共查询到19条相似文献，搜索用时 125 毫秒
1.
《赣南师范学院学报》2021,(3):44-48
采用电弧炉熔炼和急冷快淬吸铸的方法制备Ni-Fe-Ga-X(X=Si, Ge, Al, Co)合金,利用光学显微镜、X射线衍射和示差扫描量热仪,研究了Si, Ge, Al, Co元素合金化对Ni-Fe-Ga合金显微组织、晶体结构和马氏体相变特性的影响.研究结果表明,Si, Ge, Al替代Ga元素后,室温下表现出良好的热弹性马氏体特征,随着其含量增加,合金的马氏体相变特征温度线性下降;而Co替代Ga元素,具有M+γ双相显微组织结构,其相变特征温度随Co含量增加而显著提高.电子浓度和晶胞体积是影响Ni-Fe-Ga-X合金马氏体相变特征温度两个重要的因素.一方面,随着电子浓度的增加,合金的马氏体相变特征温度升高;另一方面,晶胞体积收缩也有利于提高马氏体相变特征温度. 相似文献
2.
采用电弧熔炼和高温退火的方法制备了Ni_(42)Co_8Mn_(39)Sb_(11)铁磁形状记忆合金.用X射线衍射表征样品的晶体结构,用综合物性测试系统对材料的马氏体相变以及马氏体相变附近的磁热效应、磁电阻效应和磁致应变效应进行了表征.结果表明,样品在220 K左右发生了从弱磁马氏体到铁磁奥氏体的相变,随磁场增加,马氏体转变温度向低温偏移.在马氏体相变附近,样品不仅具有较大的磁热效应,还具有磁电阻效应和磁致应变效应,这些效应都是由磁场驱动马氏体相变导致的.这些结果说明Ni-Co-Mn-Sb合金在磁制冷、磁传感、磁驱动领域有着潜在的应用. 相似文献
3.
《常熟理工学院学报》2016,(4)
采用电弧炉熔炼的方法制备了Mn_(50)Ni_(41-x)Cr_xSn_9合金铸锭.用X射线衍射、振动样品磁强计、综合物性测试系统对材料的结构、相变和磁热效应进行了研究.结果表明,由于价电子浓度的减小,Cr替代Ni使材料的马氏体转变温度降低.Cr的加入使马氏体转变伴随着较大的磁化强度的突变,从而表现出较大的低场磁熵变.Mn_(50)Ni_(41-x)Cr_xSn_9合金以其较大的低场磁热效应、可调的工作温区在磁制冷领域有着潜在的应用. 相似文献
4.
韩志达 《常熟理工学院学报》2009,23(10):19-22
采用电弧熔炼的方法制备了Ni43Mn46-xCoxSn1,系列铁磁形状记忆合金,并对其磁性和相变进行了研究．结果表明,由于价电子浓度的增加,Co替代Mn使材料马氏体转变温度迅速提高．Co的加入使合金的奥氏体居里温度迅速提高,而马氏体居里温度则略有降低．在马氏体相变附近,由于磁化强度的突变,合金表现出巨大的逆磁热效应,表明该系列合金在磁制冷领域有着潜在的应用价值． 相似文献
5.
《常熟理工学院学报》2015,(4)
通过低温DSC测试仪、金相显微镜和拉伸试验机,研究Ni Ti形状记忆合金冷轧变形量对马氏体相变行为和形状恢复率的影响.结果表明:冷轧变形生成的应力诱发马氏体和取向不同的丝织构及高密度位错,使得马氏体相变时界面迁移的阻碍作用增加,抑制了相变的发生;随冷轧变形量的增大合金的形状恢复率降低. 相似文献
6.
崔玉亭 《商丘师范学院学报》2006,22(2):12-16
测量了Ni51.6Mn23.4Ga25单晶的交流磁化率、电阻、有无磁场下的相变应变.结果表明该材料的马氏体相变温度为252K,相变热滞后仅为6K,自发相变应变量高达-1.15%.沿应变测量方向和垂直应变测量方向施加960KA/m的磁场,双向形状记忆的应变量分别增强到-2.35%和0.56%.分析表明该单晶的大自发相变应变量起源于内应力诱导的变体择优取向,而磁增强的相变应变量归功于外加磁场通过孪晶界移动的方式诱导的变体择优取向. 相似文献
7.
