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1.
In this paper, a new ternary non-azeotropic mixture of HFC-161/125/143a (0.15/0.45/0.40 in mass fraction), as a promising
mixed refrigerant to R404A, is presented. The ozone depletion potential (ODP) of the new refrigerant is zero and its basic
thermodynamic properties are similar to those of R404A, but its global warming potential (GWP) is much smaller than those
of R507A and R404A. Meanwhile, theoretical calculations show that, under the working condition I (the average evaporation
temperature: −23 °C, the average condensing temperature: 43 °C, the superheat temperature: 28 °C, the subcooling temperature:
5 °C), the volumetric refrigerating effect and specific refrigerating effect of the new mixture are 2.33% and 15.48% higher,
respectively, than those of R404A. The coefficient of performance (COP) of the new mixture is 5.19% higher than that of R404A
and the pressure ratio of the new mixture is 0.82% lower than that of R404A. Equally, under the working condition II (the
average evaporation temperature: −40 °C, the average condensing temperature: 35 °C, the superheating temperature: 30 °C, the
subcooling temperature: 5 °C), the volumetric refrigerating effect and specific refrigerating effect of the new mixture are
2.24% and 20.58% higher, respectively, than those of R404A. The COP of the new mixture is 4.60% higher than that of R404A
and the pressure ratio of the new mixture is similar to that of R404A. The performances of the new mixture and R404A are compared
in a vapor compressor refrigeration apparatus originally designed for R404A under several working conditions (condensing temperatures:
35–45 °C, evaporation temperatures: −40–−20 °C). Experimental results show that the new mixture can obtain a higher COP, by
6.3% to 12.1%, and a lower pressure ratio, by 1.8% to 6.6%, compared to R404A; although the discharge temperature of the new
mixture is slightly higher than that of R404A. The advantages of the new mixture will be further verified in the actual system. 相似文献
2.
Theoretical and experimental analysis of a new refrigerant mixture BY-3 was conducted based on a single-stage vapor compression refrigeration system. The water-water heat pump system used BY-3 to produce hot water when the low temperature was 20 ℃. The following results were obtained: the highest temperature at the condenser outlet reached about 85 ℃; when the difference between the water temperatures at the condenser outlet and the evaporator inlet was less than 40 ℃, the coefficient of performance (COP) was larger than 4; when the difference reached 55 ℃, the COP still kept 3; the discharge temperature of BY-3 was lower than 100 ℃, and the refrigerant vapor pressure kept lower than 1.8 MPa. When the water temperature at the condenser outlet reached over 85 ℃, nearly a 5 ℃ superheating temperature was maintained. 相似文献
3.
This paper proposes a new approach to the performance optimization of an auto-cascade refrigerator (ACR) operating with a
rectifying column and six types of binary refrigerants (R23/R134a, R23/R227ea, R23/R236fa, R170/R290, R170/R600a, and R170/R600)
at a temperature level of −60 °C. Half of the six binary refrigerants are nonflammable, of which the 0.5 and the 0.6 mole
fractions of R23 for the R23/R236fa possess the most prospective composition for the medium and low suction pressure compressors,
respectively. The remaining three binary refrigerants are flammable but with low global warming potentials, of which the 0.6
mole fraction of R170 for the R170/R600 is the most prospective one. The results show that the overall matching as well as
local matching of heat capacity rates of hot and cold refrigerants in the recuperators are important for the improvement of
coefficient of performance of the cycle, which can be adjusted through the simultaneous optimization of the pressure level
and composition. The new approach proposed also offers a wider range of applications to the optimization in performance of
the cycle using multi-component refrigerants. 相似文献
4.
Combined heat and power (CHP) coal-fired plants and heat-only boilers are still working as main heat sources in North China. These provide high temperature water on the primary side of district heating (DH) systems. There can be large temperature differences between the primary side and secondary side deployed in low temperature district heating (LTDH) of buildings. In this paper, a LTDH system, integrated with an organic Rankine cycle (ORC) system, is presented and evaluated on how to utilize the limited temperature difference between the primary and secondary sides in a substation. Two cases are illustrated of the performance of two modes (series or parallel connection) and energy efficiencies of the configurations with or without an ORC system. The results showed that the integrated ORC system could provide sufficient power for the circulating pumps in the DH system. The integration of the ORC leads to only a very slight decrement on the supply water temperature. Generally, the series mode can generate the maximum output power from an integrated ORC system. The parallel mode showed more flexibility on the adjustment of output power from the ORC system, especially where domestic hot water is needed. When the cold tap water was used as a cooling stream in the condenser of an ORC system before preparing to be the domestic hot water, it is very helpful in improving the performance of the ORC and increasing the energy efficiency of the DH system. 相似文献
5.
