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1.
《中国科学院院刊》2010,(5):554-555
大连化学物理所催化基础国家重点实验室纳米和界面催化研究组傅强、马丁和包信和,与理论催化研究组李微雪等合作,借助贵金属表面与单层氧化亚铁薄膜中铁原子的强相互作用所产生的界面限域效应,结合表面科学实验和密度泛函理论计算的研究结果.  相似文献   

2.
《中国科学院院刊》2014,(3):397-397
中科院大连化物所包信和院士研究组基于“纳米限域催化”的新概念,创造性地构建了硅化物晶格限域的单铁中心催化剂,成功地实现了甲烷在无氧条件下选择活化,一步高效生产乙烯、芳烃和氢气等高值化学品。  相似文献   

3.
《科协论坛》2015,(1):2
<正>包信和,1959年8月生于江苏省扬中市,中国科学院大连化学物理研究所研究员,中国科学院院士。已发表SCI论文530多篇,论文被他引8500余次;申请专利90余件;获国家自然科学二等奖、辽宁省自然科学一等奖、香港求实青年科学奖和何梁何利科学技术奖等。包信和研究员长期从事物理化学研究,在催化基础理论研究和能源高效转化过程新型催化剂开发利用等方面取得了开创性研究成果——发现并从实验和理论上证实碳纳米管孔道的电子限域效应,提出碳纳米管的"协同限域"调变催化性能  相似文献   

4.
有机化学     
正基于纳米限域效应和毛细作用的"滴管状"电催化剂用于高效二氧化碳还原南京大学化学化工学院金钟教授研发团队利用瑞利不稳定性原理构筑了"滴管状"一维中空结构的Bi纳米棒@N掺杂碳纳米管(Bi-NRs@NCNTs)复合催化剂,在较低的过电势下可以将C O2高选择性地催化转换成甲酸盐产物。相关成果发表于Nano Letters。该研究借助瑞利不稳定性原理,在高温还原反应条件下通过还原、体积收缩、弯曲、碎裂过程,  相似文献   

5.
随着体系尺寸减小到纳米级以及维度的降低,表面效应、量子限域效应、尺寸效应以及量子隧穿效应越来越显著,因而低维纳米材料通常表现出不同于普通块体材料的理化性质.第一性原理计算方法具有准确、高效、便捷以及低成本等优势,借助第一性原理计算方法,可以在原子与分子层面上设计、计算和分析新材料,在材料结构与性能计算相关领域,则可以准确预估各类材料的基本物性.因此第一性原理计算方法成为了除理论方法与实验方法外可以独立开展材料物性研究的第三种方法.  相似文献   

6.
《中国科学院院刊》2011,(6):720-720
中科院大连化物所杨维慎研究组利用了金属有机骨架(MOFs)材料(ZIF-8)的骨架柔性.实验观测和理论模拟到异丁醇分子在ZIF-8纳米粒子上吸附过程中的“gate—opening”效应。基于该效应和ZIF材料的表面超疏水性,制备出可以优先透过醇类大分子而阻止尺寸更小的水分子的高性能ZIF-8纳米复合膜。  相似文献   

7.
正潘秀莲潘秀莲,中国科学院大连化学物理研究所研究员。她长期致力于碳基纳米材料和多孔氧化物催化材料的制备,及其在能源催化转化中的应用基础研究。和团队一起经过多年的努力,在国际上提出了碳纳米管催化协同限域效应的新概念,创建了合成气直接转化制低碳烯烃的新催化过程,发明了乙炔氢氯化非金属催化剂等。主持了国家自然科学基金重点基金、面上基金,国家重点基础研究发展计划子课题,国际合作项目  相似文献   

8.
对爱因斯坦关于“时间”“空间”论证的理论基础的正确性、论据(数据)的有效性、论证过程的规范性、在“环球航行原子钟实验”中选择定量与定性分析的依据问题、空间弯曲示意图的真伪性、日全食星星偏移照片的有效性等问题提出了相应的疑问,并提出了“不同纬度时钟实验”和“等效日全食实验”,作为验证爱因斯坦“时、空”观点的验证新方法。  相似文献   

