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1.
以H-(CH2)n-CN型同系物结构重复单元数值连续变化为模型假定,获得了描述该同系物凝聚型物理性质递变规律的数学表达式:P=(α0 α1n α2n^2)/(1-b2n^2).其中α0、α1、α2、b2均为常数,n为结构重复单元数值,P为同系物的凝聚型物理性质。通过非线性回归分析。得到回归方程。结果表明该同系物的凝聚型物理性质与重复单元数值之间满足上述关系式。显示优良的相关性。  相似文献   

2.
以直链环己烷同系物结构重复单元数值连续变化为模型假定,获得了描述直链烷烃同系物物理性质递变规律的 数学表达式:P= a+ b x n~c,其中 a、b、c均为常数, n为结构重复单元数值,P为直链烷烃同系物的物理性质。通过非线性 回归分析,得到回归方程,结果表明直链环己烷同系物的物理性质与结构重复单元数值之间满足上述关系式,且显示优 良的相关性。  相似文献   

3.
New University Entrance Examination新高考物化生⑤2007年高考生适用一、同系物的判断规律1.一差(分子组成差一个或若干个CH2)2.二同(同通式,同结构)3.三注意(1)必为同一类物质。(2)结构相似(有相似的原子连接方式或相同的官能团种类和数目)。(3)同系物间物理性质不同,化学性  相似文献   

4.
【试题 1】 有专家指出 ,喝醋或服用板蓝根能够预防非典型肺炎尚没有科学根据 ,而利用过氧乙酸(CH3C—O—O—HO)进行空气消毒和物体表面消毒则有一定的预防作用 .过氧乙酸是一种强氧化剂 ,性质不稳定 ,温度稍高即分解放出氧气 .(1 )使用过氧乙酸消毒 ,主要利用了它的氧化性 ,写出过氧乙酸分解的化学反应方程式        .(2 )写出一种过氧乙酸的同系物的结构简式         .【简析】  (1 )跟过氧化氢分解类比可写出过氧乙酸分解的化学方程式 :2CH3C—O—O—HO2CH3C—O—H +O2 O(2 )根据同系物概念可写出 :CH3—CH…  相似文献   

5.
正一、同系物与同系列易混淆概念辨析具有同一通式、结构和性质相似、相互间相差一个或几个某种原子团(如CH2)的一系列化合物属同系列。同系列中的各个化合物互为同系物。相邻同系物之间相有效期的原子团叫做同系差。易错点提醒(1)判断是否属于同系物的规律:一看结构是否相似,二看组成是否相差"—CH2—",以下是同学们特别容易理解错的一些观点:①结构必须相似(链状与链状相似,环状与环状相似,含有一个苯环与含一个苯环的  相似文献   

6.
一、选择题1.某蛋白质由n条肽链组成,相对分子质量为a,如果该蛋白质分子含有的氨基酸个数为c,则氨基酸的平均相对分子质量是A.a+18(c-n)c B.a-18c(c-n)C.c-18(c-n)a D.c+18a(c-n)2.现有一种“十二肽”,分子式为CxH yN zO w S(z>12,w>13)。已知将它彻底水解后只得到下列氨基酸:COOHCH—CH2SHNH2CH3CH—COOHNH2CH2—COOHCH—COOHNH2半胱氨酸丙氨酸天门冬氨酸(CH2)3—NH2NH2—CH—COOHCH2—C6H5NH2—CH—COOH赖氨酸苯丙氨酸该“十二肽”分子水解后有A.12个赖氨酸B.(z-12)个赖氨酸C.13个天门冬氨酸D.(w-13)个天门…  相似文献   

7.
以3,5—二氯—4—氨基苯乙酮和溴化铜(CuBr2)作原料,用乙酸乙酯(CH3COOCH2CH3)、氯仿(CHCl3)、乙醇(CH3CH2OH)作溶剂一步合成3,5—二氯—4—氨基—α—溴代苯乙酮,初步探讨了反应温度、溶剂配比和反应时间等因素对反应产率的影响。  相似文献   

8.
细辨同系物     
同系物是指结构相似,在分子组成上相差一个或若干个“CH2”原子团的有机物.据此概念可扩展、延伸出如下结论: 1.同系物必符合同一通式.例如CH=CH与C6H6虽然有相同的最简式,但前者符合CnH2n-2(n≥2)的通式,后者符合CnH2n-6(n≥6)的通式,故它们不是同系物. 2.同系物必为同一类物质.例如:  相似文献   

