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1.
We review recent progress in the exploration of topological quantum states of matter in iron-based superconductors. In particular, we focus on the non-trivial topology existing in the band structures and superconducting states of iron’s 3d orbitals. The basic concepts, models, materials and experimental results are reviewed. The natural integration between topology and high-temperature superconductivity in iron-based superconductors provides great opportunities to study topological superconductivity and Majorana modes at high temperature.  相似文献   

2.
The quantum Hall effect (QHE) with quantized Hall resistance of h/νe2 started the research on topological quantum states and laid the foundation of topology in physics. Since then, Haldane proposed the QHE without Landau levels, showing nonzero Chern number |C| = 1, which has been experimentally observed at relatively low temperatures. For emerging physics and low-power-consumption electronics, the key issues are how to increase the working temperature and realize high Chern numbers (C > 1). Here, we report the experimental discovery of high-Chern-number QHE (C = 2) without Landau levels and C = 1 Chern insulator state displaying a nearly quantized Hall resistance plateau above the Néel temperature in MnBi2Te4 devices. Our observations provide a new perspective on topological matter and open new avenues for exploration of exotic topological quantum states and topological phase transitions at higher temperatures.  相似文献   

3.
Designing new cathodes with high capacity and moderate potential is the key to breaking the energy density ceiling imposed by current intercalation chemistry on rechargeable batteries. The carbonaceous materials provide high capacities but their low potentials limit their application to anodes. Here, we show that Fermi level tuning by p-type doping can be an effective way of dramatically raising electrode potential. We demonstrate that Li(Na)BCF2/Li(Na)B2C2F2 exhibit such change in Fermi level, enabling them to accommodate Li+(Na+) with capacities of 290–400 (250–320) mAh g−1 at potentials of 3.4–3.7 (2.7–2.9) V, delivering ultrahigh energy densities of 1000–1500 Wh kg−1. This work presents a new strategy in tuning electrode potential through electronic band structure engineering.  相似文献   

4.
Topological photonics is an emerging research area that focuses on the topological states of classical light. Here we reveal the topological phases that are intrinsic to the quantum nature of light, i.e. solely related to the quantized Fock states and the inhomogeneous coupling strengths between them. The Hamiltonian of two cavities coupled with a two-level atom is an intrinsic one-dimensional Su-Schriefer-Heeger model of Fock states. By adding another cavity, the Fock-state lattice is extended to two dimensions with a honeycomb structure, where the strain due to the inhomogeneous coupling strengths of the annihilation operator induces a Lifshitz topological phase transition between a semimetal and three band insulators within the lattice. In the semimetallic phase, the strain is equivalent to a pseudomagnetic field, which results in the quantization of the Landau levels and the valley Hall effect. We further construct an inhomogeneous Fock-state Haldane model where the topological phases can be characterized by the topological markers. With d cavities being coupled to the atom, the lattice is extended to d − 1 dimensions without an upper limit. In this study we demonstrate a fundamental distinction between the topological phases in quantum and classical optics and provide a novel platform for studying topological physics in dimensions higher than three.  相似文献   

5.
The search for unconventional superconductivity in Weyl semimetal materials is currently an exciting pursuit, since such superconducting phases could potentially be topologically non-trivial and host exotic Majorana modes. The layered material TaIrTe4 is a newly predicted time-reversal invariant type II Weyl semimetal with the minimum number of Weyl points. Here, we report the discovery of surface superconductivity in Weyl semimetal TaIrTe4. Our scanning tunneling microscopy/spectroscopy (STM/STS) visualizes Fermi arc surface states of TaIrTe4 that are consistent with the previous angle-resolved photoemission spectroscopy results. By a systematic study based on STS at ultralow temperature, we observe uniform superconducting gaps on the sample surface. The superconductivity is further confirmed by electrical transport measurements at ultralow temperature, with an onset transition temperature (Tc) up to 1.54 K being observed. The normalized upper critical field h*(T/Tc) behavior and the stability of the superconductivity against the ferromagnet indicate that the discovered superconductivity is unconventional with the p-wave pairing. The systematic STS, and thickness- and angular-dependent transport measurements reveal that the detected superconductivity is quasi-1D and occurs in the surface states. The discovery of the surface superconductivity in TaIrTe4 provides a new novel platform to explore topological superconductivity and Majorana modes.  相似文献   

