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1.
The application of a new class of organogels as cleaning tools for painted surfaces is described. It combines some of the most attractive features of cleaning liquids and normal gels while diminishing the deleterious characteristics of both. Thus, the ‘latent’ gellant, polyethyleneimine (PEI), reacts with CO2 at room temperature in solutions of several organic liquids to produce an ammonium carbamate form (PEICO2). This charged species organizes itself into 3D polymer networks which immobilize the liquids as gels. The properties of the original solution (i.e. a free-flowing liquid) are re-established immediately after addition of a small amount of a weak acid which displaces the CO2 molecules and makes the PEI chains positively charged. The visual changes are substantiated by rheological analyses. Results from analytical tests to determine the utility of these gels as cleaning tools for painted surfaces of historical and artistic interest, have been obtained from contact angle and FTIR measurements as well as visual comparisons of the surfaces before and after application of the gels. The analyses indicate that the PEICO2-based organogels were very effective in removing different surface patinas from painted supports. A surface layer of dammar was completely removed from a test canvas with oil paint, an aged painting from the XIX century, and a XV century oil-on-wood panel attributed to Mariotto di Cristoforo. Finally, a surface acrylic polymeric resin (used in a restoration performed during the 1960s) was also successfully removed from Renaissance wall paintings decorating the Santa Maria della Scala Sacristy in Siena, Italy. The isothermally rheoreversible gel approach described in this work represents a new, highly versatile, and very efficient method for removing aged surface patinas from works of art.  相似文献   

2.
The source of the previously unassigned weak band at 2340 cm−1 that is occasionally observed in the infrared spectrum of natural lapis lazuli pigment is here attributed conclusively to CO2 trapped in the β-cage of lazurite. In addition, the geo-sourcing potential of this infrared feature for lapis lazuli is tested and found to be more ambiguous than previously suggested. The CO2 absorption band is in fact observed in lapis lazuli samples from numerous disparate geographic locales including Afghanistan, Canada, Myanmar, Siberia, Tajikistan, and the Ural Mountains, as well as mineral hauyne samples from Germany and Italy. The spectral feature was absent from lapis lazuli samples from California, Chile, Colorado, and New York. Furthermore, poor quality lapis lazuli samples, regardless of locale, highly processed natural pigment samples, and all samples of synthetic ultramarine blue, green, and violet pigments were devoid of encapsulated CO2.  相似文献   

3.
沙舟 《文化交流》2009,(2):34-36
杭州西湖北山有个黄龙洞，历史上是南宋护国寺的道场。当年这里的住持和尚、一代高僧无门慧开曾在此向其东瀛弟子传授佛法和“尺八”演奏技艺，是中日佛教和音乐交流的圣地。那时的黄龙洞曾经是梵呗绕梁、清音袅袅。岁月荏苒，这方洞府灵山注定与艺术结缘。新中国成立后，这里又成了我省最高艺术学府浙江职业艺术学院的前身——浙江省艺术学校的所在地。  相似文献   

4.
The painting Il ritratto della figliastra (Portrait of the Stepdaughter) by Giovanni Fattori (1889, Gallery of Modern Art, Pitti Palace, Florence) was investigated using non-invasive fibre optics reflectance spectroscopy (FORS). The use of compact and transportable instrumentation made it possible to easily record spectra of the polychrome surface at the restorer’s atelier during the restoration work. The results of colour analysis before and after the cleaning procedure of the painting are reported and discussed, together with an attempt at pigment identification.  相似文献   

5.
The Sos Furrighesos necropolis (Anela) is considered to be one of the most important funerary monuments in Sardinia. The hypogeum consists of various graves, called Domus de Janas, which are decorated with Neolithic mural paintings and sculptures. This work was undertaken in order to clarify which techniques were used in the past, through the identification of pigments and binding media. The samples, scraped off from the paint surface, were studied by using various analytical techniques in order to characterise both the pigments and the binding media. The main problems concerning the characterisation were due to the small sizes (1–5 mg) of the samples and their complex nature. As regards pigments, X-ray diffraction and scanning electron microscopy-energy dispersive X-ray spectrometry analyses were performed on the samples. These techniques are well suited to the characterisation of inorganic pigments and have led to the identification of the red pigment as haematite. In order to characterise the organic binders, the samples were analysed by a procedure based on a gas chromatography–mass spectrometry technique, which allows proteinaceous and lipidic media determination in the same sample. In most of the samples, the presence of egg was suggested.  相似文献   