《常熟理工学院学报》2017,(4)
采用电弧熔炼的方法制备了Ni_(43)Mn_(46)Sn_(11)-xGax(x=0,1,2)合金铸锭.用X射线衍射表征样品的晶体结构,用振动样品磁强计和综合物性测试系统测量样品的相变和磁热效应.结果表明,所有合金在室温下均为奥氏体立方结构,表明马氏体转变温度低于室温.Ga代替Sn导致马氏体转变温度升高,这是由于Ga的原子半径小于Sn,导致晶格变小.所有样品在马氏体转变伴随着较大的磁化强度的突变,从而表现出较大的低场磁熵变.Ni_(43)Mn_(46)Sn_(11)-xGax(x=0,1,2)以其较大的低场磁热效应、可调的工作温区在磁制冷领域有着潜在的应用. 相似文献
8.
《东南大学学报》2015,(4)
采用X射线衍射和电子背散射衍射研究了第二相析出对冷轧AA3003铝合金再结晶织构的影响.当退火温度为783 K时,由于退火温度高,AA3003合金再结晶织构不明显.而在相同退火条件下,在添加了0.39%钪的AA3003合金中发现了强烈的P{011}〈111〉织构.采用EBSD分析再结晶初期的合金,发现2种合金的再结晶形核均无明显择优取向.第二相颗粒析出先于或与再结晶同时发生时,会显著阻碍除P取向晶核之外的再结晶晶核的长大,导致P取向的再结晶晶核长大速度明显快于其他取向的晶核.因此,在并发沉淀析出影响的AA3003合金中形成了强烈的P{011}〈111〉再结晶织构. 相似文献
9.
采用电弧熔炼的方法制备了Mn_(50-x)Co_xNi_(40)Sn_(10)(x=0,2,4,6)材料的合金铸锭.用X射线衍射表征样品的晶体结构,用MPMS-3磁性测量系统测量样品的相变和磁热效应.结果表明,Co替代Mn导致马氏体转变温度升高,这是由于Co原子的价电子数多于Mn原子导致的.所有样品在马氏体转变伴随着较大的磁化强度的突变,从而表现出较大的低场磁熵变.Mn_(50-x)Co_xNi_(40)Sn_(10)(x=0,2,4,6)以其较大的低场磁热效应、可调的工作温区在磁制冷领域有着潜在的应用. 相似文献
10.
《常熟理工学院学报》2017,(2)
采用电弧熔炼法制备了Mn_(50+x)Ni_(41-x)Sn_9系列合金,并通过X-射线衍射和综合物性测试系统对材料的晶体结构、相变、磁性以及交换偏置效应进行了研究.结果表明,随着x含量的增加,马氏体转变温度逐渐降低,材料的饱和磁化强度逐渐增加,而场冷条件下的交换偏置场则呈现逐渐降低的趋势.这是由于材料中铁磁相和反铁磁相的耦合导致了这种交换偏置效应. 相似文献
11.
The Mg-based hydrogen storage alloys Mg2Ni, Mg2Ni0.7Fe0.3 and Mgl.7Alo.3Ni were successfully synthesized by a two-step process （sintering and ball milling）. The crystal structure and microstructure were examined by X-ray diffraction, Scanning Electron Microscope and Malvern particle size analyzer. New phase appears in the tripe alloys doped with A1 and Fe, and the particle size ranges from 3μm to 5 μm. The electrochemical performance studies indicate that the partial substitution of AI for Mg, and Fe for Ni significantly improve the cycle life, reversibility of hydrogen absorption and desorption. The diffusion process is the control step in the electrode reaction of hydrogen storage alloys. 相似文献
12.
1 Ｉｎｔｒｏｄｕｃｔｉｏｎ ＡＢ5 ｔｙｐｅｈｙｄｒｏｇｅｎｓｔｏｒａｇｅａｌｌｏｙｓｈａｖｅｂｅｅｎｉｎｔｅｎ ｓｉｖｅｌｙｉｎｖｅｓｔｉｇａｔｅｄｓｉｎｃｅｔｈｅｆｉｒｓｔｕｓｅａｓａｎｅｌｅｃｔｒｏｄｅｒｅｐｏｒｔｅｄｂｙＪｕｓｔｉｉｎ 1973[1] .ＴｈｅｃｏｍｍｅｒｃｉａｌＡＢ5ｅｌｅｃｔｒｏｄｅｓｕｓｅｍｉｓｃｈｍｅｔａｌ,ａｌｏｗｃｏｓｔｍｉｘｔｕｒｅｏｆｒａｒｅｅａｒｔｈｅｌｅｍｅｎｔｓ ,ａｓａｓｕｂｓｔｉｔｕｔｅｆｏｒＬａ ,ｗｈｉｌｅｔｈｅＢ5ｃｏｍｐｏｎｅｎｔｒｅｍａｉｎｓｐｒｉｍａｒ… 相似文献
13.
