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In order to compare two kinds of blue electroluminescent materials,we have investigated two kinds of blue OLEDs with the similar structure ITO/CuPc/NPB/JBEM:perylene/Alq/Mg:Ag[device(J)] and ITO/CuPc/NPB/DPVBi:perylene/Alq/Mg:Ag[device(D)].The difference of luminance and efficiency was not obvious for the two devices,However,there was remarkable difference for their lifetime.The device(J) achieved longer half lifetime of 1035h at initial luminance of 100 cd/m^2,and that of device(D) was only255h,According to their energy level diagrams,the differentce of their stability may originate from different host materials in the two devices.It may be attributed to the better thermal stability of JBEM molecues than that of DPVBi.It is shown that JBEM may be a promising blue organic electroluminescent material with great stability. 相似文献
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Three types of blue-violet light-emitting devices based on an exciton-confined structure have been prepared, in which different materials were used as emitting layers and hole-transporting layers. They had structures of ITO/CuPc/NPB/CPB/TPBi/Alq3/LiF/Al(DNC), ITO/CuPc/JO3/CBP/TPBi/Alq3/LiF/Al(DJC ) and ITO/CuPc/JO3/FNPD/TPBi/Alq3/LiF/Al(DJF). Here copper phthalocyanine (CuPc) acted as hole-injecting layer( HIL), N, N-bis-(1-naphthyl)-N, N-diphenyl-1. lbiphenyl-4-4-diamine(NPB) and J03 bole-transporting layers ( HTLs), 4,4‘-dicarbazolyl-1,1‘ -biphenyl (CBP) and FNPD as emitting layers( EMLs), N, arylbenzimidazoles (TPBi) as holeblocking layer ( HBL ), and tris(8-quinolinolato ) aluminium complex ( Alq3 ) as electron- transporting layer ( ETL). TPBi applied here is a good confinement to both charges and excitons, which make the devices emit blue-violet light originating from the emitter, CBP and FNPD. Their characteristics have also been investigated. The result shows that the device DNC based on NPB/CBP has the best performance among the three devices. The excellence of DNC is attributed to the better hole-transporting ability of NPB as compared with J03, and the better emitting ability of CBP as compared with FNPD, although the best matching of energy levels is found in the hole-transporting layer and emitting layer of the device DJP. 相似文献
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A new blue electroluminescent material,distyrylarylene(DSA)derivative,4,4‘-bis[2,2-(1-naphthyl,phenyl)vinyl]-1,1-biphenyl(NPVBi)is designed and synthesized.The DSA derivative shows better thermal stability because of its high glass transition temperature.A blue organic light emitting diode(OLED0with the structure ITO/TPD/NPVBi/Alq/LiF/Al is studied.The electroluminescent(EL0spectrum of the OLED exhibits that light emission originates from NPVBi with a peak at 460nm,its Commission Internationale de l‘Eclairage(CIE)color coordinates are x=0.16,y=0.15,and showing independence of CIE color coordinates on current density.The new DSA derivative is expectable as a new candidate for blue light emitter in OLEDs. 相似文献
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