Cr(VI) and phenol are toxic contaminants that need to be treated, and different methods have been researched to simultaneously remove these two contaminants from industrial wastewater. In this study, Cr(VI) was used as a novel Fenton-like catalyst in phenol degradation by H2O2. In the pH range of 3.0‒11.0, the degradation efficiency of phenol decreased with elevated pH. At pH = 3.0, 100 mg/L phenol was effectively degraded by 2 mmol/L Cr(VI) and 20 mmol/L H2O2. At pH = 7.0 and the same conditions as those of pH = 3.0, 79% of 100 mg/L phenol was removed within 6 h, which was an improvement in pH limitation compared with the Fe(II)-mediated Fenton reaction. Quenching experiments indicated that ·OH generated from the catalysis of H2O2 by Cr(V) instead of Cr(VI) was the primary oxidant that degraded phenol. When pyrophosphate was added in the Cr(VI)/H2O2 system, complexes with the Cr(V) intermediate rapidly formed and inhibited H2O2 decomposition, implying that the decomposition of H2O2 to ·OH was catalyzed by Cr(V) instead of Cr(VI). The presence of anions such as chloride and sulfate had insignificant effect on the degradation of phenol. TOC and UV analyses suggest that phenol could not be completely oxidized to CO2 and H2O, and the intermediates identified by high performance liquid chromatography further indicates that maleic acid and benzoquinone were intermediates which may be further degraded into short chain acids, primarily maleic, formic, acetic, and oxalic acids, and eventually into CO2 and H2O. Considering that more than 50% Cr(VI) can also be removed during this process, the Cr(VI)/H2O2 system is more appropriate for the simultaneous removal of Cr(VI) and phenol contaminants from industrial wastewater.
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Peanut-like hematite has been prepared by a new facile hydrothermal method and applied in the adsorption removal of As(V). The structural features of the as-prepared hematite were characterized systematically by X-ray diffraction, X-ray photoelectron spectroscopy, Brunauer–Emmett–Teller, scanning electron microscopy, energy-dispersive X-ray spectroscopy mapping, Fourier transform infrared spectroscopy, and transmission electron microscopy. Results showed that the morphologies of hematite could be tuned to spindle-like, oval-like, and cantaloupe-like shapes by adjusting the hydrothermal conditions. The peanut-like hematite formation followed a five-step route. At pH = 3, the adsorption amount of As(V) over peanut-like hematite reached 13.84 mg/g, and the adsorption kinetic process corresponded to the pseudo-second-order kinetic model. The peanut-like hematite also showed partial selectivity over As(V) in the hydrosphere. This method can be a reference for the preparation of other architectural metal oxide materials. 相似文献
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To improve separate effect of binary heterogeneous azeotrope in the magnetic field with different magnetic induction intensity, the influence of magnetic field on the rectification process of binary heterogeneous azeotrope was investigated with l-butanol-water system. The results show that the composition of liquid-liquid phase equilibrium of l-butanol-water system has definitely changed, the composition of l-butanol in light phase （l-butanol layer） increases by 1. 17%-1.63% and the composition of water in heavy phase （water layer） increases by 1.21%-1.58% under the influence of magnetic field. By separation of magnetization, the composition of l-butanol increases by 0.8%-1.2% and the recovery ratio of 1 -butanol increases by 1.6%-2.5%. Magnetic field has positive effect, however, the magnetized effect is not in proportion to magnetic induction intensity and has an optimum condition, in the range of 0.25 T-0. 3 T. 相似文献
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Schwertmannite(Sh), a poorly crystalline iron(hydr)oxide that usually appears in acid mine drainage, plays a significant role in the immobilization of As(V). In this study, the effects of UV irradiation and oxalate on the dissolution of Sh with structurally incorporated As(V) [Sh-As(V)] and the subsequent mobilization of As(V) were investigated at pH 3.0. In the dark, more total dissolved Fe was produced(the maximum value was 33.2 mg/L) in the suspensions of Sh-As(V) with oxalate than in those without oxalate. UV irradiation slightly enhanced the mobilization of As(V) for the system of Sh-As(V)-1 and Sh-As(V)-2 in the absence of oxalate compared with that in the dark. However, in the presence of oxalate, UV irradiation caused the concentration of mobilized As(V) to decline by 630-875% compared with that in the dark. This study enhanced our understanding of the mobilization of As(V) and demonstrated that UV irradiation could contribute to the immobilization of As(V) on Sh in aqueous environments containing oxalate. 相似文献
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The effect of magnetic field on α-amylase was studied. Under the experimental conditions, α-amylase solution was treated by 0.15 T, 0.30 T and 0.45 T static magnetic fields for a known period of time, then the activ-ity, kinetic parameters, and the secondary conformation were investigated. The results showed that there was a con-siderable effect of the magnetic exposure on the α-amylase. The activity was increased by 27%, 34.1%, 37.8% compared with the control. It was also found that both kinetic parameters Km and Vm could be decreased due to the increasing magnetic field, Km decreased from 2.20×102 to 0.87×102, whereas Vm decreased from 2.0×103 g/min to 1.1×103g/min. At the same time, there were some irregular changes in α-amylase secondary conformation. 相似文献
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Transactions of Tianjin University - Schwertmannite (Sh), a poorly crystalline iron (hydr)oxide that usually appears in acid mine drainage, plays a significant role in the immobilization of As(V).... 相似文献
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Natural pyrites contain high levels of adsorbed and structurally incorporated arsenic(As),which may simultaneously result in the release of As and affect the oxidation process of pyrite.However,the oxidation and electrochemical behaviors of As on the oxidation reactivity of pyrites are still not clear.In this study,pyrite was prepared by a hydrothermal method and applied to study the oxidation mechanism between pyrite and aqueous arsenate.Analyses of X-ray diffraction,X-ray photoelectron spectroscopy,and scanning electron microscopy demonstrate that the as-prepared sample is an octahedron-like pyrite with high purity and crystallinity.The interaction between As(V)and pyrite as well as the electrochemical behaviors of pyrite oxidation in the presence of aqueous arsenate were investigated under acidic conditions by an ion analysis method,cyclic voltammetry(CV),Tafel,and electrochemical impedance spectroscopy(EIS).The results of the chemical reaction indicate that electrons are transferred from S _2~(2-)to dissolved oxygen with the formation of SO _4~(2-)in the initial As(V)concentration range of 0–0.3 mmol/L.In the initial As(V)concentration range of 0.4–1.2 mmol/L,electrons are transferred from S _2~(2-)to As(V)with the formation of elemental S ~(0 )and As(III).The CV,the Tafel plot and EIS analyses indicate that aqueous arsenate in an electrolyte promotes oxidation reactivity and passivation of the pyrite electrode.Moreover,the electron transfer rate increases with increasing aqueous arsenate concentration in the electrolyte. 相似文献
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The effect of magnetic field on α-amylase was studied. Under the experimental conditions, α-amylase solution was treated by 0.15 T, 0.30 T and 0.45 T static magnetic fields for a known period of time, then the activity, kinetic parameters, and the secondary conformation were investigated. The results showed that there was a considerable effect of the magnetic exposure on the α-amylase. The activity was increased by 27%, 34.1%, 37.8% compared with the control. It was also found that both kinetic parameters K m and V m could be decreased due to the increasing magnetic field, K m decreased from 2.20×10?2 to 0.87×10?2, whereas V m decreased from 2.0×10?3 g/min to 1.1×10?3 g/min. At the same time, there were some irregular changes in α-amylase secondary conformation. 相似文献
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