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111.
THE POLYMERIZATION OF METHYL METHACRYLATE WITH A NEW TIN-BRIDGED YTTROCENE/Al(i-Bu)_3 总被引:1,自引:0,他引:1
INTRODUCTIONSincethepolymerizationofmethylmethacrylate(MMA)withrareearthcatalystswasrealizedforthefirsttimein1991,aseriesofnewrareearthcatalystsystemssuchasNd(P204)3/Al(iBu)3,Nd(P204)3/Al(iBu)3/CCl4,Nd(Oct)3/Al(iBu)3,Ln(acac)3/BuMgCl,Y(acac)3/Al(iBu)3/BuLi,Nd(naph)3/BuLi,andNd(O… 相似文献
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This paper presents data from Brazilian Patent Office (Instituto Nacional de Propriedade Industrial, INPI) and compares them with data from the United States Patent Office (USPTO). Developing countries have technological activities that are important locally but not significant at international level (imitation, local learning, adaptation of foreign innovations). These activities might be patentable only at national level. Therefore, the study of domestic patents of developing countries provides a broader picture than USPTO patents. This paper compares 8309 INPI patents with 475 USPTO patents (between 1980 and 1995). Domestic patent data show peculiarities in the Brazilian case, possibly shared with other countries in similar technological level: (a) high share of individual patents; (b) foreign-owned firms with important activities; (c) low firm involvement in R&D activities. Some characteristics are shared with developed countries: (a) domestic firms as the major patentees; (b) according to firm size, there is a U-shaped distribution of patents; (c) evidences of multi-technology large firms; (d) a relatively small share of firms have more than one patent in the whole period. The contrast between USPTO and national patenting statistics shows different rankings according to ownership structure, leading firms, industrial sectors, and international patent classification. These differences highlight sources of international competitiveness and point to weaknesses in Brazilian innovative activities. This paper concludes evaluating the contributions (and weaknesses) of this database for the evaluation of the Brazilian National System of Innovation. 相似文献
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Jaime A. Teixeira da Silva Judit Dobránszki Aceil Al-Khatib 《Publishing Research Quarterly》2016,32(4):313-318
In biology and medicine, a scientist’s legend is most commonly determined by their sphere of influence, either on surrounding peers, on clients in the case of medical practitioners, or on the wider scientific public in the case of research scientists. A scientific paper still constitutes the most effective portal through which ideas, knowledge and opinions can be shared among academics and scholars. Thus, legends in science are built upon a scientist’s published literature. Legend was always assumed to be safe in its final form, i.e., a published paper. Yet, a powerful movement of post-publication peer review has begun to identify that not all has been well with the vetting process that led to the publication of a tranche of the scientific literature, and that editorial oversight and weakness has prevailed in a number of cases, leading to retractions and a more critical re-assessment of the literature. One could say that the half-life of a scientific paper has only just begun once it is published. Within this context of science publishing that has given a sense of false security, legends may evolve from boom to bust within the space of weeks or even months. The legendary status of a scientist is therefore no longer safe if there are hidden or undiscovered errors, fraud or misconduct. 相似文献
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António Natal Campos Rebelo Pedro Silva Vincenzo Rago Daniel Barreira Peter Krustrup 《Journal of sports sciences》2016,34(24):2246-2254
ABSTRACTThe aims of this study were (i) to characterise the acceleration demands of two different formats of small-sided game (SSG), i.e., 4v4 + goalkeepers (4v4 + GK) and 8v8 + goalkeepers (8v8 + GK); (ii) to analyse the correlation between performance in power-based tests and acceleration-based physical loading during the two different SSG formats and (iii) to analyse the neuromuscular-induced fatigue. Eighteen adult male footballers participated in the study (20.7 ± 1.0 years, 178 ± 5 cm and 71.4 ± 2.1 kg). Baseline measurements were obtained from countermovement jumps, 15 s repeated jumps and 5 and 15 m sprints. A total of 36 min was analysed for each SSG (4v4 + GK: two sets of 3 × 6 min, and 8v8 + GK: 2 × 18 min). Heart rate, blood lactate, perceived exertion and movement pattern (GPS) were analysed. Distances covered by very-high-intensity activities and very-high-speed running were lower in 4v4 + GK than in 8v8 + GK (effect sizes (ES) = ?0.69 ± 0.67 and ?1.04 ± 0.67, respectively; very likely), while accelerations and decelerations were higher in 4v4 + GK than in 8v8 + GK (ES = 1.13–1.52; almost certainly). Blood lactate concentrations were higher (ES = 1.40 ± 0.58; almost certainly) and players perceived themselves to be more tired (ES = 0.80–2.31; almost certainly) after 4v4 + GK than after 8v8 + GK. Sprint ability in 5 and 15 m tests decreased (ES = 0.87 ± 0.58 and 0.89 ± 0.58, respectively; almost certainly) only after 4v4 + GK. This SSG format appeared more demanding in relation to repetitions and fatigue development of muscle power-based actions than 8v8 + GK. It may therefore be logical to use the former type of SSG to target development of power-related football actions. 相似文献
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This study aimed to evaluate body composition, sleep, precompetitive anxiety and dietary intake on the elite female gymnasts’ performance prior to an international competition. Sixty-seven rhythmic gymnasts of high performance level were evaluated in relation to sport and training practice, body composition, sleep duration, daytime sleepiness by the Epworth Sleepiness Scale (ESS), sleep quality by the Pittsburgh Sleep Quality Index (PSQI), precompetitive anxiety by the Sport Competition Anxiety Test form A (SCAT-A) and detailed dietary intake just before an international competition. Most gymnasts (67.2%) suffered from mild daytime sleepiness, 77.6% presented poor sleep quality and 19.4% presented high levels of precompetitive anxiety. The majority of gymnasts reported low energy availability (EA) and low intakes of important vitamins including folate, vitamins D, E and K; and minerals, including calcium, iron, boron and magnesium (p?.05). Gymnasts’ performance was positively correlated with age (p?=?.001), sport practice (p?=?.024), number of daily training hours (p?=?.000), number of hours of training/week (p?=?.000), waist circumference (WC) (p?=?.008) and sleep duration (p?=?.005). However, it was negatively correlated with WC/hip circumference (p?=?.000), ESS (p?=?.000), PSQI (p?=?.042), SCAT-A (p?=?.002), protein g/kg (p?=?.028), EA (p?=?.002) and exercise energy expenditure (p?=?.000). High performance gymnasts presented poor sleep habits with consequences upon daytime sleepiness, sleep quality and low energy availability. 相似文献
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In three experiments, we examined humans’ folk physics (i.e., a naturally occurring and spontaneous understanding of the physical
world), using variations of problems used to study chimpanzees’ folk physics. Presented with trap-tube problems in two experiments,
adult humans showed an unnecessary bias to insert a stick into the end of the tube farthest from the reward to push it out
the other end. When presented with trap-table problems with ineffective trapping holes, people unnecessarily avoided the side
with the hole. The similarity of humans’ and chimpanzees’ behavior on these tasks highlights methodological and conceptual
problems in studies of chimpanzees’ folk physics and suggests alternative explanations for their behavior. 相似文献