The production of elastase by Bacillus sp. EL31410 at various temperatures was investigated. In order to study the effect of temperature on elastase fermentation,
different cultivation temperatures, ranging from 39 °C to 28 °C, were evaluated in shake flask. The result indicated that
37 °C was best for cell growth at earlier stage; while maximum elastase activity was obtained when the cells were cultivated
at 30 °C. This result was verified by batch fermentation in 5-L bioreactor under 37 °C and 30 °C temperature, respectively.
The specific cell growth rate at 37 °C was higher than that at 30 °C during earlier stage of cultivation. The maximum value
[5.5 U/(h·g DCW)] of elastase formation rate occurred at 24 h at 30 °C compared to 4.6 U/(h·g DCW) at 30 h at 37 °C. Based
on these results, two-stage temperature shift strategy and oscillatory temperature cultivation mode were evaluated in the
next study. When compared to single temperature of 37 °C or 30 °C, both two-stage temperature shift strategy and oscillatory
temperature strategy improved biomass but did not yield the same result as expected for elastase production. The maximum biomass
(both 8.6 g/L) was achieved at 30 h at 37 °C, but at 42 h using two-stage temperature cultivation strategy. The highest elastase
production (652 U/ml) was observed at 30 °C in batch process. It was concluded that cultivation at constant temperature of
30 °C was appropriate for elastase production by Bacillus sp. EL31410.
Project (No. 20276064) supported by the National Natural Science Foundation of China 相似文献
6.
A micro turbo-expander capable of high working speed was specially manufactured for use in an organic Rankine cycle (ORC).
A series of tests were executed to examine the performance of the machine. In the experiment, the machine was tested under
different inlet pressure conditions (0.2–0.5 MPa). Data such as the compressed air pressure, temperatures of the inlet and
the outlet, rotational speed, and electric power generation were analyzed to discover underlying relationships. During the
test, the rotational speed of the machine reached as high as 54 000 r/min, the peak value of the temperature drop between
the inlet and the outlet reached 42 °C, the maximum electric power generated by the motor-generator attached to the machine
reached 630 W, and the efficiency of the machine reached 0.43. 相似文献
7.
Growth kinetics of the most stable polymorph of calcium carbonate,calcite,has been studied in seeded stirred batch experiments in MEG-water solutions at 40 ℃ and 70 ℃,conditions relevant for the processing of natural gas.It was found that MEG changes the growth order from two in pure water to one in solvent mixtures of MEG and water.Assuming parabolic growth (growth order is equal to two),it could be shown that MEG decreases the growth rate constant for calcite from 0.52 nm/s to 0.11 nm/s (70 ℃) when the MEG-content is increased from 0 wt% MEG to 65 wt% MEG.Decreasing the temperature from 70 ℃ to 40 ℃ has a similar effect on the growth rate constant as raising the level of MEG to 65 wt%. 相似文献
8.
Performance of a single-stage Linde-Hampson refrigerator operating with binary refrigerants at the temperature level of-60 ℃＊ 总被引：1，自引：1，他引：0
The optimization of the performance of a single-stage Linde-Hampson refrigerator （LHR） operating with six different binary refrigerants （R23/R134a, R23/R227ea, R23/R236ea, R170/R290, R170/R600a and R170/R600） with ozone depletion potentials （ODPs） of zero was conducted using a new approach at the temperature level of-60℃. Among these binary refrig- erants, the 0.55 and the 0.6 mole fractions of R23 for R23/R236ea are the most prospective nonflammable ones for the medium and low suction pressure compressors, respectively. For these two kinds of compressors, the 0.6 and the 0.65 mole fractions of R170 for R 170/R600, respectively, are the most prospective binary refrigerants with low global warming potentials （GWPs）. The results of optimization of pressure levels indicate that the optimum low pressure value for coefficients of performance （COP） is achieved when the minimum temperature differences occur at both the hot and the cold ends of the recuperator at a specified composition and pressure ratio. Two useful new parameters, the entropy production per unit heat recuperated and the ratio of heat recuperating capacity to the power consumption of the compression, were introduced to analyze the exergy loss ratio in the recuperator. The new approach employed in this paper also suggests a promising application even to the optimization of the performance with multi-component refrigerants. 相似文献
9.
