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1.
Single crystal Ga x In1−x As films have grown up on GaAs(100) substrate at 375°C and on InP(100) substrate at 390°C, respectively, by the method of rf-sputtering with using undoped GalnAs polycrystal as target. However, on Si(100) or Si(111) substrates at 260–390°C, even at 465°C, only polycrystalline films were obtained. In addition, the structure, composition, electrical characteristic and optical properties of the Ga x In1−x As films were investigated using X-ray diffraction (XRD), reflection of high energy electron diffraction (RHEED), energy dispersion analyzer of X-ray (EDAX), Hall measurements and spectroscopic ellipsometry.  相似文献   

2.
High resistance thin film chip resistors(0603 type) were studied,and the specifications are as follows:1 k? with tolerance about ±0.1% after laser trimming and temperature coefficient of resistance(TCR) less than ±15×10-6/℃.Cr-Si-Ta-Al films were prepared with Ar flow rate and sputtering power fixed at 20 standard-state cubic centimeter per minute(sccm) and 100 W,respectively.The experiment shows that the electrical properties of Cr-SiTa-Al deposition films can meet the specification requirements of 0603 type thin film chip resistors when the deposition time was about 11 min and deposition films were annealed at 500 ℃ for 120 min.The morphologies of Cr-Si-TaAl film surfaces were examined by scanning electron microscopy(SEM).The analysis suggests that Ta and Al may be distributed in CrSi2 film with mixed form of several structures(e.g.,bridge-like,capillary-like or island-like structures),and such a structure distribution is responsible for high film resistance and low TCR of Cr-Si-Ta-Al film.  相似文献   

3.
MBE growth of ZnSxSe1−x thin films on ITO coated glass substrates were carried out using ZnS and Se sources with the substrate temperature ranging from 270°C to 330°C. The XRD σ/2σ spectra resulted from these films indicated that the as-grown polycrystalline ZnSxSe1−x thin films had a preferred orientation along the (111) planes. The evaluated crystal sizes as deduced from the FWHM of the XRD layer peaks showed strong growth temperature dependence, with the optimized temperature being about 290 °C. Both AFM and TEM measurements of these thin films also indicated a similar growth temperature dependence. High quality ZnSxSe1−x thin film grown at the optimized temperature had the smoothest surface with lowest RMS value of 1.2 nm and TEM cross-sectional micrograph showing a well defined columnar structure. Project supported by the National Science Council of PRC (No. 59910161981) and RGC grant from the Hong Kong Government under Grant (No. NS-FC/HKUST 35)  相似文献   

4.
Amorphous InGaZnO (a-IGZO) film is deposited on the glass substrate by radio-frequency sputtering and the influence of annealing on wet etch of a-IGZO films were investigated. The results show that etch rate of IGZO films decrease with the increase of annealing temperature. Etching taper angle is less than 60° and critical dimension (CD) loss is less than 1 μm in over-etching time of 30 s. The fact implies that IGZO films etching with oxalic acid may be a good wet etching way for the thin-film transistor (TFT) array process.  相似文献   

5.
Chemically processed Nb-doped SrTiO3 films and properties   总被引：1，自引：0，他引：1  
Homogeneous, crack-free SrNbxTi1−x O3 thin films on (110) silicon substrates were successfully fabricated by sol-gel processing. The optimum route and conditions were systematically investigated. Sr(OAc)2 glacial acctic acid solution, after being refluxed and reacted with tartrate, formed Sr(OAc)2(C4H6O6)2; Ti(OBu)4 formed Ti(OAc)4−x (AcAc)x after having the ligand partially exchanged with AcAc, while Nb(OC2H5)5 formed (OAc)2Nb(AcAc) (C4H6O6) by exchanging of ligand in glacial acetic acid with (CH3CO)2O. All the metal species after undergoing partial hydrolysis and polymerization with hydroxyl or oxygen, formed SrNbxTi1−x O13 cluster sol. Methyl cellulose (MCL) caused SrNbxTi1−x O3 sol to have polymeric structure and easily form films. SrNbxTi1−x O3 films with perovskite were subsequently formed after being annealed at 650∼750 °C for 60 min in 25% N2+75% H2 (volume ratio) atmosphere. Resistivity of the SrNb0.1Ti0.9O3 films at room temperature was 64 μω·cm, a particular T 2 temperature dependence of the resistivity, from 25 K up to room temperature, was observed. Project (No. 2002CB613305) supported by the National Basic Research Program (973) of China  相似文献   

