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排序方式: 共有29条查询结果,搜索用时 15 毫秒
1.
Chemical methods to determine the conformations and absolute configurations of menthol, a cyclohexane derivative with 3 chiral centres, are described.  相似文献   
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Some interesting examples of the linkage between the structure and biological function of secondary metabolites in plants and animals are described.  相似文献   
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Droplet-based microfluidics has gained extensive research interest as it overcomes several challenges confronted by conventional single-phase microfluidics. The mixing performance inside droplets/slugs is critical in many applications such as advanced material syntheses and in situ kinetic measurements. In order to understand the effects of operating conditions on the mixing performance inside liquid slugs generated by a microfluidic T-junction, we have adopted the volume of fluid method coupled with the species transport model to study and quantify the mixing efficiencies inside slugs. Our simulation results demonstrate that an efficient mixing process is achieved by the intimate collaboration of the twirling effect and the recirculating flow. Only if the reagents are distributed transversely by the twirling effect, the recirculating flow can bring in convection mechanism thus facilitating mixing. By comparing the mixing performance inside slugs at various operating conditions, we find that slug size plays the key role in influencing the mixing performance as it determines the amount of fluid to be distributed by the twirling effect. For the cases where short slugs are generated, the mixing process is governed by the fast convection mechanism because the twirling effect can distribute the fluid to the flow path of the recirculating flow effectively. For cases with long slugs, the mixing process is dominated by the slow diffusion mechanism since the twirling effect is insufficient to distribute the large amount of fluid. In addition, our results show that increasing the operating velocity has limited effects on improving the mixing performance. This study provides the insight of the mixing process and may benefit the design and operations of droplet-based microfluidics.  相似文献   
4.
We report a case of a diabetic, heterozygote with near normal hematology, marginally low level of hemoglobin A2(HbA2) having an increased level of hemoglobin F(HbF) that was pancellularly distributed among the red cells. BioRad DiaSTAT measurements gave a high glycated hemoglobin A1c(HbA1c) of 31.5% and the BioRad Variant analyzer recorded an HbA1c value which was very low, in discordance with the detected blood glucose levels. Flow cytometry and polymerization chain reaction (PCR) based studies were carried out which revealed the case to be that of the common hereditary persistence of fetal hemoglobin (HPFH)-3, an Asian Indian mutation. Fructosamine estimation and HbA1c by Boronate affinity chromatography were able to resolve the discordant value detected and was able to confirm the diabetes status. The case would have been a diagnostic dilemma, if reported without correlation.  相似文献   
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Among the traditional five sensory perceptions, colour and smell often go hand in hand, along with taste. Among the objects used for worshipping God, for instance, flowers and incenses occupy prime places. The subject matter of this article is the chemistry of musk and related perfumes derived from natural sources.  相似文献   
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A naturally occurring organic compound has been chosen to illustrate (a) structure determination by chemical and spectroscopic methods, and (b) synthesis and chemical transformations.  相似文献   
9.
Research progress of transparent conducting ZnO:Al(ZAO)films   总被引:1,自引:0,他引:1  
Owing to both of its high carrier concentration and large band gap,ZnO:Al(ZAO)films which is an n-type degenerate semiconductor,exhibits low resistance and high transmittance in the visible range.This work studies the crystal structure,optical and electrical properties and preparation methods of ZAO films,and discusses the existing problems and application prospective of ZAO films.  相似文献   
10.
The aim of this study was to develop an exercise protocol to simulate tennis matchplay on a 'category 2' surface. Match analyses were used to form the basis for the design of the protocol. The protocol involved playing against a tennis ball serving machine. Part A of the protocol comprised 92 min 46 s of simulated tennis matchplay; Part B consisted of continuous hitting to the point of 'volitional fatigue' or when the required hitting frequency for two consecutive ball feeds could no longer be maintained. Ten elite tennis players (5 males, 5 females) volunteered to participate in the study, which was performed on an indoor tennis court (Matchplay?, En-Tout-Cas)?. Their age, body mass and estimated maximal oxygen uptake were as follows: males, 21.7±1.0 years, 73.6±2.6 kg and 58.0±1.7 ml?·?kg?1?·?min?1, respectively; females, 21.9±1.3 years, 62.3±2.0 kg and 42.2±0.7 ml?·?kg?·?min?1, respectively (mean±). Heart rate, change in body mass and time to volitional fatigue were monitored. The heart rate responses of the participants to the simulated matchplay (range: 140-157 beats?·?min?1, 73-81% peak heart rate) were consistent with the results of previous studies, for 'actual' matchplay. This protocol was successful in simulating similar physiological responses in Part A to 'actual' matchplay on a 'category 2' surface, in a controlled environment; it was also a sensitive evaluation tool of skilled performance in Part B. The current protocol may be used as a baseline protocol for studying the influence of, for example, training and dietary intervention on performance.  相似文献   
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