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1.
本文采用有限元方法对金刚石/铜复合材料的传热性进行数值模拟,建立多颗粒二维随机分布复合材料测试模型,研究金刚石颗粒体积分数、颗粒半径、颗粒形貌、粒径比及界面因素对金刚石/铜复合材料传热性能的影响规律及机制。结果表明:金刚石/铜复合材料的热导率随着金刚石体积分数的增大而升高;热导率随着粒径的增大而呈现先升高后降低的规律;方形金刚石颗粒的复合材料热导率高于球形颗粒的复合材料;在金刚石体积分数一定时,适量配比细颗粒可提高材料热导率;对金刚石表面镀覆层新物质(W、Cr、Ti)来等效金刚石和铜二者物理结合时的界面热阻。 相似文献
2.
Many layered superlattice materials intrinsically possess large Seebeck coefficient and low lattice thermal conductivity, but poor electrical conductivity because of the interlayer transport barrier for charges, which has become a stumbling block for achieving high thermoelectric performance. Herein, taking BiCuSeO superlattice as an example, it is demonstrated that efficient interlayer charge release can increase carrier concentration, thereby activating multiple Fermi pockets through Bi/Cu dual vacancies and Pb codoping. Experimental results reveal that the extrinsic charges, which are introduced by Pb and initially trapped in the charge-reservoir [Bi2O2]2+ sublayers, are effectively released into [Cu2Se2]2− sublayers via the channels bridged by Bi/Cu dual vacancies. This efficient interlayer charge release endows dual-vacancy- and Pb-codoped BiCuSeO with increased carrier concentration and electrical conductivity. Moreover, with increasing carrier concentration, the Fermi level is pushed down, activating multiple converged valence bands, which helps to maintain a relatively high Seebeck coefficient and yield an enhanced power factor. As a result, a high ZT value of ∼1.4 is achieved at 823 K in codoped Bi0.90Pb0.06Cu0.96SeO, which is superior to that of pristine BiCuSeO and solely doped samples. The present findings provide prospective insights into the exploration of high-performance thermoelectric materials and the underlying transport physics. 相似文献
3.
Honeycomb or triangular lattices were extensively studied and thought to be proper platforms for realizing the quantum anomalous Hall effect (QAHE), where magnetism is usually caused by d orbitals of transition metals. Here we propose that a square lattice can host three magnetic topological states, including the fully spin-polarized nodal loop semimetal, QAHE and the topologically trivial ferromagnetic semiconductor, in terms of the symmetry and k · p model analyses that are material independent. A phase diagram is presented. We further show that the above three magnetic topological states can indeed be implemented in the two-dimensional (2D) materials ScLiCl5, LiScZ5 (Z=Cl, Br) and ScLiBr5, respectively. The ferromagnetism in these 2D materials is microscopically revealed from p electrons of halogen atoms. This present study opens a door to explore the exotic topological states as well as quantum magnetism from p-orbital electrons by means of the material-independent approach. 相似文献
4.
应用分子动力学模拟的方法,研究了纳米金刚石颗粒的导热系数对温度和颗粒尺寸的依存关系。为了得到较为准确的模拟结果,采用了平衡态分子动力学模拟的方法。计算了较长时间的热流自相关函数,并得到了导热系数的收敛结果。结果表明,纳米金刚石颗粒由于尺寸的影响,导热系数低于体材料金刚石的导热系数;随温度的升高,导热系数出现一个峰值,该峰值点的温度小于体材料金刚石出现峰值点的温度;随颗粒尺寸的增大,导热系数增加,我们预测导热系数将在一定的颗粒尺寸时收敛于体材料金刚石的导热系数。 相似文献
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6.
《Journal of The Franklin Institute》1987,323(1):33-42
Landau's thermal stability analysis is extended to a slab material whose thermal conductivity varies linearly across the slab thickness. Two simple combinations of boundary conditions are applied, and appropriate critical parameters are determined, thus ascertaining the effect of varying thermal conductivity of the slab material. The critical solutions obtained in this study can be shown to closely approach, but not be exactly reducible to, Landau's solution for constant thermal conductivity. The knowledge of a Landau solution, however, gives credence to the present results selected from a multitude of critical solutions. 相似文献
7.