6.
Osteochondral allografting has been proved to be a useful method to treat diseased or damaged areas of joint surfaces. Operational long-term stocks of grafts which supply a buffer between procurement and utilization would contribute to the commercialization or industrialization of this technology. Vitrification has been thought to be a promising method for successful preservation of articular cartilage (AC), but high concentration cryoprotectants (CPAs) are used which may cause high cellular toxicity. An effective way to reduce CPA toxicity is to increase CPA concentration gradually while the temperature is lowered. Understanding the mechanism of CPA permeation at subzero temperatures is important for designing the cryopreservation protocol. In this research, the permeation of dimethyl sulfoxide (Me2SO) in ovine AC at subzero temperatures was studied experimentally. Pretreated AC discs were exposed in Me2SO solutions for different time (0, 5, 15, 30, 50, 80, and 120 min) at three temperature levels (−10, −20, and −30 °C). The Me2SO concentration within the tissue was determined by ultraviolet (UV) spectrophotometry. The diffusion coefficients were estimated to be 0.85×10−6, 0.48×10−6, and 0.27×10−6 cm2/s at −10, −20, and −30 °C, respectively, and the corresponding activation energy was 29.23 kJ/mol. Numerical simulation was performed to compare two Me2SO addition protocols, and the results demonstrated that the total loading duration could be effectively reduced with the knowledge of permeation kinetics.  相似文献   

7.
RH和RH-KTB精炼过程中钢液流动和混合特性的研究   总被引：7，自引：0，他引：7  
The flow and mixing characteristics of molten steel during the vacuum circulation refining,including RH(Ruhrstahl-Heraeus) and RH-KTB(Ruhrastahl-Heraeus-Kawasaki top blowing) processes,were investigated on a 1/5 linear scale water model of a 90t multifunction RH degasser,The circulation rate was directly and more accurately determined,using a new method by which the more reliable results can be obtained.The fluid flow pattern and flow field in the ladle were demonstrated,observed and analyzed.The mixing time of liquid in the ladle was measured using electrical conductivity method.The residence time distribution in the RH model was obtained by tracer response technique.The influence of the main technological and geometric factors,including the gas top blowing*(KTB) operation,was examined.The results indicated that the circulation rate of molten steel in the RH degasser can be fairly precisely calculated by the formula:Q1p=0.0333Qg^0.26Du^0.69Dd^0.80(t/min),where Qg-the lifting gas flow rate(NL/min);Du and Dd-the inner diameters of the up and down-snorkels(cm),respectively.The maximum value of circulation rate of molten steel in the case of the 30cm diameters either of the up-and down-snorkels for the RH degasser(the “Saturated” rate) is approximately 31 t/min.the corresponding gas flow rate is 900NL/min.Blowing gas into the vacuum chamber through the top lance like KTB operation does not markedly influence the circulatory flow and mixing charateristics of the RH process under the conditions of the present work.There exist a major loop and a large number of small vortices and eddies in the ladle during the RH refining process.A liquidliquid two-phase flow is formed between the descnding stream from the down-snorkel and the liquid around the stream.All of these flow situation and pattern will strongly influence and determine the mixing and mass transfer in the ladle during the refining.The correlation between the mixing time and the stirring energy density is τmε^0.50 for the RH degasser.The mixing time rapidly shortens with an increase in the lifting gas flowrate.At a same gas flow rate,the mixing times with the up-and down-snorkel diameters either of 6 and 7cm are essentially same.The 30cm diameters either of the up-and down-snorkels for the RH degasser would be reasonalble.The concentration-time curve showed that three circulation cycles are at least needed for complete mixing of the liquid steel in the RH degasser.  相似文献   