Zr65 Al10 Ni10 Cu15, Zr52.5 Al10 Ni10 Cu15 Be12.5 and Zr52.5 Al10 Ni14.6 Cu17.9 Ti5 bulk amorphous alloys were prepared by copper mould casting. The crystallization kinetics was measured by differential scanning calorimeter(DSC) with different heating rates, and the activation energy was calculated using Kissinger equation. The relationship between thermal stability and rate constant of crystallization reaction is discussed on the view of crystallization kinetics, and the effect of small atom Beryllium on thermal stability of bulk amorphous alloys is also studied. 相似文献
14.
采用电弧熔炼方法制备了Mn50＋xNi41-xSn9系列铁磁形状记忆合金,并对其磁性、相变和磁热效应进行了研究。结果表明,合金在室温下均表现为四方马氏体相和立方奥氏体相的混合相,随着Mn含量的增加,由于价电子浓度的减少,马氏体转变温度逐渐下降,当x=2—4时,马氏体相变伴随着较大磁化强度的突变,同时合金表现出较大的逆磁热效应,这表明该系列合金在磁制冷领域有着潜在的应用价值。 相似文献
15.
硼对金属间化合物Ni_3Fe氢气诱发环境氢脆的影响(英文) 总被引：1，自引：0，他引：1
In this paper the tensile properties of both ordered and disordered Ni-24Fe and Ni-24Fe-0.03%B(wt%)alloys in gaseous hydrogen was investigated.The result shows that the ductility of the disordered Ni_3Fe is significantly larger than that of ordered material in gaseous hydrogen.However,the ductility of ordered Ni3Fe doped with 0.03%B is nearly the same as that of disordered one indicating the obvious suppressing effect of boron on the H_2-induced embrittlement.Based on the segregation behavior of boron in Ni_3Al,it is proposed that the suppressing effect of boron in Ni_3Fe on the H_2-induced embrittlement is attributed to the segregation of boron on grain boundaries,thereby reducing the hydrogen diffusivity along the grain boundaries. 相似文献
16.
首先采用水热法制备出铁镍合金,然后将铁镍合金加入到含有超分子氢键网络的聚酰胺高分子基体中,得到一种具有导电性能的自修复高分子材料。通过扫描电子显微镜、X-射线衍射仪、电阻率测定仪等手段对样品的结构、形貌、导电及自修复性能进行了研究。结果表明,原料中Fe2＋与Ni2＋的摩尔比对铁镍合金形貌影响较大。当Fe2＋与Ni2＋摩尔比为70∶25时,产物形貌较规整。添加铁镍合金后,高分子材料的电导率呈上升趋势。当铁镍合金质量分数为45%时,自修复导电高分子材料的修复率达80%。 相似文献
17.
试验研究了热处理对CuCr/1Cr18Ni9Ti双金属复合材料结合区组织和性能的影响。结果表明,热处理后,结合区没有明显的裂纹和脆化现象,界面反应层宽度无明显增加;热处理工艺明显提高了1Cr18Ni9Ti奥氏体不锈钢的硬度,界面反应层和CuCr合金的显微硬度略有增加。 相似文献
18.
The phase transition characteristics of the prepared Ni46Mn35Ga19 single crystal have been systematically investigated by measuring resistance, strain, heat flow, and ac magnetic susceptibility. The experimental results indicate that both magnetic transition and martensitic transformation occurred simultaneously and the corresponding transition temperature was about 356 K. Meanwhile, the prepared single crystal also exhibited spontaneous and magnetic-field-enhanced two-way thermal shape memory effect with the strains up to -0.89% and -1.90% with and without a magnetic field of 1.6 T, respectively. The possible mechanism of the large spontaneous and magnetic enhanced deformation were analyzed based on the phase transition characteristics of Ni46Mn35Ga19 single crystal and the preferential orientation of martensitic variants. 相似文献
19.
Fe-Cr-Ni heat resistant steels with different contents of Al and Si were cast in intermediate frequency induction furnace with non-oxidation method. With oxidation weight gain method, the oxidation resistance of test alloys was examined at 1 200℃ for 500 h. The effects of Al and Si on oxidation resistance were studied through analyses of X-ray diffraction (XRD) and scanning electron microscope (SEM). It is shown that the composition of oxide scales is a decisive factor for the oxidation resistance of heat resistant steels. The compounded scale composed of Cr2O3, ar-Al2O3, SiO2 and Fe(Ni)Cr2O4, with flat and compact structure, fine and even grains, exhibits complete oxidation resistance at 1 200℃ Its oxidation weight gain rate is only 0.081 g/(m2·h). By the criterion of standard Gibbs formation free energy, a model of nucleation and growth of the compounded scale was established. The formation of the compounded scale was the result of the competition of being oxidated and reduction among Al, Si, and the matrix metal elements of Fe, Cr and Ni. The protection of the compounded scale was analyzed from the perspectives of electrical conductivity and strength properties. 相似文献