6.
Limestone and marble, still frequently used as building materials are especially vulnerable to the destructive effects of efflorescence. The effect of interaction between five different calcareous stones and corrosive atmospheres has been investigated. A novel technique of stone degradation analysis has been used where thin sections of fresh stone materials were exposed in a corrosion chamber under controlled conditions (temperature, relative humidity (RH), SO2 and NO2 concentration). Following 1-week’s exposure; observations of the initial crystallisation were studied by light microscopy, scanning electron microscopy (SEM) with energy dispersive X-ray analysis (EDX) and X-ray diffraction (XRD). The results obtained from the surface analysis clearly showed sulphation of the samples and formation of gypsum. Observations of the initial corrosion indicated differences in the location of efflorescence and its shape among and within the samples. The mineralogy, grain shape and size, mineral defects and existence of cracks and pores, all influenced the substrate’s reactivity. The most vulnerable areas and the places where the corrosion started on the calcitic stones were the triple grain junctions followed by grain boundaries, and on the dolomitic marble cracks and pores.  相似文献   

7.
The binding media of the polychromy of Qin Shihuang's Terracotta Army   总被引：2，自引：0，他引：2  
The “Terracotta Army” is a worldwide known archaeological finding in China. It is a part of the burial complex of the emperor Qin Shihuangdi (259–210 BC), which is still under excavation and study. The fact that the sculptures, chariots and weapons of the First Chinese Emperor's Terracotta Army were originally all painted in bright colours is still not widely known. The chemical characterisation of the paint medium was performed through an analytical procedure based on GC-MS. The proteinaceous binder was identified for the first time through a desalting procedure used in proteomics. The identification of egg as a paint binder is extremely interesting in terms of the historical significance of the work of art itself and important in terms of the method of conservation. Moreover it represents one of the first steps towards an understanding of the painting technique used on ancient sculptures in China, of which – despite their fame – nothing is yet known.  相似文献   

8.
The Saadian tombs from the era of sultan Ahmed al-Mansour (1574–1603) are beautifully decorated and have always been a major attraction for visitors to Marrakesh. The central mausoleum, named the Hall of Twelve Columns, encloses the tombs of Ahmed al-Mansour and his family. The hall has a huge vaulted ceiling, carved cedar doors, opening windows with wooden marquetry screen (Mashrabiya), and grey Italian marble columns. This paper presents the first attempt to identify the organic materials used by the Moroccan artisans. A GC/MS analytical procedure was used for the characterization of lipids, waxes, resins, pitch, tar, proteinaceous and saccharide materials in the same paint micro-sample. The analytical study identified the organic materials used in the polychrome and gilded decorations of the walls, ceiling and dome of the hall. Data showed that the polychrome decorations were painted using animal glue as a binder, and highlighted the treatment of the wall surface with linseed oil and the retouching of the paintings based on a saccharide binder. The use of a proteinaceous-resinous-oil mixture, applied on a proteinaceous preparation layer, for the gilded decorations revealed a very similar technique to that used at the time in Europe for mural paintings.  相似文献   

9.
A new possible methodology for recognizing the nature of gypsum in artworks, in particular for wall paintings, was developed. Calcium sulfate can be an alteration product of the calcium carbonate, or a component used by the Artist himself; the problem of identification of the presence and the nature of gypsum could be found detecting the presence of strontium. This element could be used as a marker since, differently from the alteration form, in mineral gypsum simultaneous presence of calcium and strontium occurs. The correlation between these two elements may be recognized using non-invasive in situ X-ray fluorescence measurements. In the present work, we tested this occurrence in various mineral samples of gypsum and alabaster as well in tempera, fresco and Egyptian paintings. Considering the new possible role of strontium indicating the presence of natural gypsum, we expect to provide a valuable tool for conservation scientists, restorers and art historians.  相似文献   