8.
Luciferase from firefly lantern extract was immobilized on CNBr-activated Sepharose 4B. The kinetic properties of immobilized luciferase were extensively studied. TheK m′ for D-luciferin is 11.9 μmol/L, the optimum pH and temperature for Sepharose-bound enzyme were 7.8 and 25°C respectively. A luminescence fiber optic biosensor, making use of immobilized crude luciferase, was developed for assay of ATP. The peak light intensity was linear with respect to ATP concentration in range of 10−9–10−5 mol/L. A biological application was also demonstrated with the determination of serum ATP from rats bred in low versus normal oxygen environments.  相似文献   

9.
The structural characteristics and optical and electrical properties of molecular-beam-epitaxy (MBE) grown ZnS0.8Se0.2 thin films on indium-tin-oxide(ITO) glas substrates were investigated in this work. TheX-ray diffraction (XRD) results indicated that high quality polycrystalline ZnS0.8Se0.2 thin film grown at the optimized temperature had a prefered orientation along the (111) planes. The transmission electron microscopy (TEM) cross-sectional micrograph of the sample showed a well defined columnar structure with lateral crystal dimension in the order of a few hundred angstroms. Ultraviolet (UV) photoresponsivity as high as 0.01 A/W had been demonstrated and for wavelengths longer than 450 nm, the response was down from the peak response by more than 3 orders of magnitude. The thin ZnS0.8Se0.2 photosensor layer, with a wide energy gap and anisotropic electrical property, makes a transmission UV liquid crystal light valve (LCLV) with high resolution feasible. Project supported by the National Natural Science Foundation of China (No. 59910161981) and RGC grant from the Hong Kong Government Grant (No. NSFC/HKUST 35), China  相似文献   

10.
The micro-Raman method is a non-contact and non-destructive method for thermal conductivity measurement. To reduce the measurement error induced by the poor fit of the basic equation of the original micro-Raman method, we developed a new basic equation for the heat source ofa Gaussian laser beam. Based on the new basic equation, an analytical heat transfer model has been built to extend the original micro-Raman method to thin films with submicrometer- or nanometer-scale thickness. Experiments were performed to measure the thermal conductivity of dielectric thin films with submicrometer- or nanometer-scale thickness. The thermal resistance of the interface between dielectric thin films and their silicon substrate was also obtained. The obtained thermal conductivity of silicon dioxide film is 1.23 W/（m.K）, and the interface thermal resistance between silicon dioxide film and substrate is 2.35×10^-8 m^2.K/W. The thermal conductivity and interface thermal resistance of silicon nitride film are 1.07 W/（m.K） and 3.69×10^-8 m^2.K/W, respectively. The experimental results are consistent with reported data.  相似文献   

11.
INTRODUCTION Nitrogen oxide (NOx) is one of the main air pol- lutants found in the flue gases from chemical and power plants belching acid rain and photochemical smog. Over 90 percent of all man-made nitrogen ox- ides that enter our atmosphere are produced by the combustion of various fuels. Compared with the ad- vanced stage of SO2 gas removal technologies devel- opment, the removal of NOx gases is still in the initial stages of development as roughly 90 to 95 percent of NOx emitted i…  相似文献   

12.
Theaflavins (TFs) are the dimers of a couple of epimerized catechins, which are specially formed during black tea fermentation. To explore the differences among four main TF derivatives (theaflavin (TF1), theaflavin-3-gallate (TF2A), theaflavin-3′-gallate (TF2B), and theaflavin-3,3′-digallate (TF3)) in scavenging reactive oxygen species (ROS) in vitro, their properties of inhibiting superoxide, singlet oxygen, hydrogen peroxide, and the hydroxyl radical, and their effects on hydroxyl radical-induced DNA oxidative damage were systematically analyzed in the present study. The results show that, compared with (−)-epigallocatechin gallate (EGCG), TF derivatives were good antioxidants for scavenging ROS and preventing the hydroxyl radical-induced DNA damage in vitro. TF3 was the most positive in scavenging hydrogen peroxide and hydroxyl radical, and TF1 suppressed superoxide. Positive antioxidant capacities of TF2B on singlet oxygen, hydrogen peroxide, hydroxyl radical, and the hydroxyl radical-induced DNA damage in vitro were found. The differences between the antioxidant capacities of four main TF derivatives in relation to their chemical structures were also discussed. We suggest that these activity differences among TF derivatives would be beneficial to scavenge different ROS with therapeutic potential.  相似文献   