9.
《中国科学院院刊》2011,(6):716-716
中科院大连化物所洁净能源国家实验室太阳能研究部、催化基础国家重点实验室分子催化与原位表征研究组李灿院士、张文华研究组利用溶液化学的优势,采用品种诱导的方法首次生长了直径约20nm的SnSe单晶纳米线,长度从数百纳米到数十微米可调。光谱表征表明.硒化锡单晶纳米线显示明显的量子限域效应:其间接和直接带隙分别达到1.12eV和1.55eV。  相似文献   

10.
采用一阶剪切变形的Mindlin板理论研究了考虑表面效应的压电纳米板的振动问题。表面效应包括表面弹性、表面应力和表面的压电效应。基于此理论模型建立了考虑表面效应和压电效应的纳米板的修正模型,并建立了相应的控制方程。研究了四边简支压电纳米板的振动行为,并推导出了相应的频率特征方程。研究了表面效应、压电效应和剪切变形对振动频率的影响。  相似文献   

11.
Catalysis, as a key and enabling technology, plays an increasingly important role in ields ranging from energy, environment and agriculture to health care. Rational design and synthesis of highly eicient catalysts has become the ultimate goal of catalysis research. hanks to the rapid development of nanoscience and nanotechnology, and in particular a theoretical understanding of the tuning of electronic structure in nanoscale systems, this element of design is becoming possible via precise control of nanoparticles' composition, morphology, structure and electronic states. At the same time, it is important to develop tools for in situ characterization of nanocatalysts under realistic reaction conditions, and for monitoring the dynamics of catalysis with high spatial, temporal and energy resolution. In this review, we discuss coninement efects in nanocatalysis, a concept that our group has put forward and developed over several years. Taking the conined catalytic systems of carbon nanotubes, metal-conined nano-oxides and 2D layered nanocatalysts as examples, we summarize and analyze the fundamental concepts, the research methods and some of the key scientiic issues involved in nanocatalysis. Moreover, we present a perspective on the challenges and opportunities in future research on nanocatalysis from the aspects of:(1) controlled synthesis of nanocatalysts and rational design of catalytically active centers;(2) in situ characterization of nanocatalysts and dynamics of catalytic processes;(3) computational chemistry with a complexity approximating that of experiments; and (4) scale-up and commercialization of nanocatalysts.  相似文献   

12.
概念是科学教学中的重要内容之一,本文基于科学教育的研究视角,通过梳理概念和科学概念经典定义,对两者进行了进一步诠释;介绍构成概念的五个要素及其在科学教育中的作用,希望能为自然科学概念教学提供一定理论参考。  相似文献   

13.
李明玉 《科教文汇》2011,(22):53-54
概念是科学教学中的重要内容之一,本文基于科学教育的研究视角,通过梳理概念和科学概念经典定义,对两者进行了进一步诠释;介绍构成概念的五个要素及其在科学教育中的作用,希望能为自然科学概念教学提供一定理论参考。  相似文献   

14.
论信息管理学的概念与概念体系   总被引:11,自引:0,他引:11  
杨文祥 《情报科学》2000,18(3):275-280
基本概念的研究是否深入、定义是否准确,是一门学科的理论基础是否坚实的基本保证,也是检验一门学科是否成熟的首要标准。重要概念和相关概念的准确定义也至关重要。理论界许多低水平的重复研究和长期争论而无结果的现象,多半是相关概念定义不规范、不准确的结果。为避免信息管理学在初创时期便陷入这一局面,本文对信息管理学的基本概念、重要概念和相关学科的相关概念以及这些概念之间的内在联系和区别作一系统的梳理和探讨。对争议较大的概念和相关理论提出了信息管理学的定义和观点。  相似文献   

