers with a minimum of material loss in brittle zones. The cleaned test areas have been investigated by optical and scanning electron microscopy as well as by colour measurements. The investigations have shown that the dirt and the oil paint layers can be removed by laser cleaning without affecting the original sandstone surface and that the pores can be opened again. The brown shade after cleaning is not caused by laser interaction with the sandstone surface but by historic impregnation with linseed oil. Immediately after cleaning, a treatment with chemical consolidants is necessary to preserve the brittle sandstone surface. Sustainable consolidation could be problematic in some areas, because the laser cleaning also preserves heavily damaged, crumbling zones of the carvings. For economic reasons, laser cleaning should be applied only in the most endangered zones of carvings and combined with classical methods (organic solvents and scalpel). 相似文献
11.
The historical paper samples from XIII–XIX c. are characterised by means of techniques of the optical spectroscopy. The influence of pulsed laser cleaning by means of the Q-switched Nd:YAG laser at 532 nm on the spectra and also cleaning results of stained paper documents are reported and considered. In the absorption spectra, the minima around 280 and 370 nm are identified and luminescence reveals a characteristic band centred around 430 nm. The laser cleaning diagnosed by the recording of the LIF spectra with 266 nm excitation shows a profile of increasing intensity and preserved structure. The LIPS spectra reveal sharp emission lines recorded at 612.5, 644.2, 646.5, 671, 714.9, 720.2 nm (Ca I), 589.4, 616.4, 780 nm (Na I), and 766.5: 769.9 nm (Mg I) which are ascribed to the surface contaminations. The intensity decrease of these peaks is in accordance with successive laser pulses and monitors the cleaning progress of the stained paper. 相似文献
12.
The self-limiting effect during laser cleaning only occurs in a limited amount of specific applications in restoration (e.g. removal of black crust from white marble). In all the other cases, a control of the removal process will be necessary either by the operator himself or by the employment of sensor equipment. Various methods, mainly spectroscopic (e.g. LIBS), have been investigated and proposed by others. Despite the fact that these have been shown to be promising, they all have in common rather high investment cost close to that of the cleaning equipment. Furthermore, this highly sophisticated control equipment is not easy to handle by conservators in practice. As an alternative low-cost method, we employed a simple photodiode to detect the scattered light from the irradiation area on the artwork surface. In many cases, this signal contains several pieces of information on the layer just being removed. The scattered radiation detected by the photodiode originates from the laser-induced plasma as well as reflected laser radiation. A separation, if necessary in order to separate the information, is possible by spectral filters. First applications during laser cleaning of corroded metal, encrusted glass and stone were promising. It has turned out that there is a distinct influence on the scattered light amplitude or even the pulse-bandwidth once the laser has removed the encrustation completely. The corresponding signal can be used in a closed loop control or for online monitoring. 相似文献
13.
Laser and chemical cleaning tests for the conservation of the Porta del Paradiso by Lorenzo Ghiberti
In the framework of the preservation project of the Porta del Paradiso, carried on by the Opificio delle Pietre Dure of Florence, we investigated a cleaning methodology based on integrated chemical and laser techniques. This novel approach, which will replace the previous chemical protocol, was aimed at cleaning a number of gilded sculptural elements of the door frieze, without their being dismounted from the bronze framework. To such an end, optimised chemical and laser cleaning techniques were first singly investigated, and then integrated treatments were tested. The critical evaluation of each procedure was achieved through various diagnostic means to characterise the cleaned surfaces from chemical and physical points of view. The analysis demonstrated the various advantages of a laser-based treatment followed by light sodium potassium tartrate poultice application. 相似文献
14.
The eligibility of laser cleaning is tested on regionally specific sculptural stones. Marlstone and sandstone represent the most common building, architectural and sculptural stones employed in the Czech Republic since the Romanesque period. These stone types differ greatly from the marbles on which positive results have been obtained using laser cleaning. Experimental samples were prepared by sawing rock cores. Artificial blackening of samples’ surfaces simulates natural black patinas. The experimental laser cleaning was conducted using Nd:YAG commercial laser (Laserblast 50) at two different fluences—the low one corresponds to the minimum operating capability of the equipment, and the high fluence represents the maximum operating mode of the equipment (i.e. in the ordinary operating range of the equipment). The samples were cleaned under dry and wet conditions. Use of a high fluence resulted in cratering/spalling that is discussed in terms of rock mineralogical composition (presence of clay minerals), adsorption of moisture on clay minerals and physical properties (porosity). Tensional fracturing (evidenced by scanning electron microscopy) along the cleaned surface is the main mechanism of sample destruction due to the vaporization of adsorbed moisture and due to the different elasticity of present rock-forming minerals. Observed discoloration due to high fluence and insufficient cleaning effect of low fluence present other problems encountered. 相似文献
15.