9.
一、回答下列问题:1。乙炔CZHZ和丁二烯C4H。都符合通式cnHZ。一2,它们是同系物吗?为什么?2。有二种碳氢化合物,它们都含碳92.3%,氢7.7%,但它们的性质不同,你能肯定它们是同分异构体吗?3。分子式分别是CZH6、C4H;。的二种化合物是否一定是同系物?为什么?4。分子式分别是CZH4、CoH,:的二种化合物是否一定是同系物?为什么?5.分子式分别是CZHZ、C;H6的二种化合物是否一定是同系物?为什么?二、写出下列化合物的名称(系统命名法)。 (1)CH3 CH3(2) \cH/ } /CH\ CHs CH:CH3CH3 CH3\cH/eH3eHZ一连一eHZ一m, }CHZweCH3(3)CHs C…  相似文献   

10.
采用LSDA /6- 311G( d, p)方法, 研究了不同外电场( - 0. 02~ 0. 02 a. u. )作用下对CH2 O分子的基态键长、键角、总能量和电荷分布的影响. 结果 表明: 随着电场强度的增加, RCO非常缓慢的减小, R CH 逐渐变大, CH2O 基态分子的总能量、键角?? HCH 和偶极矩均逐渐减小. 外电场对CH 2O分子的激 发能和振子强度均有较大影响.  相似文献   

11.
《海外英语》2007,(5):44-45
It is worthy of noting that, whilst Crookston Castle witnessed the earlier and happier portion of Mary's variegated life,  相似文献   

12.
一、吃和喝吃苹果 eat an apple, 吃药 take medicine,吃糖 have some sweets,吃饭 have one's meals,吃馆子 dine out,吃惊 be surprised/  相似文献   

13.
《海外英语》2007,(5):10-11
Many college freshmen arrive woefully unprepared to do college work, and as disadvantaged populations continue to grow, the share of the American work force that has made it through college is expected to plummet. Many experts blame that educational failure not just on high schools but also on colleges. School & College, a special report by The Chronicle, looks at efforts to fix the system. What reforms would better prepare students for college? What should schools and colleges be doing differently? How should state and federal officials help?  相似文献   

14.
The communication of people partially is the communication of cultures. Culture has a direct effect on international commercial activities in all aspects. Different conceptions about time, space, equality, law and the like, lead people to deal with things in different ways. So to know cultures of the counterpart is to facil-itate our enterprises so as to have a smooth and successful communication in commercial activity.  相似文献   

15.
《海外英语》2007,(4):36
There are numbers of crossroads on our long and unpredictable life journey where we totally have no idea about which direction to choose. No matter what our decision is, we should not turn back, but face the music and go ahead instead. I am this kind of girl who always does try without regretting, one example is how I dealt with my love.  相似文献   

16.
王菲 《华章》2007,(12):273-273
Migration occurs behind a variety of reasons and has a great effect on the whole world. People may migrate in order to improve their economic situation, or in order to escape civil strife, persecution, and environmental disasters. The impact of migration is complex, bringing both benefits anddisadvantages. This paper briefly talks about the causes of migration, the allocation of benefits, and the ways in which individual countries and the international community deal with this important subject.  相似文献   

17.
裴水妹 《华章》2007,(11):196
Sister Carrie is one of the most controversial characters in American literature.Thought as a "fallen woman" firstly,she was defined as a "new woman" by some critics later. However, by digging into the motivaton behind the whole process of Carrie's "success", the relationship between Carrie and her creator (the author), the social conditions of then American, it can be found that Carrie has never been free-standing on her thought and she has never found her real-sdf even after becoming a famous actress. In a society dominated by mass consumerism Carrie is only an adherent of her own desires. She also is a representative of all those country girls flooded into cities, a symbol and a sacrifice of the urbanization of America in a time countryside was overcome by cities.  相似文献   

18.
19.
1.IntroductionOne-cyclecontrolmethod,whichwasproposedaboutonedecadeago[1],hasbecomeanattractivemethodinspecialfieldssuchaspowerfactorcorrection[2-6],switchingamplifiers[7,8],etc.Themainideaofthiscontrollerisbasedonintegrationofdiodevoltageinone-cycleandforcesittobeexactlyequaltothereferencevalue.Themainadvantageofthiscontrollerisitsrealtimeabilitytorejectthevariationofinputvoltage[1].Despitethisgreatability,ithasnogoodperformancesinrejectingofloaddisturbanceandfollowingreferencecommands.Espec…  相似文献   

20.
风的曲线     
Rosco and I wait for the fishermen to return.I sit at a wooden bench near the store at Mt.Baker Resort and watch the clouds change shape. Rosco has my belt around his neck and an eight foot tow chain hooked to a tree. Dogs must be on a leash. Ducks and rabbits are loose.  相似文献   

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