15.
本体集成相关的基本概念研究   总被引:1,自引:0,他引:1  
本文通过综合研究国内外典型观点.分析了本体匹配、本体映射、本体联结、本体融合、本体集成以及本体协同等概念的含义,详细描述了相似概念的区别与关系,并提出了易混淆概念的较为合适的中文译名,给出了重要概念的较为准确的定义.  相似文献   

16.
The fundamental idea of the work reported here is to extract index phrases from texts with the help of a single word concept dictionary and a thesaurus containing relations among concepts. The work is based on the fact, that, within every phrase, the single words the phrase is composed of are related in a certain well denned manner, the type of relations holding between concepts depending only on the concepts themselves. Therefore relations can be stored in a semantic network. The algorithm described extracts single word concepts from texts and combines them to phrases using the semantic relations between these concepts, which are stored in the network. The results obtained show that phrase extraction from texts by this semantic method is possible and offers many advantages over other (purely syntactic or statistic) methods concerning preciseness and completeness of the meaning representation of the text. But the results show, too, that some syntactic and morphologic “filtering” should be included for effectivity reasons.  相似文献   

17.
行政与行政法是行政法学上两个最具基础性的,同时也是存在一定学术争议的概念范畴。论文在分析了行政法学界对行政特别是行政法的定义方面所存在问题的基础上,提出了对行政与行政法的新的定义观:行政是根据法律并为了执行法律而运用国家行政权,对国家事务和社会公共事务进行组织与管理的活动;行政法则是调整国家行政主体在行使国家行政权,对国家与社会公共事务进行组织和管理的活动过程中所发生的重要的社会关系的法律规定的总和。  相似文献   

18.
We propose a new query reformulation approach, using a set of query concepts that are introduced to precisely denote the user’s information need. Since a document collection is considered to be a domain which includes latent primitive concepts, we identify those concepts through a local pattern discovery and a global modeling using data mining techniques. For a new query, we select its most associated primitive concepts and choose the most probable interpretations as query concepts. We discuss the issue of constructing the primitive concepts from either the whole corpus or from the retrieved set of documents. Our experiments are performed on the TREC8 collection. The experimental evaluation shows that our approach is as good as current query reformulation approaches, while being particularly effective for poorly performing queries. Moreover, we find that the approach using the primitive concepts generated from the set of retrieved documents leads to the most effective performance.  相似文献   

19.
In this paper, a semantic categorization method in generic home photos is proposed. In recent years, the semantic categorization of image has been a challenge due to the proliferation of digital home photos. Our approach is to detect semantically meaningful concepts contained in a photo. The proposed method incorporates an intermediate level of concepts, called local concept, so that it catches well semantic meaning of local regions of image as bridging the semantic gap of the low-level features and high-level category concepts. To detect the local concepts from the home photo, region segmentation by photographic region template and concept merging is also proposed. The efficacy of the proposed semantic categorization method was demonstrated with 3828 general home photos. The experiment results showed the proposed categorization method would be useful to detect multiple semantic meaning of the home photos.  相似文献   

20.
Document concept lattice for text understanding and summarization   总被引:4,自引:0,他引:4  
We argue that the quality of a summary can be evaluated based on how many concepts in the original document(s) that can be preserved after summarization. Here, a concept refers to an abstract or concrete entity or its action often expressed by diverse terms in text. Summary generation can thus be considered as an optimization problem of selecting a set of sentences with minimal answer loss. In this paper, we propose a document concept lattice that indexes the hierarchy of local topics tied to a set of frequent concepts and the corresponding sentences containing these topics. The local topics will specify the promising sub-spaces related to the selected concepts and sentences. Based on this lattice, the summary is an optimized selection of a set of distinct and salient local topics that lead to maximal coverage of concepts with the given number of sentences. Our summarizer based on the concept lattice has demonstrated competitive performance in Document Understanding Conference 2005 and 2006 evaluations as well as follow-on tests.  相似文献   

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