6.
WTe2, as a type-II Weyl semimetal, has 2D Fermi arcs on the (001) surface in the bulk and 1D helical edge states in its monolayer. These features have recently attracted wide attention in condensed matter physics. However, in the intermediate regime between the bulk and monolayer, the edge states have not been resolved owing to its closed band gap which makes the bulk states dominant. Here, we report the signatures of the edge superconductivity by superconducting quantum interference measurements in multilayer WTe2 Josephson junctions and we directly map the localized supercurrent. In thick WTe2 (, the supercurrent is uniformly distributed by bulk states with symmetric Josephson effect (). In thin WTe2 (10 nm), however, the supercurrent becomes confined to the edge and its width reaches up to and exhibits non-symmetric behavior . The ability to tune the edge domination by changing thickness and the edge superconductivity establishes WTe2 as a promising topological system with exotic quantum phases and a rich physics.  相似文献   

7.
Charmonium is a bound state of a charmed quark and a charmed antiquark, and a charmoniumlike state is a resonant structure that contains a charmed quark and antiquark pair but has properties that are incompatible with a conventional charmonium state. While operating at center-of-mass energies from 2 to 5 GeV, the BESIII experiment can access a wide mass range of charmonium and charmoniumlike states, and has contributed significantly in this field. We review BESIII results involving conventional charmonium states, including the first observation of the M1 transition ψ(2S) → γηc(2S) and the discovery of the ψ2(3823) state; and report on studies of charmoniumlike states, including the discoveries of the Zc(3900) and Zc(4020) tetraquark candidates, the resolution of the fine structure of the Y(4260) state, the discovery of the new production process e+e− → γX(3872) and the uncovering of strong evidence for the commonality among the X(3872), Y(4260) and Zc(3900) states. The prospects for further research at BESIII and proposed future facilities are also presented.  相似文献   

8.
Discrete-scale invariance (DSI) is a phenomenon featuring intriguing log-periodicity that can be rarely observed in quantum systems. Here, we report the log-periodic quantum oscillations in the longitudinal magnetoresistivity (ρxx) and the Hall traces (ρyx) of HfTe5 crystals, which reveal the DSI in the transport-coefficients matrix. The oscillations in ρxx and ρyx show the consistent logB-periodicity with a phase shift. The finding of the logB oscillations in the Hall resistance supports the physical mechanism as a general quantum effect originating from the resonant scattering. Combined with theoretical simulations, we further clarify the origin of the log-periodic oscillations and the DSI in the topological materials. This work evidences the universality of the DSI in the Dirac materials and provides indispensable information for a full understanding of this novel phenomenon.  相似文献   

9.
The six-membered ring (SMR) is a common structure unit for numerous material systems. These materials include, but are not limited to, the typical two-dimensional materials such as graphene, h-BN, and transition metal dichalcogenides, as well as three-dimensional materials such as beryllium, magnesium, MgB2 and Bi2Se3. Although many of these materials have already become ‘stars’ in materials science and condensed-matter physics, little attention has been paid to the roles of the SMR unit across a wide range of compositions and structures. In this article, we systematically analyze these materials with respect to their very basic SMR structural unit, which has been found to play a deterministic role in the occurrence of many intriguing properties and phenomena, such as Dirac electronic and phononic spectra, superconductivity and topology. As a result, we have defined this group of materials as SMR inorganic materials, opening up a new perspective on materials research and development. With their unique properties, SMR materials deserve wide attention and in-depth investigation from materials design, new physical discoveries to target-wizard applications. It is expected that SMR materials will find niche applications in next-generation information technology, renewable energy, space, etc.  相似文献   

