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黄元乔 《湖北第二师范学院学报》2009,26(8):30-32
采取液相共沉淀法沉淀出前驱复合氢氧化物,再用高温固相焙烧的方法合成了多元掺杂的氧化物正极材料LiaNi0.9Co0.1Fe0.03O2,用电化学实验方法研究了材料的电化学性能。结果表明:通过预处理后合成的电极材料具有比较好的电化学性能,首次充放电比容量可达到168.9和167.1mAh·g^-1,充放电电流效率可达98.9%。 相似文献
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黄元乔 《湖北第二师范学院学报》2009,26(2):4-6
采取三种方法合成了镍钴酸锂电极材料LiaNi0.7Co0.3O2用电化学实验方法研究了合成方法对材料的电化学性能的影响,材料用XRD表征。结果表明:通过预处理后合成的电极材料具有较好的电化学性能,首次充放电比容量可达到196.5和167.9mAh·g^-1。 相似文献
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采取三种方法合成了镍钴酸锂电极材料Lia Ni0.7Co0.3O2,用电化学实验方法研究了合成方法对材料的电化学性能的影响,材料用XRD表征.结果表明:通过预处理后合成的电极材料具有较好的电化学性能,首次充放电比容量可达到196.5和167.9 mAh·g-1. 相似文献
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本文采用流变相法合成纳米尺寸锂离子电池正极材料LiFePO4/C,并用X射线衍射(XRD),扫描电镜(SEM),透射电镜(SEM),热分析(TG-DSC)以及恒流充放电测试等方法进行结构和电化学性能表征。结果表明此方法合成的LiFePO4/C复合材料的粒径为50nm,表层的碳膜厚度为1~2nm,具有较好的振实密度,在充放电循环过程中有稳定的充放电平台和较高的循环稳定性以及良好的高倍率性能。 相似文献
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井玉龙 《河南科技学院学报》2009,37(4):40-42
以共沉淀氢氧化物Ni1/3Co1/3Mn1/3(OH)2和LiOH·H2O为原料,采用流变相反应法(简称RPR法)在950℃煅烧15 h合成了锂离子电池正极材料LiNi1/3Co1/3Mn1/3O2.用X-射线衍射仪(XRD)、扫描电子显微镜(SEM)、电化学工作站、充放电仪等设备测试了材料的结构和电化学性能,XRD表明,合成的材料具有良好的α-NaFeO2层状结构. 相似文献
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采用溶胶凝胶模板结合煅烧的方法,合成得到磷酸钛介孔材料,研究了煅烧温度对磷酸钛介孔材料的介孔结构及其电化学性能的影响;分别采用了X-射线粉末晶体衍射技术(XRD)、低温N2吸脱附技术、高分辨透射电子显微技术(HRTEM)及元素分析等方法对样品进行了表征. 实验结果表明,高温煅烧对材料的介孔结构不利,并使材料晶体化;充放电测试结果表明,在500℃下煅烧得到的材料表现出较好的电化学性能,在150mA/g下充放电,材料首次放电容量高达94mAh/g,而650℃时的材料只有64mAh/g. 相似文献
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采用共沉淀制备前驱体,微波高温固相烧结制备富锂正极材料0.5Li2Mn O3·0.5Li Ni1/3Co1/3Mn1/3O2.通过X射线衍射(XRD)、电镜扫描SEM、循环伏安(CV)、充放电性能等材料结构的表征和电化学性能测试,研究了不同烧结时间(微波3 min、5 min、7 min、15 min)对材料结构电化学性能的影响.发现较佳的合成条件所合成的富锂正极材料0.5Li2Mn O3·0.5 Li Ni1/3Co1/3Mn1/3O2结构是α-Na Fe O2型,为二维层状结构.在2.0~4.8 V的截止电压范围、17 m Ah·g-1的电流密度,首次放电容量为284.6 m Ah·g-1,20个循环容量的保有率为75.6%.通过微波高温烧结合成正极材料,研究了制备工艺对材料结构和电化学性能的影响,并探讨了该体系的应用前景. 相似文献
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硼对金属间化合物Ni_3Fe氢气诱发环境氢脆的影响(英文) 总被引:1,自引:0,他引:1
In this paper the tensile properties of both ordered and disordered Ni-24Fe and Ni-24Fe-0.03%B(wt%)alloys in gaseous hydrogen was investigated.The result shows that the ductility of the disordered Ni_3Fe is significantly larger than that of ordered material in gaseous hydrogen.However,the ductility of ordered Ni3Fe doped with 0.03%B is nearly the same as that of disordered one indicating the obvious suppressing effect of boron on the H_2-induced embrittlement.Based on the segregation behavior of boron in Ni_3Al,it is proposed that the suppressing effect of boron in Ni_3Fe on the H_2-induced embrittlement is attributed to the segregation of boron on grain boundaries,thereby reducing the hydrogen diffusivity along the grain boundaries. 相似文献
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INTRODUCTION Chlorophenols (CPs) are chemicals widely used in industry to manufacture insecticides, herbicides, fungicides, biocides, and dye, are also found in the effluent of the pulp and paper mill industry, and are mainly man-made compounds, and have been recog-nized as organic pollutants of air, groundwater, soil and sediments. They are carcinogenic and stable in water. Most chlorophenols are listed as priority pol-lutants by the US Environmental Protection Agency (1988) due to th… 相似文献
