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1.
Holographic interferometry (HI) was chosen as the diagnostic tool to support non-destructive identification of structural defects commonly found in numerous art conservation problems. Holographic recording provides the highest information content of the concerned artwork and by implementation of a portable pulse laser the procedure becomes vibration isolation free for use outside the laboratory. Nowadays, it is comprehensively appreciated from art conservators that detailed structural knowledge is essential when conservation of precious artworks is concerned. The versatility of a holographic interferometer when used to acquire explicit structural information of art objects is demonstrated here in characteristic cases.  相似文献   

2.
Fibre Optics Reflectance Spectroscopy (FORS) is a well-established technique, widely used in the conservation field for in situ investigations and non-invasive diagnostics on traditional artworks. Nevertheless, there is little knowledge on the use of this technique for investigating modern artists materials used in contemporary artworks. The present study, carried out within the wider framework of the EC funded Project “POPART” (Preservation of Plastic ARTefacts in museum collections”), was aimed at investigating the possibility of extending the applications of FORS to synthetic polymers, and proposing this technique as new non-invasive analytical tool for diagnostics on plastic artworks in museum collections. Thus, a real case was selected from the permanent collection of the Conteporary Art Centre “Luigi Pecci” (Prato, Italy). The artwork, created in 1990 by the artist Stefano Arienti, was entirely constituted of expanded polystyrene (EPS) and it showed diffused signs of degradation. The need of singling out the main causes of deterioration in order to prevent further damages was evident. An in situ FORS measurements campaign was performed with the aim of gaining in-depth information about its conservation state and identifying the main agents responsible for the observed degradation. Thanks to the non-invasivity of the technique an extensive spectroscopic characterisation of different areas of the EPS surface could be performed and the spectral data were exploited to build a map of the degraded areas of the artwork. Data acquired in field were compared with those obtained from laboratory test performed on artificially aged EPS samples. These results helped in ascertaining the detrimental actions of the light sources used to back illuminate the artwork. In particular, in this case FORS proved to be effective in detecting EPS alterations before the chromatic effects became visually evident. These results suggested that FORS may be considered as a good candidate to be used for non-invasive investigations also on some modern materials and contemporary artworks. The research was completed with an interview to the artist Stefano Arienti, whose point of view was constructively integrated with the scientific results obtained. This emphasized the importance of an interdisciplinary approach to the solution of conservative problem in the field of contemporary art.  相似文献   

3.
Many deterioration processes are linked to unsuitable microclimatic condition in cultural buildings. One of the most diffused processes is soluble salts crystallization that can be accelerated in masonry structures within specific microclimatic values for different chemical compounds. In this paper, microclimate and efflorescence diffusion were monitored over a one-year period in the Crypt of the Cathedral of Lecce (South Italy). This allowed to relate the microclimate with the efflorescence variation over time. A three-dimensional computational fluid dynamics (CFD) model was then developed to detail the thermo-hygrometric parameters and airflow patterns responsible for salts crystallization and artworks deterioration. Two main conditions were reproduced; one to simulate the current microclimate, which simulations showed to be inadequate for conservation, and the other to search for a more appropriate solution. In both cases, summer and winter conditions were simulated and compared to find a microclimate able to ensure more suitable thermo-hygrometric intervals required by the constituting artworks materials. The results helped to suggest actions to improve maintenance of the Crypt.  相似文献   

4.
The removal of a brass-based paint (purpurin) used in painting gilded wood to cover losses of gold leaf, represents today a difficult task to conservators, who may have to resort to toxic chemical solvents in order to clean the painted surface. This action, due to its nature, is unsuitable for both the conservator and the artwork itself. In this study, a Q-switched Nd:YAG laser system outputting 1 064 nm (infrared), 532 nm (visible, green) and 266 nm (ultra-violet) radiation was used to study the interaction of these wavelengths in a gilded sample surface painted with purpurin. All tested wavelengths interacted differently with the tested surface and, also, the several layers that form the gilded surface (purpurin, varnish and gold) showed different interactions to each wavelength. The ultra-violet radiation (266 nm), in a multi-pulse mode at low fluences, was found to be the most efficient wavelength in cleaning the painted gilded surface.  相似文献   