13.
1, 10-Phenanthroline (phen) was tested as a complexing agent for on-line preconcentration of iron on RP-C18 material in a microcolumn with flow injection coupled with flame atomic absorption spectrometer (FI-FAAS). The on-line formed Fe(II)-phen complexes were adsorbed on the C18 sorbent material. Various parameters affecting the on-line Fe(II)-phen complex formation and its subsequent adsorption in the microcolumn as well as its elution into the nebulizer of AAS were optimized. A 2.5×10−3 mol/L phen in 2% through the microcolumn for 30 s. The adsorbed Fe(II)-phen complexes in the microcolumn were eluted with ethanol in 10 s into the nebulizer of AAS. Ascorbic acid (5×10−4 mol/L) was added to the sample solution for the reduction of Fe(III) to Fe(II). A good precision (RSD=1.1%,n=10), high enrichment factor (19) and sample throughput (90 h−1) with detection limit (3σ) of 3 μg/L were obtained. The method was applied on standard reference materials (i. e. mussel and tomato leaves,) for iron determination and yielded results agreeing well with certified values. Project supported by the Zhejiang Provincial Natural Science Foundation of China and Zhejiang Environmental Protection Foundation From Pakistan Institute of Nuclear Science & Technology, Islamabad, Pakistan and now ZJ University, Ph. D. student.  相似文献   

14.
Acoustic wave propagation in piezoelectric crystals of classes?43m and 23 is studied. The crystals Tl3VS4 and Tl3TaSe4 (43m) of the Chalcogenide family and the crystal Bi12TiO20 (23) possess strong piezoelectric effect. Because the surface Bleustein-Gulyaev waves cannot exist in piezoelectric cubic crystals, it was concluded that new solutions for shear-horizontal surface acoustic waves (SH-SAWs) are found in the monocrystals using different electrical boundary conditions such as electri- cally “short” and “open” free-surfaces for the unique [101] direction of wave propagation. For the crystal Tl3TaSe4 with coefficient of electromechanical coupling (CEMC) Ke2=e2/(C×g)～1/3, the phase velocity Vph for the new SH-SAWs can be calculated with the following formula: Vph=(Va Vt)/2, where Vt is the speed of bulk SH-wave, Vt=Vt4(1 Ke2)1/2, Va=aKVt4, aK=2[Ke(1 Ke2)1/2-Ke2]1/2, and Vt4=(C44/ρ)1/2. It was found that the CEMC K2 evaluation for Tl3TaSe4 gave the value of K2=2(Vf–Vm)/Vf～0.047 (～4.7%), where Vf～848 m/s and Vm~828 m/s are the new-SAW velocities for the free and metallized surfaces, respectively. This high value of K2(Tl3TaSe4) is significantly greater than K2(Tl3VS4)～3% and about five times that of K2(Bi12TiO20).  相似文献   

15.
A bench-scale experiment for control of hydrogen sulfide (H2S) emissions was carried out continuously for nearly four months by using bio-trickling filter packed with ZX01 stuffing. The results suggested that the bio-trickling filter had proven excellent performance over substantial operational periods. Removal efficiency of H2S was nearly 100% when volumetric loading of the bio-trickling filter varied from 0.64 g/(m3·h) to 38.20 g/(m3·h) and metabolism products of H2S were mainly composed of SO42–. When inlet concentration of H2S was 250 mg/m3, the optimum gas retention time was 30 s and the optimum spray water flow rate was 0.005 9~0.012 L/(cm2·h). The bio-trickling filter had good ability to resist shock of high volumetric loading, and was not blocked during experiments for nearly four months during which resistance was maintained at relatively lower value, so that the bio-trickling filter need not carry out back washing frequently and can be operated steadily for long-term.  相似文献   