10.
The use of numerical simulation methods for the Cultural Heritage is of increasing importance for the analysis, conservation, restoration and appreciation of works of art. This is particularly important when their preservation and planned maintenance is the primary aim. Today museums, and particularly historical buildings converted to museums, should be considered as places where precious artefacts should have first-rate protection and conservation. It is a question of solving the compromise between protection, conservation and comfort for works of art and/or visitors, with the consequence that preservation and planned maintenance criteria must prevail over use requirements. Refurbishment and conservation of a building, and requirements for visitor presence and works of art need different thermo-physical indoor parameter values. The present paper concerns the thermal and air velocity analysis of the Salone dei Duecento (the Hall of the Two Hundred of the Palazzo Vecchio (Old Palace)) in Florence. In this paper an appropriate transient 3D model by Computational Fluid Dynamics (CFD) software based on the finite element method (FEM) was used. Variations and interaction between indoor and outdoor microclimatic conditions, and thermo-physical behaviour of the building connected to lighting, visitor presence and cooling–heating fan coils system were considered. The 3D modelling method provided by the present paper can be applied to several situations where there is interaction between outdoor and indoor climate variations and the building structure. It can be very useful for defining measures to preserve tapestries, understanding deterioration processes, and developing new conservation techniques and strategies for care and exhibition.  相似文献   

11.
Land Artists and Art Markets   总被引：1，自引：1，他引：0  
This paper focuses on the relations of land artists to the art market.As landworks are by their very nature site specific, what is sold is mostoften the documentation of the project. This paper examines whether there isa market for Land Art and if so, whether it shares the same characteristicsas markets for Minimal and Conceptual Art, which started at about the sametime. Data collected on auctions over the period 1972–1992, show thatthis market is very thin. This was probably realized by Land artists wholater seem to have turned to more marketable creations.  相似文献   

12.
Dhruv Raina 《Minerva》1996,34(2):161-176
Conclusions The centre-periphery relationship historically structured scientific exchanges between metropolis and province, between the fount of empire and its outposts. But the exchange, if regarded merely as a one-way flow of scientific information, ignores both the politics of knowledge and the nature of its appropriation. Arguably, imperial structures do not entirely determine scientific practices and the exchange of knowledge. Several factors neutralise the over-determining influence of politics—and possibly also the normative values of science—on scientific practice.In examining these four examples of Indian scientists in encounters with their peers at the centre, exceptional scientists are seen in a social context where the epistemology of science supposedly describes its practice. Imperialism imposes practices and patronage, which moderate the exchange of scientific knowledge. But, at Level Two, the politics of knowledge and the patterns of patronage within it mediate exchanges between the centre and the periphery.The first step in reconfiguring exchanges between centre and periphery —in this case, between Europe and India during the period 1850 to 1930— is to recognise the relation between the acquisition of resources and the maintenance of legitimacy and identity.67 Political life is not confined to the core of political institutions.68 Second, in examining science as practised in the colonies, it is necessary to see stages of scientific institutions, whose development structures the exchange.From the encounter of Ramchandra and De Morgan, it is evident that the centre-periphery framework should be separated from the models of transmission embedded within it. The notion of translation helps to suggest that scientists bring personal motives and meanings to each encounter. Ramchandra, for example, sought a novel method of teaching Indians calculus, while De Morgan's interest lay in finding a place for algebra in a liberal education.The hierarchy inherent in the centre-periphery framework compels the conclusion that, at Level Two, the autodidact outside the institutions of science must have his work presented to scientists at the centre by authoritative figures from the centre. This is not mainly a question of imperialism, but rather of patronage. The peripheral scientist could not be granted direct entry into the collegial circle until his efforts at the periphery could be translated into the language and concerns of the central community. Ramanujan's enigmatic formulas were translated into the language of analysis by Hardy, which enabled the creation of a field to which Hardy was committed.Scientists from the periphery who were already part of the circle by virtue of their training, were not necessarily subject to the same degree of attestation as other scientists from the periphery. P.C. Ray, with his DSc from Edinburgh, and his position at Calcutta University, had less difficulty in winning the trust of colleagues at the centre, even when he returned to India. On the contrary, remaining at the periphery, he moved from a context of patronage to a sphere of competition. In addition, Ray's collegiality, even at Level Two, was more comprehensive, and connected him with Level One.Eventually, the professional Indian science graduate found collegiality within the international community of scientists. Saha's self-imposed progressive nationalism constrained his identification with the centre and made him a potential competitor instead. Once having achieved eminence in the world of science, C.V. Raman and Saha shifted their work to journals of physics published in India in order to further the cause of physics research in their own country.69 To go beyond the limitations of the centre-periphery model, it is necessary not merely to examine exchanges between scientists functioning in a shared epistemological universe,70 but also to recognise the part played by institutions, the experience of colonialism, and the forms of patronage characterising both colonialism and science. Put another way, although there is relative epistemological autonomy within the disciplinary research communities of science, the interplay between knowledge and power structures this exchange.The scientific links between colonial India and Britain at the turn of the century were mediated by structures which prefigured change. Does structure determine all? If it does, we are left with an Orientalist reconstruction of the docile native, and a passive cultural medium into which science percolates. But this neglects the role of scientists in creating new structures within which they worked. A middle position—one more sensitive to the exigencies of colonial scientific life—would be one where the participants are seen not as the dupes of structure nor the potentates of action, but as occupying a ground between the two.71  相似文献   