Characteristics of fluoride emission from five clay minerals (montmorillonite, kaolinite, vermiculite, geothite, and allophane)
as affected by temperature, heating time and addition of calcium compounds were studied. Marked increase of the fluoride emission
rate was noticed with increase of temperature. The fluoride release, began at 500°C–600°C, and the main bulk of the fluoride
emission occurred at the temperature of about 800°C. The loss of crystalline water was primarily responsible for the increase
of fluoride emission. When minerals were heated at 800°C, The fluoride emission rate from the clay minerals reached the highest
after heating for 1 hour. The samples treated by CaO, CaCO3, Ca(OH)2, Ca3(PO4)2, and CaSO4 had 55.45%, 59.58%, 46.45%, 54.31%, 31.25% reduction in the fluoride emission from montmorillonite at the temperature of
800°C, respectively. CaCO3 had the highest fluoride fixing capacity compared to other calcium compounds.
Project supported by the Special Funds for Major State Basic Research Project 973 (G1999011809) and Natural Science Foundation
of Zhejiang Province. 相似文献
10.
Response to temperature stress of reactive oxygen species scavenging enzymes in the cross-tolerance of barley seed germination 总被引：1，自引：0，他引：1
A number of studies have shown the existence of cross-tolerance in plants, but the physiological mechanism is poorly understood.
In this study, we used the germination of barley seeds as a system to investigate the cross-tolerance of low-temperature pretreatment
to high-temperature stress and the possible involvement of reactive oxygen species (ROS) scavenging enzymes in the cross-tolerance.
After pretreatment at 0 °C for different periods of time, barley seeds were germinated at 35 °C, and the content of malondialdehyde
(MDA) and the activities of ROS scavenging enzymes were measured by a spectrophotometer analysis. The results showed that
barley seed germinated very poorly at 35 °C, and this inhibitive effect could be overcome by pretreatment at 0 °C. The MDA
content varied, depending on the temperature at which seeds germinated, while barley seeds pretreated at 0 °C did not change
the MDA content. Compared with seeds germinated directly at 35 °C, the seeds pretreated first at 0 °C and then germinated
at 35 °C had markedly increased activities of superoxide dismutase (SOD), ascorbate peroxidase (APX), catalase (CAT), and
glutathione reductase (GR). The SOD and APX activities of seeds germinated at 35 °C after 0 °C-pretreatment were even substantially
higher than those at 25 °C, and GR activity was similar to that at 25 °C, at which the highest germination performance of
barley seeds was achieved. These results indicate that low-temperature pretreatment can markedly increase the tolerance of
barley seed to high temperature during germination, this being related to the increase in ROS scavenging enzyme activity.
This may provide a new method for increasing seed germination under stress environments, and may be an excellent model system
for the study of cross-tolerance. 相似文献
11.
Viscosity reduction is an important process in mining heavy oil.To predict the temperature variation and viscosity variation of heavy oil in flow direction,computational fluid dynamics(CFD) was adopted to simulate the process of heat transfer and flow in this paper.Moreover,an objective function,namely viscosity reduction efficiency,was established to analyze the effect of viscosity reduction.The results indicate that circulating hot water can reduce viscosity significantly,and that the effect of viscosity reduction depends on the inlet temperature and inlet volumetric flow rate of hot water.There is a maximum temperature of heavy oil in flow direction.With the inlet volumetric flow rate of 2.0m3/h and the inlet temperatures of 60,℃,70,℃ and 80,℃,viscosity reduction efficiencies are 94.6%,96.7% and 97.3%,respectively.With the inlet temperature of 70,℃ and the volumetric flow rates of 1.5m3 /h,2.0 m3/h and 2.5m3/h,viscosity reduction efficiencies are 94.4%,96.7% and 97.2%,respectively. 相似文献
12.
