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Azo dyes discharged in the environment are persistent organic pollutants (POPs), which are very difficult to remove. We developed a microwave-assisted Fenton-like process to degrade methyl orange (MO), an azo dye, with hydrogen peroxide (H2O2) catalyzed by chromium compounds coexisting with MO in the solution. Comparison between the Cr(Ⅲ)-H2O2 and Cr(Ⅵ)-H2O2 systems shows" that Cr(Ⅵ) has a stronger and more stable catalytical activity than Cr(Ⅲ), and Cr(Ⅲ) is more susceptible to a change in the acidity or alkalinity of the reaction system. With a Cr(Ⅵ) concentration of 10 mmol L^-1 or a Cr(Ⅲ) concentration of 12 mmol L^-1 in the solution under the microwave irradiation of a power larger than 300 W for 3 min, 10 mmol L^-1 H2O2 can degrade more than 95% of 1 000 mg L^-1 methyl orange; when the microwave power is increased to 700 W, the same amount of H2O2 can degrade all methyl orange in the solution with the same amount of Cr(Ⅵ ) catalyst. Ultraviolet-visible spectrography indicates the cleavage of the azo bond in methyl orange after treatment, suggesting the potential o of this Fenton-like process to degrade azo dye POPs. Reusing waste chromium compounds coexisting with dyestuff in wastewater to catalyze the degradation of azo dyes could be a cost-effective technique for azo dyes and chromate manufacturers and/or users to treat their wastewater and prevent POPs from endangering the environment. This is of particula importance to controlling the water quality of the Three Gorges Reservoir. 相似文献
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合金钢中铬钒快速、连续测定 总被引:1,自引:0,他引:1
黄海燕 《邵阳学院学报(社会科学版)》1999,(5)
:根据铬、钒在钢中存在状态快速溶样 ,详述了分析方法操作过程及所需试剂的配制 ,利用滴定方法连续测定合金钢中铬、钒 相似文献