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1.
《文物保护研究》2013,58(4):281-297
Abstract

Cellulose poultices are frequently used in stone and wall painting conservation for the purposes of soluble salt extraction, consolidation and cleaning. They have the reputation of being easy and pleasant to work with, have a neutral pH, high water absorption and plasticity, exhibit good conformance and adhesion to the substrate, and in most cases leave minimal residues after clearance. The cellulosic materials from which they are composed range from cotton wool, blotting paper or newspaper, to cellulose powders, the latter now by far the most common form of cellulose used today by conservators. Drawbacks of these products include poor water retention when applied to vertical surfaces, a tendency to redistribute salts further into the object substrate, and poor long-term treatment effectiveness for salt extraction. Hence cellulose poultices are used frequently due to good working properties, but apparently are in some situations not very effective. In this paper, existing knowledge of these poultices is outlined, followed by investigations undertaken to fill some of the knowledge gaps. Investigations include characterization of poultice properties such as pore size distribution and workability, and of moisture transport processes within poultice/substrate systems including moisture penetration depth, moisture distribution, and poultice shrinkage during drying. Cellulose powder products known under the trade name Arbocel®, extensively tested and used in conservation over several decades, were a particular focus. Resulting guidelines include counter-intuitive measures such as (when used for salt extraction purposes) the use of thinner poultices to reduce drying shrinkage and salt redistribution further into the substrate. The relatively uniform pore size distribution (around 10 μm) of Arbocel® poultices makes them more appropriate for salt extraction on substrates with a medium-coarse pore size (i.e. 15 μm and above), while on fine porous substrates (10 μm and below), the extraction will not be as efficient.  相似文献   

2.
In paper conservation ethanol is used as an antifungal agent. However, information on the antifungal efficacy of this alcohol is scarce and often inconsistent. In this study, we clarify if ethanol is effective and safe to use in paper conservation in the short as well as in the long term. None of the tested ethanol concentrations (5–100%) promoted conidia germination, but rather delayed or entirely inhibited it, depending on alcohol concentration and contact time. In a simulation of an interventive treatment of samples colonized by fungi, all the tested ethanolic solutions (30, 70, and 100%) revealed antifungal activity. The best results were obtained with 70% ethanol, showing fungicidal properties on four of the five-tested fungal species (Aspergillus niger, Cladosporium cladosporioides, Penicillium chrysogenum, and Penicillium corylophilum). No deleterious effects of 70% ethanol on the tested paper were observed either in the short or in the long term.  相似文献   

3.
The gellan hydrogel is used as a cleaning agent for paper artworks. The purposes of this work were to give the gellan hydrogel both a microbial resistance and a cytocidal action against the biodeteriogens using hydrolates. Broth microdilution assays were performed to identify the fungicidal action of 16 hydrolates vs 3 fungal strains. The study concerned the Minimal Fungicidal Concentration and pH, colour, and ultra-structural variations on all paper samples, by placing them in contact with GELYD (GELlan?+?hYDrolat). The in vitro tests showed that eight out of 16 hydrolates strongly inhibited fungal growth, but only two of them (Monarda fistulosa, Citrus aurantium subsp amara) showed in situ fungicidal action. Data indicate a new and interesting eco-innovative use of hydrolates, since GELYD is able not only to clean paper artworks, but also to kill the fungal cells present on paper that are potentially harmful for paper and operators.  相似文献   

4.
Despite substantial literature on the dyeing of textiles, there is a lack of research about colouring Japanese mending papers (tissue papers) used for paper conservation purposes. This study investigates the fungal bioreceptivity of Japanese tissue papers after they have been treated with various dyes and pigments. A variety of toning materials including plant dyes, watercolours, acrylic paints, inks, pastels, gouaches, and colour pencils are commonly used by conservators for paper toning purposes. In this study, two Japanese tissue papers (Yukyu-shi and Sekishu Mare) were treated with selected plant dyes, watercolours, and acrylic paints and then inoculated with fungal species. Quantitative real-time polymerase chain reaction (qPCR) was used to quantify the DNA from Aspergillus niger and Penicillium rubrum as a proxy for fungal species abundance before and after inoculation and artificial moist heat ageing. qPCR primers which were universal for fungi amplified DNA from papers inoculated with A. niger and P. rubrum and these species were found to grow less on treated Sekishu Mare and Yukyu-shi papers compared with untreated papers. Sekishu Mare papers treated with artists' acrylic paints were found to be more resistant to fungal growth than similarly treated Yukyu-shi papers. This study suggests that for the best long-term preservation outcomes for paper materials in archives, libraries, galleries, and museums, acrylic paints generally perform better in conservation terms than most plant dyes and watercolours, although most colourants displayed some bioinhibition.  相似文献   