5.
The main advantage of a multi-technique non-invasive artwork investigations relies on the use of different spectroscopic techniques that give rise to complementary information. Despite the artworks complexity, this approach allows great insight into the artwork composition and alteration phases. However, difficulties arise from the great amount of heterogeneous interconnected data that has to be stored for a prompt analysis and preserved. A suitable tool to handle and analyse all the information on the fly is therefore crucial to optimize work, specially in in situ investigations. In this paper we present MOVIDA, a new tool for the data management and analysis of non-invasive investigations in the Cultural Heritage field that not only allows the digital preservation of all the information and knowledge, but can also be used as an analytical tool while the investigation is being developed. The software can be installed on any computer to record, elaborate and analyse the data on-the-spot. All the data generated can be managed within the same application and the information can be easily consulted, compared and related to the corresponding areas of the artwork. The software is self-comprehensive and user-friendly and can be used by all the professionals involved in the investigation and preservation of Cultural Heritage whatever their background and computer skills are.  相似文献   

6.
With the aim of identifying new water dispersed polymers for textile conservation, the structure and properties of three commercial polyacrylates and one commercial polyvinylacetate were analysed. The characteristics of these materials, not previously used in the conservation and restoration fields, were compared with that shown by Primal AC33 and Mowilith DMC2 and SDM5, widely used as consolidating or adhesive agents of ancient textiles. To achieve a thorough characterisation of each polymer, molecular, thermal, structural and mechanical investigation techniques were applied on film samples, obtained from polymer water dispersions through water casting at room temperature and/or compression moulding. The photo-oxidative resistance of these materials was also assessed by artificial weathering of water cast films and by measuring the Yellowing Index (YI) as a function of the exposure time under xenon-arc lamp. Collected data were used to appropriately compare the performances shown by these polymers when applied on artefacts consisting of natural fibres. In particular it was found that, among the products not previously used in the conservation and restoration fields, a high potential for carrying out treatments on textiles is shown by the samples commercialised with the trade names of Acrilem RP6005 and Acrilem 30WA. These products, in fact, exhibit properties that make them suitable as substitutes for Primal AC33 and Mowilith DMC2 and SDM5, respectively, depending upon conservation needs. It was very interesting to note that Acrilem 30WA, also after aging, shows YI values lower than that shown by Mowilith DMC2 and SDM5.  相似文献   

7.
Within a hedonic pricing model, the preferences of Australian art purchasers are investigated. Emphasis is placed on the impact of an artwork’s dimensions upon its auction price. A salient aspect of this is the first test of the ‘golden ratio’ hypothesis in a market situation. It is concluded that purchasers prefer paintings that deviate from the golden rule. The ‘orientation’ of works (portrait, landscape or square) as well as size also helps determine price. The impact of winning the Archibald portraiture prize (Australia’s foremost art prize) is found to have significant and positive impacts on winning artists’ prices. This suggests that purchasers are not fully informed. In addition, a previously unsuspected relationship between artwork dimensions and Archibald prize winners was found. As well as purchasers’ preferences, the artists’ choices of the dimensions of their artworks are considered.  相似文献   

8.
The Benedictine monastic community at New Norcia, Western Australia needed an assessment of their historic textile collection as a preliminary step in gaining financial support to preserve the garments. The textiles were grouped according to functional use with sampling controlled by random number generation of the registers. The highest significance and conservation rankings were rated at 5 and the lowest in the categories was given values of one. The numbers in each category fell logarithmically as the significance values increased. The number of hours of work required to stabilise the objects increased logarithmically as the conservation ranking increased from 1 to 5. Analysis of the conservation needs indicated that nearly 84% of the collection, the sum of the level 1 and level 2 textiles can be stabilised with simple preventive conservation methods practised by trained volunteers, leaving the most significant items in the care of experienced conservators. Multiplication of the conservation and the significance values provides a treatment priority score to guide collection managers in determining which objects are treated by conservators. Data is also provided on the impact of light exposure on the deterioration of the coloured fabrics of the vestments.  相似文献   