16.
1　Introduction　Ahugeamountofliteratureexistsonthestudyofi dentifyingtracemetalionsbymeansofspectropho tometry[1 3] ,fluorimetry[4 6 ] aswellas polarogra phy[7 9] ,whichhaveactiononlocatingtheendpointoftheindicatingreaction .Howeverbothspectropho tometryandfluorimetryareeasytobeinterferedbycolororprecipitation ,whilepolarographyhasanissueofmercurypollution .Thecatalyzingkineticanalysishasthecharacteristicsofhighsensitivityandspeedi ness.Oscillographicpotentiometryisasimpleintu itionisticanal…  相似文献   

17.
INTRODUCTION Monocrystalline SBN (Strontium barium nio-bium, SrxBa1?xNb2O6, denoted SBNx?100, where 0.25≤x≤0.75) solid solution, is currently being inves-tigated as potential material for many micro-device applications, such as piezoelectric infrared detectors, piezoelectric, electro-optic modulators, and holo-graphic storage (Koch et al., 1998), because SBN has one of the largest known linear electro-optic coeffi-cients (r33=1300 pm/V for SBN75), two orders of magnitude larger th…  相似文献   

18.
Well-cubic perovskite lanthanum aluminate (LaAlO3) film on (110) silicon substrate was fabricated by sol-gel method with corresponding inorganic salts. Lanthanum acetate and aluminum acetate glacial acetic acid solutions were prepared via ligand exchange starting from lanthanum nitrate hexahydrate and aluminum nitrate hexahydrate after being refluxed. (CH3CO)2O removed nitrates and the crystallized H2O completely, acetylacetone (AcAc) was partially bidentated with metallic ion of the metallic acetates and formed La(OAc)3−x (AcAc) x which were hydrolyzed into La(AcAc)3−x(OH) x by adding 10 ml 0.4% methyl cellulose (MCL) solution. The La(AcAc)3−x (OH) x , polymerizing and combining with MCL, formed the LaAlO3 sol precursor with heteropolymeric structure and formed film easily. The epitaxial LaAlO3 film on Si(110) substrate was crystallized after being annealed in thermal annealing furnace for 650–750 °C/30 min. The morphologies and microstructures were characterized. The refractive index of the LAO film was 1.942 to 2.007; the dielectric constant and the dissipation factors were estimated to be 23–26 and 2.1×10−4−2.4×10−4 respectively. Project (No. 2002CB613305) supported by the National Basic Research Program (973) of China  相似文献   

19.
With InCl3·4H2O being used as raw materials, the precursor of nano-sized In2O3 powder was prepared by hydrolysis, peptization and gelation of InCl3·4H2O. After calcination, nano-sized In2O3 powder was obtained. The powder was characterized by thermo-gravimetric and differential thermal analysis (TG-DTA), X-ray diffractometry (XRD) and transmission electron microscopy (TEM), respectively. Calculation revealed that the mean crystalline size increased with increasing the calcination temperature, but crystal lattice distortion rate decreased with the increasing in the average crystalline size. This indicated that the smaller the particle size, the bigger the crystal lattice distortion, the worse the crystal growing. The activation energies for growth of nano-sized In2O3 were calculated to be 4.75 kJ·mol−1 at the calcination temperature up to 500°C; and 66.40 kJ·mol−1 at the calcination temperature over 600°C. TEM photos revealed that the addition of the chemical additive (OP-10) greatly influenced the morphology and size of In2O3 particles.  相似文献   

20.
Ethene/norbornene copolymerization by the catalyst system [Me2Si(3-tertBuCp)(NtertBu)]TiCl2/MAO was investigated in detail at 30 °C, 60 °C, and 90 °C. A mass flow controller was used in this work to obtain kinetic data and investigate temperature's effects on activity, norbornene incorporation, copolymerization parameter, microstructure, glass transition temperature, and molar masses were described. High copolymerization valuesr ξ and high alternation are determined. The number of isotactic alternating sequences is much higher than that of the syndiotactic alternating sequences.  相似文献   

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