A novel voltage output integrated circuit temperature sensor 总被引：1，自引：0，他引：1
The novel integrated circuit (IC) temperature sensor presented in this paper works similarly as a two-terminal Zener, has breakdown voltage directly proportional to Kelvin temperature at 10 mV/℃, with typical error of less than ±1.0℃ over a temperature range from -50℃ to +125℃. In addition to all the features that conventional IC temperature sensors have, the new device also has very low static power dissipation ( 0.5 mW ) , low output impedance ( less than 1Ω), excellent stability, high reproducibility, and high precision. The sensor's circuit design and layout are discussed in detail. Applications of the sensor include almost any type of temperature sensing over the range of -50℃-+125℃. The low impedance and linear output of the device make interfacing the readout or control circuitry especially easy. Due to the excellent performance and low cost of this sensor, more applications of the sensor over wide temperature range are expected. 相似文献
13.
Black clay(BC) was used as a catalyst for the decolorization of Azure B dye by Fenton process. BC was modified by acid, alkali, distilled water, and calcination to check their changes in characterization and efficiency on decolorization of Azure B. Among three modified catalysts, maximum decolorization was obtained by acid-modified BC(AMBC) catalyst due to the highest removal of impurities, comparatively. The characterization of AMBC was done by Fourier-transform infrared spectroscopy and X-ray diffraction spectroscopy which show the presence of metal ion. The BET surface area, pore volume, pore size, and density of AMBC were calculated to be 79.402 m~2/g, 0.0608 m~3/g, 0.00306 nm, and 16 g/cm~3, respectively. The highest decolorization of 97.59% was achieved only in 10 min using AMBC at optimized calcination of 100 °C and 3 h of aging. AMBC was considered as the main catalyst for optimizing the different process parameters. Optimized conditions were obtained: pH 2, 0.2 mL of H_2O_2, catalyst dose 0.3 g, room temperature(30 °C), and stirring speed 400 r/min. The catalyst has showed excellent stability and reusability. It could remove more than 85% of color even after four cycles of run and less than negligible leaching of iron. AMBC has good recycling ability among other modified catalysts. To check the selectivity of catalyst, different dyes such as Congo red and mixed dye(mixture of Azure B and Congo red) decolorization were studied. In the present work, kinetic study was also carried out and a three-stage decolorization process was found. 相似文献
14.
A temperature sensor is demonstrated and fabricated by coating the single-mode tapered optical fiber with temperature-sensitive silicone rubber. It works on the change of the evanescent fields in the tapered optical fiber. Small changes in the refractive index of coating film greatly influence the power of evanescent fields, which modulate the transmission optical power in the waist region. The range of temperature measured is from 20°C to 70°C. The results show that the temperature sensor has high temperat... 相似文献
15.
The influence of calcination temperature on TiO2 nanotubes＇ catalysis for TiO2/UV/03 was investigated. TiO2 nanotubes （TNTs） were prepared via the sol-gel method and calcined at 300--700 ℃, which were labeled as TNTs-300, TNTs-400, TNTs-500, TNTs-600 and TNTs-700, respectively. TNTs were characterized by transmission electron microscopy （TEM） and X-ray diffraction （XRD）. It is found that TNTs calcined at 400 ℃ showed the best thermal stability. When the calcination temperature increased from 400 ℃ to 700 ℃, the special structure of tubes was destroyed and gradually converted into nanorods and/or particles. The transformation from anatase to rutile occurred at 600 ℃, and the rutile phase was enhanced when the calcination temperature was increased to over 600 ℃. The calcina- tion temperature＇s influence on TNTs＇ adsorption activity for for TiO2/UV/O3 was investigated in landfill leachate solution chemical oxygen demand （COD） and catalytic activity In landfill leachate solution, the adsorption activity of COD decreased in the reduced order of TNTs-300, TNTs-400, TNTs-500, TNTs-600 and TNTs-700. In photocatalytic ozonation, TNTs-400 showed the best catalytic activity while TNTs-700 exhibited the worst. In other three processes, the COD removal of TNTs-300/UV/O3 was higher than those of TNTs-500/UV/O3 and TNTs-600/UV/O3 in the first 20 rain, and then became close to those of the latter two in the following 40 rain. Compared with TNTs-300 and TNTs- 400, TNTs-600 had the best anti-fouling activity, while TNTs-500 and TNTs-700 had lower anti-fouling activity than the former three. In photocatalytic ozonation, the calcination temperature of 400 ℃ was appropriate when TNTs were obtained at the synthesis temperature of 105 ℃. 相似文献
16.