9.
The need of inspecting a masterpiece of fine art without affecting it led to develop non destructive methods of investigation. In the field of art conservation, several diagnostic techniques are being widely used to inspect works of art, giving different but complementary results. The present work deals with two of these methods, reflectography and thermography, both techniques examining objects in the infrared spectrum but in different wavelength bands. Their integrated data potentially provide a powerful tool for mapping hidden features and alterations of artworks. This was confirmed during the inspections of a 13th century panel painting under restoration at the Opificio delle Pietre Dure laboratories (Florence, Italy). A graphical user interface was also designed to aid operators in the field of conservation dealing with the results of the two IR methods. Many options such as image adjustment, comparison, overlaying and transparency variation, in addition to thermographic elaborations, have been made available to users. Imaging data integration provides a multi-layered and multi-spectral representation of the painting that yields a comprehensive diagnosis confirms the anomalies individuation and reduces the ambiguities of information coming from a single diagnostic method.  相似文献   

10.
The European project Friendly-Heating (FH): comfortable to people and compatible with conservation of artworks preserved in churches addressed the problems caused by the continuous or intermittent heating of historic churches, which disturbs the microclimatic conditions to which the building and the artworks preserved inside have acclimatised. As thermal comfort and the preservation of artworks often conflict with each other, a balance between the two needs is necessary. The proposed heating strategy is to provide a small amount of heat directly to people in the pew area while leaving the conditions in the church, as a whole, undisturbed. This novel heating system is based on some low-temperature radiant emitters mounted in a pew to provide a desirable distribution of heat to the feet, legs and hands of people occupying it. Due to little heat dispersion, this novel system not only significantly reduces the risk of mechanical stress in wooden artworks and panel or canvas paintings, fresco soiling and cyclic dissolution-recrystallization of soluble salts in the masonry, but is energy-efficient. The detailed environmental monitoring was conducted in the church of Santa Maria Maddalena in Rocca Pietore, Italy over a 3-year period to verify the performance of the novel heating system in comparison to the warm-air system that was active earlier in the church. The methodology and results of this comprehensive and multidisciplinary study were included in three draft standards of the European Committee for Standardisation intended for use in the study and control of environments of cultural heritage objects.  相似文献   

11.
The preservation of early 20th century, late 19th century albumen prints is of great concern to collection managers and conservators of photographic materials. Attenuated Total Reflection Fourier Transform Infrared (ATR-FTIR) spectroscopic imaging is presented for the first time as analytical methodology for the study of albumen photographs. This paper shows the feasibility of obtaining FTIR images of samples from albumen photographs with a high spatial resolution using a Ge ATR objective coupled with an infrared microscope. The improved spatial resolution compared to FTIR images obtained by the reflection method is due to the high refractive index of the ATR crystal, which gives a high numerical aperture and hence, a higher spatial resolution. The technique reveals detailed information on the organic functional group distribution in the individual layers of embedded cross sections and is used complementary to visual microscopy and scanning electron microscopy/energy dispersed X-ray spectroscopy. The main results of the study are discussed with regard to their historical and artistic significance, and they are compared with data from historical and conservation literature.  相似文献   

12.
Albert Namatjira (1902–1959), Emily Kame Kngwarreye (c1910–1996) and Rover (Julama) Thomas (c1926–1998) are three of Australia’s best-known Indigenous artists. Each is known for one style of painting—Namatjira for watercolor on paper, Kngwarreye for acrylic (synthetic polymer) on canvas and Thomas for natural earth pigments on canvas. We estimate a sample selectivity model using data from the Australian Art Sales Digest to study the determinants of sales and the hammer price of artworks offered at auction from these artists. The results show that pre-sale information on the artwork and auction effects are significant and that the three artists studied are very different from each other. Thus, data should not be pooled when estimating these models.  相似文献   