5.
This paper studies the influence of poultice type and application techniques on the desalination efficiency of two limestone substrates having similar porosities (22–25%) but different pore size distributions: microporous Bateig Novelda and macro porous Tosca Rocafort stones. Three poultice types are compared: pure sepiolite (fine porous), sepiolite and aggregate (medium porous), and pure cellulose powder (coarse porous). Four application techniques are studied: (i) direct application on the stone, (ii) pre-wetting before poultice application, (iii) Japanese paper before application, and (iv) pre-wetting?+?Japanese paper before application. Samples were taken from poultices on the one hand, and from substrates at different depths on the other hand. Their content in soluble salts was estimated by ionic conductivity measurements. After three application runs, the best result for both substrates is achieved with the combined application of coarse- and fine-porous poultices (FPs) (desalination depth: 4.5/6?cm for macro/micro-porous substrates). The FP is also able to extract salts properly, but the desalination depth achieved is less important (3?cm). A direct poultice application without pre-wetting nor Japanese paper is to be preferred for both stone types.  相似文献   

6.
Microfibril angle (MFA) – the orientation of cellulose fibres in the S2 layer of the secondary cell wall – is a key determinant of the stiffness and strength of timber. The microfibril angle depends on the way in which the timber was grown and its position within the tree. Microfibril angle can be measured by X-ray diffraction and other methods, but the methods in current use are slow or require advanced instrumentation. The aim of this study was to explore the use of polarised Fourier transform infrared (FTIR) microscopy as a relatively fast and inexpensive method for measuring MFA in historic Scots pine (Pinus sylvestris L.). The FTIR measurements were calibrated against X-ray measurements of MFA in modern Scots pine. We observed a wide range in MFA values and a radial pattern of MFA similar to modern Scots pine in undecayed Scots pine heartwood from sixteenth and seventeenth century beams in Scottish secular buildings. The density of the heartwood was also similar to modern plantation-grown Scots pine despite the much slower growth rate recorded in the ring widths of the historic timber. The sapwood, which had been attacked by both insect pests and fungi, showed an erratic reduction in density and a large increase in MFA compared to the modern material. The increased sapwood MFA was attributed to selective destruction of the S2 layer of the wood cell walls by fungal decay. Using MFA measurements in conjunction with density offers the possibility to estimate the mechanical properties of sound historic pine timber, to detect fungal decay more sensitively than by density alone, and to distinguish between pest and fungal attack in a way that relates directly to the remaining mechanical performance of the timber.  相似文献   

7.
《文物保护研究》2013,58(4):258-273
Abstract

This paper describes the development and testing of a highly specific molecular tool for the identification of moulds on works of art, based on the two internal transcribed spacer regions (ITS1 and ITS2) of fungal ribosomal deoxyribonucleic acid (rDNA). The conventional identification of fungi in microbiology laboratories by means of phenotypic features and physiological tests is timeconsuming and often not capable of detecting all the species living on and in the substrate. Furthermore, fungi that are dead, which may also represent a potential health threat to the conservator, cannot be identified by these conventional methods. To complement the microbiological identification, a diagnostic DNA microarray was developed for the rapid and simultaneous detection and highly specific identification of 39 potentially pathogenic fungal species and 17 genera inhabiting works of art. Because this technique uses DNA hybridization-based genotypic identification, it provides a cultivation-independent characterization of moulds on works of art.  相似文献   

8.
《文物保护研究》2013,58(1):23-29
Abstract

Upon aging, paper documents and books become progressively damaged. Paper deacidification is a fundamental conservation intervention. In this study, we report on the use of nanoparticles of titanium dioxide (TiO2) and magnesium hydroxide (Mg(OH)2) associated with hydroxyethylcellulose (HEC) to inhibit acidification, photo-induced degradation, and biodeterioration of paper. With the aid of ultrasound, Mg(OH)2 nanoparticles with a narrow size distribution can be obtained through homogeneous precipitation in water. Furthermore, to demonstrate the efficacy of the nanocomposite and the performance of treated and untreated paper, photo- and thermal-induced degradation is discussed. The results show that using the controlled double-jet precipitation (CDJP) it is possible to synthesize Mg(OH)2 particles with a narrow size distribution (18–87 nm). The nanocomposite of Mg(OH)2–TiO2–HEC increases the durability of paper by imparting fungal growth resistance (D = 34.6 mm), moderate alkalinity (pH = 8.4), mechanical reinforcement (from 817–896 N/m), and UV protection. Additionally, there is a slight color difference (ΔE* = 0.8) between the treated and untreated paper. Both photodegradation and thermal degradation indicate that the paper treated with this nanocomposite (Mg(OH)2–TiO2–HEC) has increased stability.  相似文献   

