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1.
Jun Lin Wei-ying Zheng Peng-ruo-feng Liu Ning Zhang Hui-ping Lin Yi-jing Fan Xin-hua Gu Oliver Vollrath Christian Mehl 《Journal of Zhejiang University. Science. B》2014,15(7):649-660
The aim of this study is to evaluate the influence of Tooth Mousse (TM) application, smear layer removal, and storage time on resin-dentin microtensile bond strength (μTBS). Dentin specimens were divided into two groups: (1) smear layer covered; (2) smear layer removed using 15% EDTA for 90 s. In each group, half the specimens were treated once with TM for 60 min. After bonding procedures using a two-step self-etching adhesive (Clearfil SE Bond (CSE); Kuraray Medical, Tokyo, Japan), an all-in-one adhesive (G-Bond (GB); GC Corp, Tokyo, Japan), and a total-etch adhesive (Adper Single Bond 2 (SB); 3M ESPE, St. Paul, MN, USA), the specimens were stored for 3 d or 6 months in deionized water at 37 °C, and μTBS was tested and analyzed. With the exception of SB (no TM application) and GB, the μTBS was significantly increased for CSE and SB using EDTA pre-conditioning and 3 d of storage (P≤0.001). Bond strength of GB decreased significantly when using EDTA (3 d storage, P<0.05). TM application only increased the μTBS of GB (no EDTA) and SB (with EDTA) after 3 d (P≤0.02). Comparing the adhesives after 3 d of storage, CSE exhibited the greatest μTBS values followed by GB and SB (P≤0.02). The factors of adhesive, EDTA, and TM did not show any significant impact on μTBS when specimens were stored for 6 months (P>0.05). The additional application of TM and EDTA for cavity preparation seems only to have a short-term effect, and no influence on μTBS of dentin bonds after a period of 6 months. 相似文献
2.
The preparation of calcium phosphate (CP) coating on alumina ceramics using electric pulse stimulating method has been investigated. The cup-shaped alumina ceramics were soaked in a simulated body fluid ( SBF), and a square pulse potential with frequency of 1 Hz and voltage of 110 V was applied between the inner and outer surfaces of the alumina cup. Surface morphology of CP coatings during different deposition periods was observed by a Philips XL-30 scanning electron microscope (SEM). Compositional analysis was examined by EDAX. The mechanism of nucleation and growth of CP coating was discussed. SEM result indicates that the coating comprises of a large number of tiny needle-like grains and has a porous microstructure. There is a strong bond between the deposited layer and Al2O3 substrate, which may be due to the gentle growth of the biomimetic method. The EDAX analysis indicates that main composition of the coating is calcium and phosphor. The formation of CP coating may be contributed to the stimulation of electric pulse and the high ions concentration which is 1.5 times of the concentration of SBF solution ( 1.5SBF solution). Such surface functionalization method by electric pulse potential can be used to prepare CP coating on various electric-insulating bioinert materials for improving their bioactive character. 相似文献
3.
Preparation of bone-like apatite coating on surface of Ti-25Nb-2Zr alloy by biomimetic growth method
A bone-like apatite layer consisting of nano-crystals of apatite phase was prepared on the surface of Ti-25Nb-2Zr alloy by chemical biomimetic growth method. TiNbZr alloy specimens were first oxidized at 500℃ for 2 h in the air. Then, they were immersed in 40℃ saturated Na2HPO4 solution for 15 h and 25 ℃ saturated Ca(OH)2 solution for 8 h in turn for pre-calcification. The pre-calcified specimens were immersed in modified simulated body fluid up to 15 d for biomimetic growth. After common oxidization, amorphous titania and anatase were detected on the specimen surface. Except for the substantial amount of calcium and phosphorus, no new phase appeared on the pre-calcified specimens. After the coating process, it was found that the (002) orientation was the preferred orientation during the growing period of hydroxyapatite. The inorganic composition and structure of the coating are very similar to those of human thigh bone, which will be advantageous for its application as biomedical material. 相似文献
4.
以Na2WO4和C12H25NH3·Cl作原料,通过液相沉淀法制备了WO3纳米粉体,再用稀土硝酸铕浸滞法制备了铕掺杂的WO3纳米粉体,并采用透射电子显微镜、紫外-可见漫反射吸收光谱和X-射线衍射对其结构进行了表征.以可溶性染料罗丹明B光催化降解反应为探针反应,考察了铕掺杂的WO3纳米粉体的光催化性能.实验结果表明,铕掺杂能拓展WO3的光响应范围,显著提高WO3对罗丹明B的光催化降解效率和光稳定性. 相似文献
5.
以NazWO4和C12H25NH3·Cl作原料，通过液相沉淀法制备了WO3纳米粉体，再用钛酸胶体浸滞法制备了TiO2包覆的WO3纳米粉体，并采用透射电子显微镜、紫外-可见漫反射吸收光谱和X-射线衍射对其结构进行了表征．实验结果表明，TiO2包覆WO3的光响应范围扩大，吸附量增大，显著提高了WO3对可溶性染料罗丹明B的光催化降解活性和光稳定性． 相似文献
6.