10.
Exploration of superconductivity in Cr-based compounds has attracted considerable interest because only a few Cr-based superconductors (CrAs, A2Cr3As3 and ACr3As3 (A = K, Rb, Cs, Na)) have been discovered so far and they show an unconventional pairing mechanism. We report the discovery of bulk superconductivity at 5.25 K in chromium nitride in Pr3Cr10-xN11 with a cubic lattice structure. A relatively large upper critical field of Hc2(0) ∼ 12.6 T is determined, which is larger than the estimated Pauli-paramagnetic pair-breaking magnetic field. The material has a large electronic specific-heat coefficient of 170 mJ K−2 mol−1—about 10 times larger than that estimated by the electronic structure calculation, which suggests that correlations between 3d electrons are very strong in Pr3Cr10-xN11, and thus quantum fluctuations might be involved. Electronic structure calculations show that the density of states at the Fermi energy are contributed predominantly by Cr 3d electrons, implying that the superconductivity results mainly from the condensation of Cr 3d electrons. Pr3Cr10-xN11 represents a rare example of possible unconventional superconductivity emerging in a 3D system with strong electron correlations. Nevertheless, clarification of the specific pairing symmetry needs more investigation.  相似文献   

11.
Weyl points (WPs), nodal degenerate points in three-dimensional (3D) momentum space, are said to be ‘ideal’ if they are symmetry-related and well-separated, and reside at the same energy and far from nontopological bands. Although type-II WPs have unique spectral characteristics compared with type-I counterparts, ideal type-II WPs have not yet been reported because of a lack of an experimental platform with enough flexibility to produce strongly tilted dispersion bands. Here, we experimentally realize a topological circuit that hosts only topological bands with a minimal number of four ideal type-II WPs. By stacking two-dimensional (2D) layers of inductor-capacitor (LC) resonator dimers with the broken parity inversion symmetry (P), we achieve a strongly tilted band structure with two group velocities in the same direction, and topological surface states in an incomplete bandgap. Our results establish an ideal system for the further study of Weyl physics and other exotic topological phenomena.  相似文献   

12.
We present numerical simulations of DNA-chip hybridization, both in the “static” and “dynamical” cases. In the static case, transport of free targets is limited by molecular diffusion; in the dynamical case, an efficient mixing is achieved by chaotic advection, with a periodic protocol using pumps in a rectangular chamber. This protocol has been shown to achieve rapid and homogeneous mixing. We suppose in our model that all free targets are identical; the chip has different spots on which the probes are fixed, also all identical, and complementary to the targets. The reaction model is an infinite sink potential of width dh, i.e., a target is captured as soon as it comes close enough to a probe, at a distance lower than dh. Our results prove that mixing with chaotic advection enables much more rapid hybridization than the static case. We show and explain why the potential width dh does not play an important role in the final results, and we discuss the role of molecular diffusion. We also recover realistic reaction rates in the static case.  相似文献   

13.
Many layered superlattice materials intrinsically possess large Seebeck coefficient and low lattice thermal conductivity, but poor electrical conductivity because of the interlayer transport barrier for charges, which has become a stumbling block for achieving high thermoelectric performance. Herein, taking BiCuSeO superlattice as an example, it is demonstrated that efficient interlayer charge release can increase carrier concentration, thereby activating multiple Fermi pockets through Bi/Cu dual vacancies and Pb codoping. Experimental results reveal that the extrinsic charges, which are introduced by Pb and initially trapped in the charge-reservoir [Bi2O2]2+ sublayers, are effectively released into [Cu2Se2]2− sublayers via the channels bridged by Bi/Cu dual vacancies. This efficient interlayer charge release endows dual-vacancy- and Pb-codoped BiCuSeO with increased carrier concentration and electrical conductivity. Moreover, with increasing carrier concentration, the Fermi level is pushed down, activating multiple converged valence bands, which helps to maintain a relatively high Seebeck coefficient and yield an enhanced power factor. As a result, a high ZT value of ∼1.4 is achieved at 823 K in codoped Bi0.90Pb0.06Cu0.96SeO, which is superior to that of pristine BiCuSeO and solely doped samples. The present findings provide prospective insights into the exploration of high-performance thermoelectric materials and the underlying transport physics.  相似文献   