Méndez A Pérez C Montañéz JC Martínez G Aguilar CN 《Journal of Zhejiang University. Science. B》2011,12(12):961-968
The combined effects of pH and temperature on red pigment production and fungal morphology were evaluated in a submerged culture
of Penicillium purpurogenum GH2, using Czapek-Dox media with d-xylose as a carbon source. An experimental design with a factorial fix was used: three pH values (5, 7, and 9) and two temperature
levels (24 and 34 °C) were evaluated. The highest production of red pigment (2.46 g/L) was reached with a pH value of 5 and
a temperature of 24 °C. Biomass and red pigment production were not directly associated. This study demonstrates that P. purpurogenum GH2 produces a pigment of potential interest to the food industry. It also shows the feasibility of producing and obtaining
natural water-soluble pigments for potential use in food industries. A strong combined effect (p<0.05) of pH and temperature was associated with maximal red pigment production (2.46 g/L). 相似文献
17.
INTRODUCTION Located in subtropical monsoon area, the redsoil region in western Zhejiang, China, is one of themain cash crop production bases of this province. Dueto the climate, the temporal and spatial distribution ofrainfall varies greatly in this region. Only 15 percentof rainfall occurs in summer (July, August and Sep-tember), while about 60 percent of rainfall occurs inspring (from March to June). The region suffersdrought in summer and waterlogging in spring. Theparent ma… 相似文献
18.
A homogeneous theoretical model is developed to predict the performance of R22 and R290 in adiabatic capillary tubes. The model is based on conservation equations of mass, momentum and energy. Metastable both liquid and two-phase flow regions are considered in the model. In metastable two-phase region, superheated liquid is introduced into the metastable mixture viscosity and two methods are presented to evaluate it. The model is validated by comparing the predicted pressure and temperature profile and mass flow rate with several investigators′ experimental data of R22 and one of its alternatives R290 reported in literature. All of the predicted mass flow rates are within ±8% of measured values. Comparisons are also made between the present model and other investigators′ models or sizing correlation. The model can be used for design or simulation calculation of adiabatic capillary tubes. 相似文献
19.
Phosphate-accumulating aerobic granules cultivated in a sequencing batch reactor were composed of inner rod-shaped bacteria aggregates and outer twining filamentous bacteria. The influence of two-month storage under different conditions on the storage and subsequent reactivation performance of aerobic granules was investigated. After two-month storage the granules sealed at 4 ℃ in distilled water or normal saline (named granules A and granules B, respectively) could maintain their characteristics as before, while the granules idled in the reactor at room temperature (named granules C) exhibited decreased properties. During reactivation, granules A and granules B presented almost identical recovery performance, faster than granules C, in terms of phosphorus removal efficiency, mixed liquor suspended solids (MLSS), phosphate release and accumulating ability. The results suggest that hermetical storage at low temperature promoted the maintenance of the granular properties and the reviving behaviors of phosphateaccumulating aerobic granules, and storage medium had little influence on the storage and recovery performance. 相似文献
20.
Effect of temperature on the hydration process and strength development in blends of Portland cement and activated coal gangue or fly ash 总被引：1，自引：0，他引：1
This paper describes the results of an investigation into the effect of the variation of curing temperatures between 0 and
60 °C on the hydration process, pore structure variation, and compressive strength development of activated coal gangue-cement
blend (ACGC). Hardened ACGC pastes cured for hydration periods from 1 to 360 d were examined using the non-evaporable water
method, thermal analysis, mercury intrusion porosimetry, and mechanical testing. To evaluate the specific effect of activated
coal gangue (ACG) as a supplementary cementing material (SCM), a fly ash-cement blend (FAC) was used as a control. Results
show that raising the curing temperature accelerates pozzolanic reactions involving the SCMs, increasing the degree of hydration
of the cement blends, and hence increasing the rate of improvement in strength. The effect of curing temperature on FAC is
greater than that on ACGC. The pore structure of the hardened cement paste is improved by increasing the curing temperature
up to 40 °C, but when the curing temperature reaches 60 °C, the changing nature of the pore structure leads to a decrease
in strength. The correlation between compressive strength and the degree of hydration and porosity is linear in nature. 相似文献