13.
During the mid 1920s, the Spanish Government, prompted by the Rockefeller Foundation, began for the first time to support fundamental research in physics. The negotiations leading to this outcome are instructive, in reflecting key differences between the Foundation’s vision and the practices of scientists accustomed to a ‘culture of scarcity’. This paper shows how the Foundation and the Dictator of Spain, Miguel Primo de Rivera, tested the limits of ‘civil discourse’, and reached a resolution.  相似文献   

14.
The paper examines whether intellectual property rights in art should be extended to the entire world. In earlier papers, the economics of patent rights have been examined and the argument made that world welfare is likely to fall if patent rights are extended to the entire world. This argument is recapitulated here with special attention to the assumptions that are needed for its validity. These assumptions are then reexamined in the context of markets for art to see whether the argument carries over. It is found that while most of the assumptions do carry over well enough to justify the argument, there are also certain circumstances that may require greater geographic extension of intellectual property rights in some cases.Paper prepared for a conference on The Economics of Intellectual Property Rights, International Center for Art Economics, University of Venice, October 6–8, 1994.  相似文献   

15.
This paper examines Brazil’s Sector Funds, an emerging research and development policy that seeks to increase public-private research collaboration. The first section sets the context of the ‘policy problem’. The second section discusses the policy’s implementation, and discusses its likely implications for Brazil and beyond.  相似文献   

16.
The use of coloured pastes for inlaying marble and limestone wall panels is one of the ornamental techniques that were widely used during the Mamluk period in Egypt (1250–1516 AD). Red and black pastes from Qijmas El-Eshaqe mosque (1482 AD) in Cairo were studied to identify their main components. The study of the samples involved the identification of the pigments, additive materials and organic binding media. The study was performed using various analytical methods such as polarising microscopy (PLM), scanning electron microscopy equipped with energy dispersive X-ray analyser (SEM-EDX), inductively-coupled plasma (ICP-AES), X-ray diffraction (XRD) and Fourier-transform infrared spectroscopy (FTIR). These complementary analytical techniques provide precise identification of inorganic and organic substances used in the pastes. The results indicated that the red pigment is mainly obtained from red ochre containing hematite, whereas amorphous carbon (bone black and charcoal) was used to obtain the black colour. Both samples contain calcium sulphate, which was used to give some hardness to the pastes. Beeswax was used as an organic medium in both pastes. The study provides the information required for the conservation of the coloured paste ornaments.  相似文献   