14.
Understanding the correlation between exposed surfaces and performances of controlled nanocatalysts can aid effective strategies to enhance electrocatalysis, but this is as yet unexplored for the nitrogen reduction reaction (NRR). Here, we first report controlled synthesis of well-defined Pt3Fe nanocrystals with tunable morphologies (nanocube, nanorod and nanowire) as ideal model electrocatalysts for investigating the NRR on different exposed facets. The detailed electrocatalytic studies reveal that the Pt3Fe nanocrystals exhibit shape-dependent NRR electrocatalysis. The optimized Pt3Fe nanowires bounded with high-index facets exhibit excellent selectivity (no N2H4 is detected), high activity with NH3 yield of 18.3 μg h−1 mg−1cat (0.52 μg h−1 cm−2ECSA; ECSA: electrochemical active surface area) and Faraday efficiency of 7.3% at −0.05 V versus reversible hydrogen electrode, outperforming the {200} facet-enclosed Pt3Fe nanocubes and {111} facet-enclosed Pt3Fe nanorods. They also show good stability with negligible activity change after five cycles. Density functional theory calculations reveal that, with high-indexed facet engineering, the Fe-3d band is an efficient d-d coupling correlation center for boosting the Pt 5d-electronic exchange and transfer activities towards the NRR.  相似文献   

15.
A well-known discrete stability test is used to derive from the denominator D(z) of a given stable high-order transfer function G(z), the denominator of a low-order approximant of G(z). The proposed method, based on the truncation and inversion of a continued fraction formed with the coefficients of D(z), yields a reduced denominator d(z) of degree, say m, which is always stable. Furthermore, depending on the neglected parts of the continued fraction, d(z) approximates m1 and m2 = m−m1 zeros of D(z), located very near the points z=1 and z=-1, respectively. In the special case m1=m, d(z) is identical to the polynomial obtained by applying to D(z) the indirect technique, which combines the bilinear transformation with the Routh or the Schwarz approximation method.  相似文献   

16.
Multiferroics are rare in nature due to the mutual exclusive origins of magnetism and ferroelectricity. The simultaneous coexistence of robust magnetism/ferroelectricity and strong magnetoelectric coupling in single multiferroics is hitherto unreported, which may also be attributed to their potential conflictions. In this paper, we show the first-principles evidence of such desired coexistence in ultrathin-layer CuCrS2 and CuCrSe2. The vertical ferroelectricity is neither induced by an empty d shell nor spin-driven, giving rise to an alternative possibility of resolving those intrinsic exclusions and contradictions. Compared with their bulk phases, the ferromagnetism in the thin-layer structures (two–six layers) can be greatly stabilized due to the enhanced carrier density and orbital shifting by vertical polarization, and the Curie temperatures of both ferromagnetism and ferroelectricity can be above room temperature. Moreover, a considerable net magnetization can be reversed upon ferroelectric switching, where the change in spin-resolved band structure also renders efficient ‘magnetic reading + electrical writing’. The thickness-different layers may even exhibit diversified types of magnetoelectric coupling, which both enriches the physics of multiferroics and facilitates their practical applications.  相似文献   