The six-membered ring (SMR) is a common structure unit for numerous material systems. These materials include, but are not limited to, the typical two-dimensional materials such as graphene, h-BN, and transition metal dichalcogenides, as well as three-dimensional materials such as beryllium, magnesium, MgB2 and Bi2Se3. Although many of these materials have already become ‘stars’ in materials science and condensed-matter physics, little attention has been paid to the roles of the SMR unit across a wide range of compositions and structures. In this article, we systematically analyze these materials with respect to their very basic SMR structural unit, which has been found to play a deterministic role in the occurrence of many intriguing properties and phenomena, such as Dirac electronic and phononic spectra, superconductivity and topology. As a result, we have defined this group of materials as SMR inorganic materials, opening up a new perspective on materials research and development. With their unique properties, SMR materials deserve wide attention and in-depth investigation from materials design, new physical discoveries to target-wizard applications. It is expected that SMR materials will find niche applications in next-generation information technology, renewable energy, space, etc. 相似文献
8.
Xinyuan Zhang Lina Li Chengmin Ji Xitao Liu Qing Li Kun Zhang Yu Peng Maochun Hong Junhua Luo 《国家科学评论(英文版)》2021,8(10)
Polarization-sensitive photodetection is central to optics applications and has been successfully demonstrated in photodetectors of two-dimensional (2D) materials, such as layered hybrid perovskites; however, achieving high polarization sensitivity in such a photodetector remains extremely challenging. Here, for the first time, we demonstrate a high-performance polarization-sensitive photodetector using single-crystalline 2D/3D perovskite heterostructure, namely, (4-AMP)(MA)2Pb3Br10/MAPbBr3 (MA = methylammonium; 4-AMP = 4-(aminomethyl)piperidinium), which exhibits ultrahigh polarization sensitivity up to 17.6 under self-driven mode. To our knowledge, such a high polarization selectivity has surpassed all of the reported perovskite-based devices, and is comparable to, or even better than, the traditional inorganic heterostructure-based photodetectors. Further studies reveal that the built-in electric field formed at the junction can spatially separate the photogenerated electrons and holes, reducing their recombination rate and thus enhancing the performance for polarization-sensitive photodetection. This work provides a new source of polarization-sensitive materials and insights into designing novel optoelectronic devices. 相似文献
9.
The effect of an electrical double layer (EDL) on microchannel flow has been studied widely, and a constant bulk electric conductivity is often used in calculations of flow rate or pressure drop. In our experimental study of pressure-driven micropipette flows, the pipette diameter is on the same order of magnitude as the Debye length. The overlapping EDL resulted in a much higher electric conductivity, lower streaming potential, and lower electroviscous effect. To elucidate the effect of overlapping EDL, this paper developed a simple model for water flow without salts or dissolved gases (such as CO2) inside a two-dimensional microchannel. The governing equations for the flow, the Poisson, and Nernst equations for the electric potential and ion concentrations and the charge continuity equation were solved. The effects of overlapping EDL on the electric conductivity, velocity distribution, and overall pressure drop in the microchannel were quantified. The results showed that the average electric conductivity of electrolyte inside the channel increased significantly as the EDL overlaps. With the modified mean electric conductivity, the pressure drop for the pressure-driven flow was smaller than that without the influence of the EDL on conductivity. The results of this study provide a physical explanation for the observed decrease in electroviscous effect for microchannels when the EDL layers from opposing walls overlap. 相似文献
10.
GaN材料在光电子和微电子领域中得到广泛的应用,因此它是第三代半导体材料的典型代表。它具有宽的直接带隙、强的原子键、高的热导率、化学稳定性好(几乎不被任何酸腐蚀)等性质和强的抗辐照能力,在光电子、高温大功率器件和高频微波器件应用方面有着广阔的前景。在成像技术方面,GaN类的成像器件包括紫外摄像机和紫外数字照相机。 相似文献
11.
Carbon-based nanomaterials such as graphene and nanodiamonds have demonstrated impressive physical and chemical properties, such as remarkable strength, corrosion resistance, and excellent electrical and thermal conductivity, and stability. Because of these unique characteristics, carbon nanomaterials are explored in a wide range of fields, including the diagnosis and treatment of viruses. As there are emerging concerns about the control of virus including Middle East respiratory syndrome virus (MERS), severe acute respiratory syndrome coronavirus (SARS-CoV), and severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2), this review highlights the recent development of carbon based-nanomaterials for the management of viral infections. 相似文献
12.