17.
This paper examines the role of visitors’ clothing as a source of fibres and dust in museums. Some idealised experiments determined the mass of fibres and dust emitted from clothing and the range of particle sizes found. In chamber studies it was possible to examine the effect of different humidity and airflow on fibre release. Image analysis was used to determine particle size from sub-micron to giant particles including clothing fibre. Clothing was a significant contributor to fibre and dust generation and at low humidity winter garments composed largely of wool was especially large. High air velocity increased particle shedding from clothing. Clean clothing typically released a third to a tenth the weight of particulate material from dirty clothing. It is possible that the fibres and dust produced indoors from visitors could be reduced by an air-shower at the entrance, but less intrusive procedures such as keeping visitors at a distance from objects may be preferable.  相似文献   

18.
The scientific approach to the restoration and monitoring of mural paintings, at S. Girolamo Chapel – SS. Annunziata Church in Florence, is reported as a fruitful example of the synergic collaboration between restorers and scientists in the planning and development of conservative interventions. Before restoration, the painting technique and the state of preservation of the pictorial cycle have been investigated firstly by close examination of the painted surfaces and then by optical and/or SEM-EDS microscopy and μFT-IR spectroscopy on appropriately selected samples. In particular, the original constituent materials and those belonging to subsequent restorations were characterized together with those originating from decay processes. In this mural painting cycle, a peculiar “fresco” technique has been used although an auxiliary binder for pigment distemper has been also employed. The use of this technique, sometimes in an improper way together with uncorrected restoration interventions, are the main responsible of the unsatisfactory state of conservation of many painted areas. Preliminary conservation trials and scientific studies were carried out to design the most convenient restoration intervention and to verify the correctness and non-invasive of the necessary operations. Special attention was devoted to cleaning procedures, continuously monitored by a physico-chemical methodology, mainly based on microinvasive, microscopic and spectroscopic investigations, to evaluate the efficiency, advantages and drawbacks of the proposed cleaning procedures and define the most appropriate ones. Finally, specific decay markers have been recognized, by a comparison of the results obtained from the detached samples with those deriving from artificially aged models, to be used for a correct future monitoring and maintenance of the wall paintings.  相似文献   

19.
Past studies on art investment generally have found that returns are low and risk is high. In this study we find that the return to art investment is more in line with traditional investments and thus the cost for consumption associated with art seems fairly small. Employing a large sample of paintings by 66 American artists sold at auction between 1971–1992, average returns are found to be over 9 per cent and 3 per cent in nominal and real terms, respectively. The model employs a log linear price regression estimated by pooled cross section and time series data, and allows rates of return as well as hedonic values for various painting and auction attributes to be estimated. These include size, media, age of execution, authenticity of the work, and auction month and house. In addition, rates of return are differentiated by artist, time period of investment, price range and genre of the painting. The findings indicate significant sensitivity of rates of return to these data stratifications.This paper was presented at the 9th international conference of the Association for Cultural Economics, held in Boston, May 8–11, 1996.  相似文献   

20.
In a 1995 representative survey, 1,080 Germans were asked by standardized questionnaire to assess the subjective significance of 23 motives and barriers to visiting art museums, history museums and technology museums on a scale from 1 (very unimportant motive/barrier) to 5 (very important motive/barrier). An analysis of the results of the survey revealed entrance fees to be the only significant subjective barrier. In contrast to recent price elasticity studies of cultural demand, this study uses a micro-level approach – comparing individual socioeconomic and geographic characteristics with individual and subjective assessments of museum entrance fees as a barrier. The results of an ordered-probit analysis suggest income to be the only significant individual characteristic which can explain this subjective assessment. However, using correspondence analysis, several other individual characteristics such as education and professional status also appear to have a relative impact on the subjective assessment of entrance fees.  相似文献   

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