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The objective of the present study was to compare the toxicity and availability of Fe(II) and Fe(III) to Caco-2 cells. Cellular
damage was studied by measuring cell proliferation and lactate dehydrogenase (LDH) release. The activities of two major antioxidative
enzymes [superoxide dismutase (SOD) and glutathione peroxidase (GPx)] and differentiation marker (alkaline phosphatase) were
determined after the cells were exposed to different levels of iron salts. The cellular iron concentration was investigated
to evaluate iron bioavailability. The results show that iron uptake of the cells treated with Fe(II) is significantly higher
than that of the cells treated with Fe(III) (P<0.05). Fe(II) at a concentration >1.5 mmol/L was found to be more effective in reducing cellular viability than Fe(III).
LDH release investigation suggests that Fe(II) can reduce stability of the cell membrane. The activities of SOD and GPx of
the cells treated with Fe(II) were higher than those of the cells treated with Fe(III), although both of them increased with
raising iron supply levels. The results indicate that both Fe(II) and Fe(III) could reduce the cellular antioxidase gene expression
at high levels.
Project supported by the International Cooperative Project from the Ministry of Science and Technology of China (No. 2006DFA31030),
the Bureau of Science and Technology of Zhejiang Province (No. 2006C32019) and HarvestPlus-China (No. 8022), and the Program
for Changjiang Scholars and Innovative Research Team in University of China (No. IRT0536) 相似文献
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张延琪 《安徽技术师范学院学报》2013,(6):48-56
以单分散的Fe3O4微球(粒径为200 nm)为核,通过水热碳化和原位还原,合成了核壳结构的碳包覆复合材料Fe3O4/C/Pd(0),研究了其催化Suzuki反应的活性及磁分离回收特性.实验结果表明:Fe3O4/C/Pd(0)热稳定性好,可在空气氛围下高效地催化碘代、溴代芳烃与苯硼酸的Suzuki偶联反应.该催化剂还表现了非常好的可循环性,连续使用五次依然能保持很高的催化活性,为进一步拓展碳包覆磁性材料在催化领域的应用积累了经验. 相似文献
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柳长宇 《西安文理学院学报》2014,(1):71-73
通过实验制备出了Fe3O4、Fe3O4/C、Fe3O4/C/Pd纳米粒子,并将其应用于Suzuki偶联反应.以Fe3O4为载体通过溶剂热法将C包覆在Fe3O4上,再在得到的复合材料上包覆Pd得到Fe3O4/C/Pd催化剂.通过X-射线衍射(XRD)和透射电子显微镜(TEM)对产物进行表征,并对结果进行粒径形貌分析.实验结果表明,Suzuki反应在以DMF/H2O(V/V=1)为溶剂,Na2CO3为碱时,在反应温度为80℃下,反应5 h时催化剂的催化性能最佳. 相似文献
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采用静电纺丝技术制备了PVP/[Co(NO3)3+Ni(CH3COO)2+Fe(NO3)3]复合纤维,通过X射线衍射(XRD)、扫描电镜(SEM)和振动样品磁强计(VSM)对复合纤维及其焙烧产物进行了表征,较为系统地考察了制备参数,如PVP含量、醇/水比例、电场强度以及无机盐含量对复合纤维形貌和直径的影响,获得了最佳制备条件。将所得复合纤维在550℃焙烧2h可以制得单相尖晶石结构的晶态Co0.5Ni0.5Fe2O4纳米纤维,其平均直径约为80nm,在室温下具有良好的磁性,比饱和磁化强度和矫顽力分别为52.3A.m2/kg和81.0kA/m。 相似文献
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1 Introduction IronaluminidesbasedonFe3 Alhavemanyadvantagesforstructuralusesatelevatedtemperaturebecauseoftheirexcellentcorrosionresistanceandrelativelylowmaterialcost.However,thesealloyshavenotyetfoundwidespreadusebecausetheyexhibitpoorductilityandbr… 相似文献