Chi Zhang Junyang Tan Yikun Pan Xingke Cai Xiaolong Zou Hui-Ming Cheng Bilu Liu 《国家科学评论(英文版)》2020,7(2):324
The scalable and high-efficiency production of 2D materials is a prerequisite to their commercial use. Currently, only graphene and graphene oxide can be produced on a ton scale, and the inability to produce other 2D materials on such a large scale hinders their technological applications. Here we report a grinding exfoliation method that uses micro-particles as force intermediates to resolve applied compressive forces into a multitude of small shear forces, inducing the highly efficient exfoliation of layer materials. The method, referred to as intermediate-assisted grinding exfoliation (iMAGE), can be used for the large-scale production of many 2D materials. As an example, we have exfoliated bulk h-BN into 2D h-BN with large flake sizes, high quality and structural integrity, with a high exfoliation yield of 67%, a high production rate of 0.3 g h−1 and a low energy consumption of 3.01 × 106 J g−1. The production rate and energy consumption are one to two orders of magnitude better than previous results. Besides h-BN, this iMAGE technology has been used to exfoliate various layer materials such as graphite, black phosphorus, transition metal dichalcogenides, and metal oxides, proving its universality. Molybdenite concentrate, a natural low-cost and abundant mineral, was used as a demo for the large-scale exfoliation production of 2D MoS2 flakes. Our work indicates the huge potential of the iMAGE method to produce large amounts of various 2D materials, which paves the way for their commercial application. 相似文献
13.
Ultrathin two-dimensional (2D) materials have attracted considerable attention for their unique physicochemical properties and promising applications; however, preparation of freestanding ultrathin 2D noble metal remains a significant challenge. Here, for the first time, we report use of a wet-chemical method to synthesize partially hydroxylated ultrathin Ir nanosheets (Ir-NSs) of only five to six atomic layers’ thickness. Detailed analysis indicates that the growth confinement effect of carbon monoxide and the partially hydroxylated surface play a critical role in formation of the ultrathin structure. The ultrathin Ir-NSs exhibit excellent performance for both the hydrogen evolution reaction and oxygen evolution reaction in a wide pH range, outperforming the state-of-the-art Pt/C and IrO2, respectively. Density-functional theory calculations reveal that the partial hydroxylation not only enhances the surface electron transfer between Ir-sites and intermediate O-species, but also guarantees efficient initial activation of bond cleavage of H-O-H for first-step H2O splitting. This, ultimately, breaks through barriers to full water splitting, with efficient electron transfer essentially maintained. 相似文献
14.
Abdul Aziz 《Journal of The Franklin Institute》2011,348(4):640-651
The homotopy analysis method (HAM) is applied to generate an analytic solution for heat transfer in a moving fin of variable thermal conductivity which is losing heat by simultaneous convection and radiation to its surroundings. The accuracy of the analytic solution is validated by comparing it with the direct numerical solution of the problem. The analytic solution is found to be accurate to at least three places of decimal for a wide range of values of the parameters that are commonly encountered in thermal processing application. Graphs displaying the results are interpreted in physical terms. 相似文献
15.
目的观察腰椎牵引配合电子热磁治疗仪治疗运功性腰肌劳损的疗效。方法选取68例运动性腰肌劳损病例,根据JOA制定的腰椎疾患疗效判断标准随机分为治疗组、对照组。两组均应用电脑控制腰椎牵引装置治疗,治疗组配合电子热磁治疗仪。结果根据JOA制定的腰椎疾患疗效判断标准评分计算治疗前后的改善率,统计学处理后进行比较。结论腰椎牵引配合电子热磁治疗仪在治疗运动性腰肌劳损较单一腰椎牵引治疗效果更佳显著。 相似文献
16.
一种改进的遥感热惯量模型初探 总被引：6，自引：0，他引：6
本文改进了遥感热惯量模型 ,考虑到植被因素的影响 ,在植被覆盖区 ,使用双层模型中的土壤热能量平衡方程 ,同时在热传导方程的边界条件中引进显热通量和潜热通量 ,使热惯量模型的应用范围从裸土扩展到植被覆盖区 .通过顺义地区的MODIS影像数据和同步野外测量数据对此模型进行验证 ,所获得的热惯量值与实测热惯量值进行比较 ,结果表明改进模型的实用性和可行性 . 相似文献
17.
Jiongzhao Li Weicheng Cao Yufei Shu Haibing Zhang Xudong Qian Xueqian Kong Linjun Wang Xiaogang Peng 《国家科学评论(英文版)》2022,9(2)
High-quality colloidal nanocrystals are commonly synthesized in hydrocarbon solvents with alkanoates as the most common organic ligand. Water molecules with an approximately equal number of surface alkanoate ligands are identified at the inorganic–organic interface for all types of colloidal nanocrystals studied, and investigated quantitatively using CdSe nanocrystals as the model system. Carboxylate ligands are coordinated to the surface metal ions and the first monolayer of water molecules is found to bond to the carboxylate groups of alkanoate ligands through hydrogen bonds. Additional monolayer(s) of water molecules can further be adsorbed through hydrogen bonds to the first monolayer of water molecules. The nearly ideal environment for hydrogen bonding at the inorganic–organic interface of alkanoate-coated nanocrystals helps to rapidly and stably enrich the interface-bonded water molecules, most of which are difficult to remove through vacuum treatment, thermal annealing and chemical drying. The water-enriched structure of the inorganic–organic interface of high-quality colloidal nanocrystals must be taken into account in order to understand the synthesis, processing and properties of these novel materials. 相似文献
18.