9.
ABSTRACT

Boundary walls are neglected but important parts of historic urban environments, and they are often prone to serious deterioration. Understanding moisture and salt dynamics within boundary walls can help infer the causes and dynamics of deterioration. This investigation investigates the patterns of moisture, salt, and deterioration on a 300 year old limestone boundary wall in Worcester College, Oxford. Multiple methods to assess moisture and salts within and across the wall (electrical resistivity tomography, handheld resistivity-based moisture meter, paper pulp poultices, scanning electron microscopy, inductively coupled plasma optical emission spectrometry, and ion chromatography of small scale sampling of deteriorated limestone) were used in conjunction with decay mapping of both sides of the wall. The salt weathering strongly correlates with severely weathered zones at the wall and salts, mainly sulfates, seem to be the main agent of decay processes. The combined results demonstrate that the environmental influences driving stone decay can differ on a very small scale even at a comparatively simple structure like a boundary wall, and that repairs can have adverse effects if the patterns of salt and moisture dynamics are not sufficiently known.  相似文献   

10.
《文物保护研究》2013,58(4):308-313
Abstract

The oak timbers of the Swedish warship Vasa are deteriorating. High amounts of oxalic acid have been found along with a low pH and low molecular weight cellulose deep in the wood timbers. The iron-rich surface wood differs from the interior wood in that it displays higher pH and cellulose with higher molecular weight. The objective of this study was to determine why there is a difference in cellulose degradation, pH, and oxalic acid amount between the surface region and the interior of the Vasa timbers. Analysis of cellulose weight average molecular weight by size exclusion chromatography was performed, as well as quantification of oxalic acid and iron by high-performance anion exchange chromatography and atomic emission spectroscopy, respectively. It was found that a decrease in iron content coincides with an increase in oxalic acid concentration and a drop in pH at a certain depth from the wood surface. When iron-rich surface wood samples from the Vasa were mixed with an aqueous solution of oxalic acid, a fast increase of pH over time was observed. Neither interior wood poor in iron nor the fresh oak reference showed the same neutralizing effect during the time of measurement. This indicates that the presence of iron (rust) causes a neutralization of the wood, through the formation of iron(III) oxalato complexes, thus protecting the wood from oxalic acid hydrolysis. This effect was not observed to the same extent for other acids observed in Vasa wood (sulfuric, formic, glycolic, and acetic acids).  相似文献   

11.
《文物保护研究》2013,58(1):140-144
Abstract

This paper presents the program initiated to conserve the templete in the Mudéjar Cloister in the Royal Monastery of Our Lady of Guadalupe. The program included evaluation of the original materials, development of repair materials and design of a conservation program for the templete. The paper concentrates on the analysis and conservation of the stuccos of the templete, which is a typical mudéjar-style structure of molded brick with an exterior stucco finish. Samples of stucco from the templete were analyzed by microscopy, both reflected and transmitted light; acid digestion (gravim～tric analysis); water vapor transmission rate; and Fourier transform infrared spectroscopy. Samples of pigments and salts were identified by microchemical methods. Data from these analyses were used to develop a replication stucco mix and a grout mix that would be physically and chemically compatible with the existing materials. The process of developing the mixes is described. Application of these materials to the conservation of the templete is outlined. The stucco mix was used for repairing the upper stage of the templete, which was largely devoid of its original stucco coating, and the grout was used to stabilize the stuccos of the base, which were largely intact but detached from the underlying brick.  相似文献   