17.
This paper gives a general review of the Theory of Nonlinear Systems. In 1960, the author presented a paper “Theory of Nonlinear Control” at the First IFAC Congress at Moscow. Professor Norbert Wiener, who attended this Congress, drew attention to his work on the synthesis and analysis of nonlinear systems in terms of Hermitian polynomials in the Laguerre coefficients of the past of the input.Wiener's original idea was to use white noise as a probe on any nonlinear system. Applying this input to a Laguerre network gives u1, u2,…, us, and then to a Hermite polynomial generator gives V(α)'s. Applying the same input to the actual nonlinear system gives output c(t). Putting c(t) and V(α)'s through a product averaging device, we get c(t)V(α) = Aα2лs2, where the upper bar denotes time average and Aα's can be considered as characteristic coefficients of the nonlinear system. A desired output z(itt) may replace c(itt) to get a new set of Aα's.The Volterra functional method suggested by Wiener in 1942 has been greatlydeveloped from 1955 to the present. The method involves a multi-dimensional convolution integral with multi- dimensional kernels. The associated multi-dimensional transforms are given by Y.H. Ku and A.A. Wolf (J. Franklin Inst., Vol. 281, pp. 9–26, 1966). Wiener extended the Volterra functionals by forming an orthogonal set of functionals known as G-functionals, using Gaussian white noise as input. Volterra kernels and Wiener kernels can be correlated and form the characteristic functions of nonlinear systems.From an extension of the linear system to the nonlinear system, the input-output crosscorrelation φxy can be shown to be equal to the convolution of system impulse response h1 with the autocorrelation φxx. Using the white noise as input, where its power density spectrum is a constant, say, A, the crosscorrelation is given by φxy(σ) = Ah1(σ), while the autocorrelation is φxx(τ) = Au(τ). This extension forms the basis of an optimum method for nonlinear system identification. Measurement of kernels can be made through proper circuitry.Parallel to the Volterra series and the Wiener series, another series based on Taylor-Cauchy transforms developed since 1959 are given for comparison. The Taylor-Cauchy transform method can be applied in the analysis of simultaneous nonlinear systems. It is noted that the Volterra functional method and the Taylor-Cauchy transform method give identical final results.A selected Bibliography is appended not only to include other aspects of nonlinear system theory but also to show the wide application of nonlinear system characterization and identification to problems in biology, ecology, physiology, cybernetics, control theory, socio- economic systems, etc.  相似文献   

18.
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19.
Understanding the mineralogy of the Earth''s interior is a prerequisite for unravelling the evolution and dynamics of our planet. Here, we conducted high pressure-temperature experiments mimicking the conditions of the deep lower mantle (DLM, 1800–2890 km in depth) and observed surprising mineralogical transformations in the presence of water. Ferropericlase, (Mg, Fe)O, which is the most abundant oxide mineral in Earth, reacts with H2O to form a previously unknown (Mg, Fe)O2Hx (x ≤ 1) phase. The (Mg, Fe)O2Hx has a pyrite structure and it coexists with the dominant silicate phases, bridgmanite and post-perovskite. Depending on Mg content and geotherm temperatures, the transformation may occur at 1800 km for (Mg0.6Fe0.4)O or beyond 2300 km for (Mg0.7Fe0.3)O. The (Mg, Fe)O2Hx is an oxygen excess phase that stores an excessive amount of oxygen beyond the charge balance of maximum cation valences (Mg2+, Fe3+ and H+). This important phase has a number of far-reaching implications including extreme redox inhomogeneity, deep-oxygen reservoirs in the DLM and an internal source for modulating oxygen in the atmosphere.  相似文献   

20.
Development of novel catalysts for nitrogen reduction at ambient pressures and temperatures with ultrahigh ammonia (NH3) yield and selectivity is challenging. In this work, an atomic catalyst with separated Pd atoms on graphdiyne (Pd-GDY) was synthesized, which shows fascinating electrocatalytic properties for nitrogen reduction. The catalyst has the highest average NH3 yield of 4.45 ± 0.30 mgNH3 mgPd−1 h−1, almost tens of orders larger than for previously reported catalysts, and 100% reaction selectivity in neutral media. Pd-GDY exhibits almost no decreases in NH3 yield and Faradaic efficiency. Density functional theory calculations show that the reaction pathway prefers to perform at the (Pd, C1, C2) active area because of the strongly coupled (Pd, C1, C2), which elevates the selectivity via enhanced electron transfer. By adjusting the p–d coupling accurately, reduction of self-activated nitrogen is promoted by anchoring atom selection, and side effects are minimized.  相似文献   

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