Ce Huang Awadhesh Narayan Enze Zhang Xiaoyi Xie Linfeng Ai Shanshan Liu Changjiang Yi Youguo Shi Stefano Sanvito Faxian Xiu 《国家科学评论(英文版)》2020,7(9):1468
WTe2, as a type-II Weyl semimetal, has 2D Fermi arcs on the (001) surface in the bulk and 1D helical edge states in its monolayer. These features have recently attracted wide attention in condensed matter physics. However, in the intermediate regime between the bulk and monolayer, the edge states have not been resolved owing to its closed band gap which makes the bulk states dominant. Here, we report the signatures of the edge superconductivity by superconducting quantum interference measurements in multilayer WTe2 Josephson junctions and we directly map the localized supercurrent. In thick WTe2 (, the supercurrent is uniformly distributed by bulk states with symmetric Josephson effect (). In thin WTe2 (10 nm), however, the supercurrent becomes confined to the edge and its width reaches up to and exhibits non-symmetric behavior . The ability to tune the edge domination by changing thickness and the edge superconductivity establishes WTe2 as a promising topological system with exotic quantum phases and a rich physics. 相似文献
19.
《国家科学评论(英文版)》2014,(1)
Hall efect is a well-known electromagnetic phenomenon that has been widely applied in the semiconductor industry.he quantum Hall efect discovered in two-dimensional electronic systems under a strong magnetic ield provided new insights into condensed mater physics,especially the topological aspect of electronic states.he quantum anomalous Hall efect is a special kind of the quantum Hall efect that occurs without a magnetic ield.It has long been sought ater because its realization will signiicantly facilitate the studies and applications of the quantum Hall physics.In this paper,we review how the idea of the quantum anomalous Hall efect was developed and how the efect was inally experimentally realized in thin ilms of a magnetically doped topological insulator. 相似文献
20.
Myoglobin is one of the premature identifying cardiac markers, whose concentration increases from 90 pg∕ml or less to over 250 ng∕ml in the blood serum of human beings after minor heart attack. Separation, detection, and quantification of myoglobin play a vital role in revealing the cardiac arrest in advance, which is the challenging part of ongoing research. In the present work, one of the electrokinetic approaches, i.e., dielectrophoresis (DEP), is chosen to separate the myoglobin. A mathematical model is developed for simulating dielectrophoretic behavior of a myoglobin molecule in a microchannel to provide a theoretical basis for the above application. This model is based on the introduction of a dielectrophoretic force and a dielectric myoglobin model. A dielectric myoglobin model is developed by approximating the shape of the myoglobin molecule as sphere, oblate, and prolate spheroids. A generalized theoretical expression for the dielectrophoretic force acting on respective shapes of the molecule is derived. The microchannel considered for analysis has an array of parallel rectangular electrodes at the bottom surface. The potential and electric field distributions are calculated using Green’s theorem method and finite element method. These results also compared to the Fourier series method, closed form solutions by Morgan et al. [J. Phys. D: Appl. Phys. 34, 1553 (2001)] and Chang et al. [J. Phys. D: Appl. Phys. 36, 3073 (2003)]. It is observed that both Green’s theorem based analytical solution and finite element based numerical solution for proposed model are closely matched for electric field and square electric field gradients. The crossover frequency is obtained as 40 MHz for given properties of myoglobin and for all approximated shapes of myoglobin molecule. The effect of conductivity of medium and myoglobin on the crossover frequency is also demonstrated. Further, the effect of hydration layer on the crossover frequency of myoglobin molecules is also presented. Both positive and negative DEP effects on myoglobin molecules are obtained by switching the frequency of applied electric field. The effect of different shapes of myoglobin on DEP force is studied and no significant effect on DEP force is observed. Finally, repulsion of myoglobin molecules from the electrode plane at 1 KHz frequency and 10 V applied voltage is observed. These results provide the ability of applying DEP force for manipulating nanosized biomolecules such as myoglobin. 相似文献