During a conservative operation, a restorer noted a grey shade on a ‘fresh’ (recently fractured) marble surface during laser cleaning. Following this report, the authors began a study on ten Carrara white marble specimens polished on the surface and treated in the same restoration conditions using two types of laser equipment: the first one a Q-switched laser (20-ns pulse), the second one a short free-running laser with a medium pulsewidth of 20 μs. In a few specimens a grey shade appears on the surface. These specimens were investigated by optical microscopy in reflected and raking light and by SEM/EDX. After that, the same samples were embedded in resin and polished to obtain cross sections to be analysed in the same way. Results show that the white marble of the greyish samples contains very small fragments of pyrite (iron sulphide) of dark shiny aspect and that after cleaning the aspect of the fragment appreciably changes. The morphological studies allow two different behaviours of dark inclusion to be observed following the different laser pulses: the first one occurs after short-pulse laser treatment in the form of micro-explosion surrounding the pyrite grains (mechanical effect); the second one (medium pulsewidth) appears like a fusion and spread of particles on the surface. Results are reported showing microphotographs and SEM/EDS documentation. 相似文献
16.
Very often traces of paint and pigment have been found on medieval sculpture. Presently, little is known about the effects of laser radiation on polychromy. It is important to protect and preserve these traces during any cleaning or restoration process. The absorption properties of polychrome materials are likely to be different from those of the underlying stone or substrate and as a result special care must be taken to avoid any damaging or discolouring phenomena associated with laser cleaning. Spectroscopic methods (XPS, AES, reflectance spectroscopy) together with optical microscopy, digital photography and X-ray diffraction analysis have been used in a series of experiments on simulated samples of common medieval pigments (vermilion, red and white lead and ochres in linseed oil) on limestone plates, in order to study the reaction of these materials to infrared laser radiation. 相似文献
17.
An investigation has been undertaken into the effect of wavelength in the laser cleaning of parchment. Tests have been carried out using the fundamental (1 064 nm), second harmonic (532 nm) and fourth harmonic (266 nm) outputs from a Q-switched Nd:YAG laser (pulse length 10 ns). Initial testing was carried out on new parchment to characterise the damage caused by overcleaning. The fluence and wavelength of the laser beam were then optimised so that any damage to the parchment or loss of ink during dirt removal from a late eighteenth century parchment document were minimised. The cleaned surfaces were examined by optical and scanning electron microscopy and analysed by measurement of the shrinkage temperature of cleaned collagen fibres. The laser-cleaned areas were compared with uncleaned areas and areas cleaned by traditional techniques. 相似文献
18.
The Church of the Maddalena was built between 1763 and 1778 by Tommaso Temanza. The building has a central plan and is surmounted by a copper-covered brick masonry dome. The conservation work conducted on the façade has highlighted the superb quality workmanship of the Istrian stone surfaces, which feature extremely fine grain, perfectly regular tooth-chiselling. This finish has led, however, to very specific conditions of decay and laser treatment provided appreciably better results than traditional chemical and mechanical methods. In addition to laser, however, other methods of cleaning were used in order to find the best response to each of the various situations encountered. Indeed it should be emphasized that in restoration it is often appropriate to exploit the potential of several systems, combining their action on the basis of careful preliminary analyses. 相似文献
19.
Within the framework of a European project, three cleaning laser devices are tested to evaluate the influence of different parameters on stone cleaning rate and efficiency. The project objective is to design a large surface-cleaning laser. One of the devices is a prototype with some technological improvements compared to the lasers used today for restoration. The tests are performed on limestone and sandstone covered with various dirt layers. The influence of fluence, water spraying, spot area, frequency, as well as particle emission rate is investigated. Results allow a comparison of the importance of each parameter and confirm the increase in cleaning speed of the new prototype. Nevertheless, it can be concluded that an automatic device will be suitable to attain a cleaning speed competitive with other traditional cleaning techniques. 相似文献
20.
Vassilis Papadakis Afrodite Loukaiti Paraskevi Pouli 《Journal of Cultural Heritage》2010,11(3):325-328
This study aims to introduce a new spectral imaging methodology that can be used to monitor on-line, non-destructively and in situ the cleaning level of pollution encrustation on stonework. The suggested technique is based on the optical properties of monochromatic light penetration in matter. The calculated differences of images, obtained at two different spectral bands, could reliably map the depth of cleaning. This novel approach was tested in the laboratory during laser cleaning trials on polluted stonework enabling high accuracy measurements (such as the detection of thin crust layers remaining on the under-cleaned marble surfaces). However, it may also apply for the monitoring of any other cleaning technique (micro air-abrasive, etc). A detailed presentation of the results will be demonstrated while the potential of its wide application on everyday conservation practice on stonework will be discussed. 相似文献