13.
This article illustrates a preventive conservation methodology for wooden collections and objects based on the respect of the historic climate, as established by the European standard EN 15757:2010. This requires the knowledge of the past indoor climate that should be kept unchanged in the present and the future, because discontinuities would be noxious for conservation. To this aim, a very vulnerable object, i.e. a wooden inlay bookcase cabinet built by G.M. Platina in 1477 AD has been considered. The paper illustrates the methodology used to reconstruct the historic climate, i.e. with proxy data from 1500 to 1715 and from 1716 to 2009 with instrumental observations. For the present, the indoor climate of the exhibition room and the cabinet response have been investigated to remove the perturbing factors that are damaging the cabinet. For the future, the ENSEMBLES model has been used for a probabilistic forecast of the temperature and humidity over the next century, the sustainability and the potential risk for conservation connected with the expected climate change. This research constitutes an example of a novel methodology based on the relevance of the Historic climate, and includes a synergistic effort of climatologists, material scientists and conservators, to be applied for preventive conservation and to evaluate and face the negative impact of the expected climate change.  相似文献   

14.
This paper describes some results from an experiment carried out regarding a procedure to be adopted for temperature and R.H. monitoring of indoor spaces designed for exhibiting events, such as museums and similar institutions. The monitored data employed in this study has been collected by the Department di Ricerche Energetiche ed Ambientali of the Università degli Studi di Palermo in co-operation with the Regional Gallery ''Palazzo Abatellis'' of Palermo. The study analyses a simple method for characterising the environmental quality of museums so as to ensure the optimal conservation of works of art. This methodology is based on the procedure (where thermal and hygrometry parameters are concerned) proposed by an Italian standard rule. A new technique, firstly applied to the industrial environment, based on the passive reactive monitoring of proper coupons is also proposed for monitoring air quality in museums. The methodology adopted, has been applied to two survey campaigns which were carried out at a distance of 5 years. This shows the two aspects of thermal-hygrometry and levels of indoor air quality aimed at preserving works of art. The future developments of this work are oriented towards the definition of guidelines in support of those responsible for the conservation of works of art and improvements in the quality of environments for artwork conservation and for the comfort of visitors through the use of proper HVAC systems.  相似文献   

15.
A new possible methodology for recognizing the nature of gypsum in artworks, in particular for wall paintings, was developed. Calcium sulfate can be an alteration product of the calcium carbonate, or a component used by the Artist himself; the problem of identification of the presence and the nature of gypsum could be found detecting the presence of strontium. This element could be used as a marker since, differently from the alteration form, in mineral gypsum simultaneous presence of calcium and strontium occurs. The correlation between these two elements may be recognized using non-invasive in situ X-ray fluorescence measurements. In the present work, we tested this occurrence in various mineral samples of gypsum and alabaster as well in tempera, fresco and Egyptian paintings. Considering the new possible role of strontium indicating the presence of natural gypsum, we expect to provide a valuable tool for conservation scientists, restorers and art historians.  相似文献   

16.
To prevent the deterioration of artwork on stretched canvas in a museum, it is often necessary to neutralize the transmission of vibrations from sources such as the wall or the floor. An anti-vibratory system easily optimizes vibrations that are transmitted from the floor because the artwork's motion occurs in vertical translation. Hanging artwork, which receives vibrations from the wall, presents a more complex case because the motion consists of a translation and a rotation. This paper presents a model to determine a cutting frequency above which vibrations transmitted to the artwork are lowered. A procedure to obtain the parameters of this model is also presented. Experiments in a laboratory and in the Louvre Museum validate the predicted cutting frequency given by the model. A downloadable spreadsheet is available to apply this method to specific artwork.  相似文献   

17.
The present work was one of the first attempts to analyze the conservation status of two ferrotypes, ancient photographic plates realized on a support made of iron. The photographic material was constituted of collodion as binder for the photosensitive silver halides grains. The two ferrotypes studied belonged to a private collection of a family from Durham, UK, and were made at the end of the 19th century. The analytical techniques used for the morphological and physicochemical characterization were noninvasive. The surface morphology was studied by means of optical microscopy (OM) and environmental scanning electron microscopy (ESEM) coupled with an energy dispersive X-rays (EDX) system for the elemental analysis. These techniques, together with microreflectance Fourier transform infrared spectroscopy (μ-FTIR) and contact angle, allowed to obtain information on both the chemical – elemental – composition of the materials constituting the ferrotypes, and the conservation status of these photographic plates. The study showed that the physicochemical diagnostics allowed to characterize the two ferrotypes that, despite their similar age and provenance, showed different conservation status, surface properties, and elemental composition.  相似文献   