采用罗丹明B作为目标降解物,考察了几种离子对光催化降解罗丹明B脱色率的影响.结果显示,低浓度的Ca2＋和Al3＋对罗丹明B的脱色率影响不明显,但是当它们的浓度增加到一定值后,则脱色率明显下降;当Fe3＋的浓度为0.2 ～0.5 mmol·L-1时,其对光催化降解罗丹明B有一定的促进作用,继续增加Fe3＋的浓度,反而起到明显的抑制作用;Cu2＋对光催化降解罗丹明B具有显著的抑制作用;Na＋、Cl-、NO3-、SO42-对光催化降解的影响均不明显,有些离子的影响机制有待进一步研究. 相似文献
7.
For reinforced concrete structures located along the seaside, the penetration of chloride ions into concrete may be a threat to the durability of the structures. Experimental investigations were carried out to study the effect of chloride content on the bond behavior between concrete and fiber reinforced polymer (FRP) plates. Direct shear tests were conducted on the FRP strengthened concrete members. Before testing, the specimens were immersed in NaCl solutions with concentrations ranging from 3%—15% for different time (0—120 d). Then, the specimens were dried and tested to obtain the initial and ultimate debonding loads, together with strain distributions along the FRP plates of different load values. The correlations between chloride content and debonding parameters are established. Test results show that the debonding parameters are closely related to the immersing time rather than the chloride content of the solution. 相似文献
8.
以Na2WO4和C16H33(CH3)3NBr为原料,通过液相沉淀法制备了WO3纳米粉体,用钛酸胶体溶液浸滞法制备了TiO2掺杂的WO3纳米粉体,再用Gd(NO3)3溶液浸滞TiO2掺杂的WO3纳米粉体法制备了稀土Gd和TiO2共掺杂的WO3纳米粉体,并采用透射电子显微镜、紫外-可见漫反射吸收光谱和X-射线衍射对其结构进行了表征.实验结果表明,稀土Gd和TiO2共掺杂拓展了WO3的光响应范围,提高了对可溶性染料罗丹明B(RB)的吸附作用,使WO3对RB的光催化降解活性和光稳定性得到了显著提高. 相似文献
9.
采用共沉淀法合成了Ag2O/NaNbO3复合光催化剂,并利用X射线衍射(XRD)和扫描电子显微镜(SEM)分别对其物相和形貌进行表征,用紫外可见漫反射光谱仪对其光学性质进行研究。在可见光下以罗丹明B(RhB)为目标降解物,检测了Ag2O/NaNbO3光催化剂的光催化性能。结果表明,与纯的Ag2O和纯的NaNbO3相比,Ag2O/NaNbO3复合光催化剂具有较高的光催化活性,其光催化活性的提升可能归结于p-n结的形成,使得光生电子空穴对的复合机率大大降低。 相似文献
10.
In this study, the effect of steel fibers coated with chemically reactive enamel (CRE) on the system response of concrete structures with reinforcing bars has been investigated for the first time. In particular, the ultimate strength, ductility, and failure mechanism of 24 reinforced concrete slabs were experimentally characterized under static and blast loads. CRE coating applied on steel bars reduced the crater area of slabs under blast loads by up to 20%; it slightly increased the strength of slabs and significantly reduced the strength degradation of slabs when increasingly deflected under static loads, making the slabs more ductile. CRE coating applied on steel fibers increased the strength of slabs by up to 16% under static loads. The influence of CRE coating applied on both steel fibers and bars may be taken into account by introducing a coating factor in the range of 0.57<β<1.0 in the American Concrete Institute (ACI) development length equation. 相似文献
11.
通过对河南地区某焦煤不同粒级试样黏结指数G值和奥亚膨胀度的测定分析,发现不同粒级的某焦煤黏结指数G值和奥亚膨胀度都呈规律性地变化,且两指标之间存在较好的相关性,粒度小于0.3mm以后其黏结性和膨胀性都劣化严重。研究结论可用于指导选择炼焦煤的粉碎工艺。 相似文献
12.
排水性沥青路面上中面层层间结合状况研究 总被引：1，自引：0，他引：1
通过环氧树脂、SBS改性乳化沥青、SBS改性热沥青和H#桥面防水材料等4种粘结层材料组合试件的剪切试验,对影响排水性路面的行车荷载、温度和水等外部因素进行了研究和分析.试验结果表明,温度升高会造成层间结合能力的降低,层间剪切强度与温度之间的关系接近一条对数曲线.在实际路面中,行车荷载作用中心区域下的剪切强度较其他部位要小.冻融和饱水等水损害都明显地降低了路面抗剪强度,破坏了上中面层间的层间结合.荷载、温度和水等因素的作用会对层间结合状况产生一定的不利影响,需要通过优选粘结层材料来提高排水性路面的耐久性. 相似文献
13.