12.
ABSTRACT

In the Mogao Grottoes of Dunhuang, China, the ambient relative humidity (RH) fluctuation in the caves is the main cause for the deterioration that has been observed, especially the deterioration of the earthen plaster and wall paintings linked to the presence of NaCl and Na2SO4 salt contaminants. To help identify the mechanism responsible for this salt-related deterioration and provide a theoretical basis for the development of a preventive conservation regime, this study addressed the basic moisture adsorption mechanisms of earthen plaster with soluble salts by taking an experimental approach. It is shown that, as ambient RH increases, the moisture adsorption process of the plaster containing the soluble salts can be regarded to have three basic stages, as evidenced by the results of the moisture adsorption tests performed on earthen plaster samples with different NaCl or Na2SO4 contents at various humidity levels. The moisture adsorption mechanism and its determining factors at each stage are also analysed. In addition, it is suggested that the hygroscopicity of the plaster structure and the interaction between the different kinds of salts in the plaster, which makes the dissolution or hydration of the salt in the plaster pores much easier, should be considered more seriously regarding increases in the ambient RH in the caves.  相似文献   

13.
An in-depth scientific survey revealed the deterioration mechanisms affecting the ‘Santa Maria della Stella’ church in Saluzzo, Italy, where various salt crystallization processes are strongly damaging the building materials and artworks. Rainwater seepage permeates the vault and interior, causing: (1) epsomite growth as interstitial columnar crystals (resulting in pictorial coating detachment) or superficial, powdery efflorescence; (2) formation of nesquehonite/hydromagnesite crusts on wall paintings; and (3) nitratine growth causing pigment staining and detachment. These processes involve selective Mg2+ mobilization from magnesian-lime mortars and bacterial-induced formation of nitrates from guano, with consequent precipitation of degrading salts. The study confirms how characterization of all deterioration agents is fundamental to planning a viable cultural heritage conservation and restoration programme.  相似文献   

14.
ABSTRACT

Currently, there is a lack of research on the migration and distribution of soluble salt solutions in the pores of fragile silicate cultural relics, especially the thermodynamic changes during crystallization, and the forces causing the destruction of cultural relics. Thus, this paper used infrared thermal imaging analysis and extended depth-of-field microscopy to observe the changes in temperature, morphology, migration, and crystallization rate of Na2SO4 solution – the most typical solution that causes damages to cultural relics – in the crystallization process and in different capillary pores. The results show that the formation of soluble salt crystal nuclei and subsequent crystal growth mainly occurred in the liquid phase region below the ambient temperature, and then the salt crystals in the deliquescent state became more compact due to the attractive force generated from liquid-phase water evaporation. Additionally, three stages of migration and crystallization of the salt solution in different capillary pores were found. Large-area crystals appeared in the capillary pore with a large diameter, and bubbles were generated. This is likely because the surface tension of the Na2SO4 solution decreased with increasing concentration, and the solubility of the air dissolved at the solid–liquid interface of the mouth of the capillary pore and the pressure in the capillary pore decreased. A self-designed double-layer contact surface internal pressure method and extended depth-of-field microscopy were used to carry out real-time online observation of the force applied on the contact surface during the crystallization of the salt solution. It was found that the airflow determined the direction of capillary movement of the solution, and water migration determined the laminar flow in the capillary pore. Salt crystallization played a role in distortion and shape-fixation of pores. Small spikes in the mass indicated that the expansion–contraction force generated by the salt solution during the crystallization process was in a state of constant change, and the degree of expansion was always slightly more significant than the change caused by contraction. Expansion forces dominated the surface of the sample. In this paper, the change in crystallization and the forces of the soluble salt solution were analyzed.  相似文献   

15.
Salt crystallization is recognized as a major cause of damage to porous building materials, threatening the sustainable preservation of our valuable built heritage. Unfortunately, the crystallization behavior of the detected salt mixtures is complex and not fully understood. While the deliquescence points of single salts are well documented, this is not the case for salts in a mixture where one is confronted with the presence of different cations and anions. In this paper the salt content of the murals and the limestone tracery of the main entrance porch from the sixteenth century church of St. James in Liège, Belgium is investigated and related to the climatic conditions of its environment. Concerning the salt load, the research consists of hygroscopic moisture content measurements, quantitative ion analyses, and the prediction of phase equilibria using the thermodynamic model ECOS/RUNSALT. This model can predict the salt crystallization sequences of a particular ion mixture. The output is mathematically evaluated with collected temperature and relative humidity data, which enables the calculation of the number of salt crystallization–deliquescence cycles. The results show that even small amounts of salts can cause damage over a long period of time when the environment causes frequent cycles of crystallization–deliquescence over time. It is shown how a mixture of small amounts of (double) salts, including hygroscopic ones, can have a significant effect on the decay of historic building materials in the case of daily changing climatic conditions and periods of extreme drought. As a result, the crystallization of double salts and hygroscopic salts such as calcium nitrate cannot be ignored. The scientific method and the results are described.  相似文献   