18.
We study the incentives that museums face in determining how much resources to invest in the protection of their artwork from theft. We present and analyze a game-theoretic model of art heists that accounts for the strategic interactions between museums’ and art thieves’ decisions and that incorporates several key features of the black market for stolen art. We find that the equilibrium level of security museums choose need not be monotonic in the true market value or the black market value of artwork, i.e., increasing the value of an art piece—whether it is the true market value or the black market value—does not necessarily lead museums to invest more in protecting their artwork. The effects of parameter changes in the model that reflect a shift of public policy depend critically on what type of policy change is considered. For instance, an increase in the penalty imposed for committing art theft cannot raise the amount of theft in equilibrium and could in fact lead museums to increase their level of security. On the other hand, investing more resources on law enforcement agencies so that they are better able to solve art crimes can actually increase the amount of theft in equilibrium by causing museums to spend less on security.  相似文献   

19.
The self-limiting effect during laser cleaning only occurs in a limited amount of specific applications in restoration (e.g. removal of black crust from white marble). In all the other cases, a control of the removal process will be necessary either by the operator himself or by the employment of sensor equipment. Various methods, mainly spectroscopic (e.g. LIBS), have been investigated and proposed by others. Despite the fact that these have been shown to be promising, they all have in common rather high investment cost close to that of the cleaning equipment. Furthermore, this highly sophisticated control equipment is not easy to handle by conservators in practice. As an alternative low-cost method, we employed a simple photodiode to detect the scattered light from the irradiation area on the artwork surface. In many cases, this signal contains several pieces of information on the layer just being removed. The scattered radiation detected by the photodiode originates from the laser-induced plasma as well as reflected laser radiation. A separation, if necessary in order to separate the information, is possible by spectral filters. First applications during laser cleaning of corroded metal, encrusted glass and stone were promising. It has turned out that there is a distinct influence on the scattered light amplitude or even the pulse-bandwidth once the laser has removed the encrustation completely. The corresponding signal can be used in a closed loop control or for online monitoring.  相似文献   

20.
Many whale (baleen whale or toothed whale) skeletons still contain residual lipids even after an initial osteological preparation. This paper examines the different possibilities of re-treatment. Before a conservation intervention, it was necessary to determine the materials of which bones are made up. The samples were analyzed by Raman spectroscopy. Different compounds were identified: a mineral part (apatite), an organic part (collagen) and lipids. Chromatography analysis yielded a detailed composition of the lipids. It was in fact degraded fat with saturated and unsaturated fatty acids. To remove these lipids, several techniques were identified and tested: enzymatic treatments, supercritical CO2, and green or organic solvents. Esterification catalyzed by lipases could be suitable for a degreasing treatment since the solubility of esters is higher than that of the corresponding fatty acids. The enzymatic treatment acted only on the surface and did not appear to be very efficient. The use of supercritical CO2 was even less effective. Some green solvents can partially extract lipids but prove difficult to eliminate after treatment. The best results for degreasing were achieved using organic solvents. Different solutions were evaluated at hot or ambient temperature and in simple immersion or with agitation (Soxhlet or pulsed pressure): hexane, heptane, a mixture of hexane/isopropanol, or an azeotropic mixture of methanol/chloroform. Only the mixture of methanol/chloroform succeeded in extracting the overall fat content, but this treatment degraded the organic part of the bones. The other organic solvents extracted mainly colored fat, which generally corresponded to a weight loss of 20 to 50%. The majority of fat was extracted during the first bath. Thus the treatment selected is that of immersion in heptane at ambient temperature. The degreasing of whole bones is less effective because of the film of sticky degraded fat on the bone's surface. A pre-cleaning is necessary to eliminate this film.  相似文献   

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