采用半连续种子乳液聚合法,将反应性乳化剂A引入丙烯酸酯乳液聚合体系,制备了丙烯酸酯乳液胶粘剂.实验结果表明:所制乳胶具有核/壳结构,核/壳问形成了化学键连接;反应性乳化剂参与了化学反应.是以共价键的方式与高分子结合的;随着反应性乳化剂用量的增加.单体转化率及剥离强度逐渐降低;当反应性乳化剂用量为2%时聚合物耐水性较好;乳胶对极性与非极性塑料薄膜、非极性与非极性塑料薄膜均有良好的粘接能力. 相似文献
14.
氰酸酯树脂是一种新型的高性能热固性树脂,介电性能优异,在宽的频率范围内介电常数和介电损耗因子的变化很小,优异的耐湿热性能和力学性能．是一种有广泛应用前景和强劲市场竞争力的材料。综述了氰酸酯树脂增韧改性的几种主要研究方法。其中包括橡胶增韧法、热固性树脂增韧法、热塑性树脂增韧法、不饱和物增韧法、刚性粒子增韧法和有机硅增韧法等,对其研究方法和增韧机理进行评述．并对目前氰酸酯树脂的研究现状及发展趋势进行了探讨。 相似文献
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16.
The degradation characteristic of 4-bromdiphenyl ether （BDE-4） was investigated in different solutions.The study indicates that the process of direct degradation of this compound is dependent upon the bromine and the ether bond connected to diphenyl by electron beam.laser flash photolysis was employed to determine the degradation of each species （cationic,neutral,and anionic）.From these data,intermediate products of BDE-4 degradation were shown for direct irradiationdegradation.The neutral radical was formed during the photolysis of these compounds.For all the compounds,diphenyl ether and hydroxybiphenyl were observed as common products.Reaction of the BDE-4 under electron beam was debromide.The debromide rate of BDE-4 at pH=5.5 is somewhat lower than that of BDE-4 at pH=10.0.The decomposition rate for BDE-4 is 99.8% at pH=10.0 on the dose of 14 kGy.BDE-4 from its radical could provide bromine ion into water and the cation radical of BDE-4 formed quickly recombine with hydrogen radical and formed phenyl ether. 相似文献
17.
Experimental Study on Decolorization and Degradation of Reactive Brilliant Red X—3B in a White Rot Fungal Biofilm Reacor 总被引：1，自引：0，他引：1
Experimental results of an azo dye(reactive brilliant red X-3B,RBR X-3B) decolorization and degradation in a white rot fungal biofilm reactor were introduced and discussed.The fungal biofilm reactor is highly potential for dye decolorization and degradation with the highest decoloring rate of 95% within 96 hours reaction time at initial pH 4.5 under high nirogen level (HN) (24mmol/L ammonium tartrate)condition.Experimental conditions.such as nutrient nitrogen levels in reaction mixture and initial pH,significantly affected dye decolorization and degradation.Effluents from this bioilm reactor can be well treated to meet the discharging requirements by use of chemical flocculation.RBR X-3B was first absorbed onto fungal biomass and then degraded gradually,The SH-13 fungus monopolized the biofilm throughout the experiments,though the reactor was exposed to open air for 4 months. 相似文献
18.
《International Journal of Educational Research》2006,45(6):325-340
For Malaysian adolescents, writing in English covers various forms and serves a range of purposes. Outside the formal school context, students engage in more personalized forms of writing. This paper examines one such form, namely, the writing of short messages, using a sociocultural perspective of literacy as a social discursive practice that implicates identity construction. This paper draws on a larger qualitative study which looked at school and personal writing by a class of Form 4 (Year 10) students in an urban school in Malaysia. Data were taken mainly from student interviews and students’ written products during six months of fieldwork. Findings from the study showed students’ informal writing involved new hybrid forms of English and included the use of a mixture of short forms, “Penang English” and Net English. This study has implications for the English literacy education of Malaysian high school students learning ESL while immersed in a contemporary digital and Internet culture. 相似文献
19.
针对玄武岩纤维增强树脂基复合筋(BFRP)在混凝土环境中的耐碱性能进行了加速腐蚀试验研究.腐蚀试验环境包括3种,分别为自来水、盐水及室内空气环境,将包裹有混凝土保护层的BFPR筋试件分别放置在上述3种环境中,试验同时采用碱溶液直接浸泡BFRP筋作为对比,对直接碱溶液浸泡环境与混凝土包裹环境之间的加速系数进行了研究.试验采用60℃的高温进行加速.试验结果表明:自来水和盐水浸泡对于包裹有混凝土的BFRP筋试件没有明显差异.分析认为,与混凝土内部高碱性的孔隙溶液接触是BFRP筋退化的主要原因,当经受高温和高湿环境共同作用时,混凝土环境中BFRP筋的退化将明显加速;BFRP筋的退化速率在初期较快,随着龄期的增长,退化速率降低.基于试验数据分析表明,对于所采用的BFRP筋,60℃饱和吸湿混凝土环境下,BFRP筋2.18 a的退化程度与60℃碱溶液直接浸泡环境下1 a的退化程度相当. 相似文献
20.
Mu-zi Li Jin-rui Wang Hong Liu Xia Wang Kang Gan Xiu-ju Liu De-li Niu Xiao-qing Song 《Journal of Zhejiang University. Science. B》2016,17(9):703-711