16.
This paper reviews a number of studies comparing Thomson Scientific’s Web of Science (WoS) and Elsevier’s Scopus. It collates their journal coverage in an important medical subfield: oncology. It is found that all WoS-covered oncological journals (n = 126) are indexed in Scopus, but that Scopus covers many more journals (an additional n = 106). However, the latter group tends to have much lower impact factors than WoS covered journals. Among the top 25% of sources with the highest impact factors in Scopus, 94% is indexed in the WoS, and for the bottom 25% only 6%. In short, in oncology the WoS is a genuine subset of Scopus, and tends to cover the best journals from it in terms of citation impact per paper. Although Scopus covers 90% more oncological journals compared to WoS, the average Scopus-based impact factor for journals indexed by both databases is only 2.6% higher than that based on WoS data. Results reflect fundamental differences in coverage policies: the WoS based on Eugene Garfield’s concepts of covering a selective set of most frequently used (cited) journals; Scopus with broad coverage, more similar to large disciplinary literature databases. The paper also found that ‘classical’, WoS-based impact factors strongly correlate with a new, Scopus-based metric, SCImago Journal Rank (SJR), one of a series of new indicators founded on earlier work by Pinski and Narin [Pinski, G., & Narin F. (1976). Citation influence for journal aggregates of scientific publications: Theory, with application to the literature of physics. Information Processing and Management, 12, 297–312] that weight citations according to the prestige of the citing journal (Spearman’s rho = 0.93). Four lines of future research are proposed.  相似文献   

17.
ABSTRACT

Calcarenite stone samples from a historic building (Bizerte, Tunisia) were collected and treated under different environmental conditions with several consolidating products: alkoxysilane (ethyl silicate), a surfactant-templated novel sol–gel, Ca(OH)2, and SiO2 nanoparticles. These were subjected to marine aerosol accelerated aging cycles and studied by several non-destructive tests and techniques to assess the stability of the products. Results show that weathering caused by salt crystallization is not inhibited but it is slowed down due to the enhancement of superficial mechanical properties (surface cohesion and micro-hardness) achieved after one month of treatments application. A high or low relative humidity of the consolidation environment significantly affects the final mechanical and aesthetical physical properties and therefore conditions the durability of the treated substrates, even producing higher damage than observed in the blank specimens, depending on the product.  相似文献   

18.
The ability to correctly classify sentences that describe events is an important task for many natural language applications such as Question Answering (QA) and Text Summarisation. In this paper, we treat event detection as a sentence level text classification problem. Overall, we compare the performance of discriminative versus generative approaches to this task: namely, a Support Vector Machine (SVM) classifier versus a Language Modeling (LM) approach. We also investigate a rule-based method that uses handcrafted lists of ‘trigger’ terms derived from WordNet. Two datasets are used in our experiments to test each approach on six different event types, i.e., Die, Attack, Injure, Meet, Transport and Charge-Indict. Our experimental results show that the trained SVM classifier significantly outperforms the simple rule-based system and language modeling approach on both datasets: ACE (F1 66% vs. 45% and 38%, respectively) and IBC (F1 92% vs. 88% and 74%, respectively). A detailed error analysis framework for the task is also provided which separates errors into different types: semantic, inference, continuous and trigger-less.  相似文献   

19.
This study analyses the representation of immigrants in four Spanish national newspapers, El País, El Mundo, La Razón and ABC, between 1 June 2013 and 31 June 2014. Seven days per month were randomly selected, each corresponding to a different day of the week; 91 editions of each paper, 364 in total, were analysed. Of the 289 items relating to immigrants, 179 in which one or more photographs appeared in addition to text were chosen for analysis. Among the main results, two stand out: first, immigrants do not usually have an opportunity to communicate directly with readers and, secondly, the treatment of news items on immigration by the four Spanish newspapers is variable.  相似文献   

20.
While previous research has focused on the uses of a variety of online services—such as Web pages and, more recently, Twitter—by media organizations and their audiences, a rather limited amount of empirical inquiry has been directed towards the often more and broadly used Facebook platform. The current paper contributes to the research field by providing a longitudinal study of journalist and audience engagement on the Facebook pages of Sweden's four major newspapers—Aftonbladet, Dagens Nyheter, Expressen and Svenska Dagbladet. Employing state-of-the-art methods for data collection, the results indicate that while audiences appear to be increasing their engagement with news organizations on Facebook—albeit mostly through so-called “likes”—the media organizations themselves are decreasing their engagement with audiences.  相似文献   

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