生命活性分子与金属离子配合行为的极谱研究——Cu(II)二元配合物(I)     

刘新文 《天水师范学院学报》2006,(5)

通过脉冲极谱法研究了以生命活性分子(Serine,Cysteine,Salicylic acid等)作为配体与Cu(II)形成多元配合物的极谱行为。在模拟生理条件μ=0.1(NaNO3)、T=310±0.2K下,发现电极过程为准可逆;通过对二元配合物稳定常数的测定表明,不同配体与金属离子配合的能力显著不同,配合物稳定性差异较大;同时还研究了各配合物的形态分布、引起稳定性差异的原因及影响因素。  相似文献   

农远工程中信息化教学的“公开课情结”分析及对策研究   总被引：1，自引：0，他引：1  

张文兰  史婷 《现代教育技术》2008,18(8):78-81

"公开课情结"是农远工程中信息化教学挥之不去的一种普遍现象,即信息技术与课程整合仅仅停留在公开课层面,难以持续、深入到常态课中。该文就这一现象进行了剖析,并提出了理性应用合适技术,应用发展性评价,基于校本资源建设以及多因素协同构建良好支持环境的解决对策。  相似文献   

Chelators effect on soil Cu extractability and uptake byElsholtzia splendens     

Jiang  Li-ying  Yang  Xiao-e 《浙江大学学报(A卷英文版)》2004,5(4):450-456

Phytoremediation is emerging as a potential cost-effective solution for remediation of contaminated soils, and bioavailability of metal in the soil for plant uptake is an important factor for successful phytoremediation. This study aimed at investigating the ability of EDTA and citric acid for enhancing soil bioavailability of Cu and phytoremediation by Elsholtzia splendens in two types of soils contaminated with heavy metals [i.e. mined soil from copper mining area (MS), and paddy soil (PS) polluted by copper refining]. The results showed that addition of 2.5 mmol/kg EDTA significantly increased the H₂O extractable Cu concentration from 1.20 to 15.78 mg/kg in MS and from 0.26 to 15.72 mg/kg in PS, and that shoot Cu concentration increased 4-fold and 8-fold as compared to the control. There was no significant difference between the treatment with 5.0 mmol/kg EDTA and that with 2.5 mmol/kg EDTA, probably because that 2.5 mmol/kg EDTA was enough for elevating Cu bioavailability to the maximum level. As compared with the control, citric acid had no marked effect on both soil extractable Cu and shoot Cu concentration or accumulation. The results indicated that EDTA addition can increase the potential and efficiency of Cu phytoextraction byE. splendens in polluted soils. Project supported by the National Natural Science Foundation of China (No. 29977017) and the Science and Technology Ministry of China (No. 2002CB410804)  相似文献   

CuO气敏元件的制备及气敏性能研究     

侯振雨  谷永庆  张玉泉  王建新 《河南科技学院学报》2006,34(1):69-71

用Cu2O制备CuO气敏元件，对乙醇、汽油、丁烷和氢气等气氛进行气敏试验，并进行机理分析，结果表明，由Cu2O制备的CuO气敏元件，对所测气体的灵敏度优于由CuO制备的气敏元件。  相似文献   

火焰原子吸收光谱法测定杞菊地黄丸中的铜     

刘月成  王尚芝  孟双明  郭永  吴月芳 《雁北师范学院学报》2006,22(5):43-45

研究了火焰原子吸收光谱法测定杞菊地黄丸中铜含量的方法,样品采用HNO3:HClO4(4:1)消化体系,方法简便、快速、省时.具有良好的精密度和准确度.精密度为7.45%,检出限为0.0059μg/ml,回收率达到92.3~110%.  相似文献   

Experiments on Cu-isotope fractionation between chlorine-bearing fluid and silicate magma: implications for fluid exsolution and porphyry Cu deposits     

Haihao Guo  Ying Xia  Ruixia Bai  Xingchao Zhang  Fang Huang 《国家科学评论(英文版)》2020,7(8):1319

Hydrothermal fluid is essential for transporting metals in the crust and mantle. To explore the potential of Cu isotopes as a tracer of hydrothermal-fluid activity, Cu-isotope fractionation factors between Cl-bearing aqueous fluids and silicate magmas (andesite, dacite, rhyolite dacite, rhyolite and haplogranite) were experimentally calibrated. Fluids containing 1.75–14 wt.% Cl were mixed together with rock powders in Au₉₅Cu₅ alloy capsules, which were equilibrated in cold-seal pressure vessels for 5–13 days at 800–850°C and 2 kbar. The elemental and Cu-isotopic compositions of the recovered aqueous fluid and solid phases were analyzed by (LA-) ICP–MS and multi-collector inductively coupled plasma mass spectrometry, respectively. Our experimental results show that the fluid phases are consistently enriched in heavy Cu isotope (⁶⁵Cu) relative to the coexisting silicates. The Cu-isotope fractionation factor (Δ⁶⁵Cu_FLUID-MELT) ranges from 0.08 ± 0.01‰ to 0.69 ± 0.02‰. The experimental results show that the Cu-isotopic fractionation factors between aqueous fluids and silicates strongly depend on the Cu speciation in the fluids (e.g. CuCl(H₂O), CuCl₂^– and CuCl₃²⁻) and silicate melts (CuO_1/2), suggesting that the exsolved fluids may have higher δ⁶⁵Cu than the residual magmas. Our results suggest the elevated δ⁶⁵Cu values in Cu-enriched rocks could be produced by addition of aqueous fluids exsolved from magmas. Together with previous studies on Cu isotopes in the brine and vapor phases of porphyry deposits, our results are helpful for better understanding Cu-mineralization processes.  相似文献   

长期训练大鼠血清Fe、Zn、Cu 、Mg动态变化的研究     

王豫 《北京体育大学学报》2007,30(4):504-506

为了揭示长期运动训练对大鼠血清微量元素代谢的影响,通过动物实验法,观察大鼠血清Fe、Zn、Cu、Mg的动态变化.方法:对Wistar大鼠采用递增负荷训练五周,分别于实验开始、第一周、第二周、第四周以及实验结束第五周取血测定大鼠血清Fe、Zn、Cu、Mg含量.结果:长期递增负荷训练大鼠血清Fe、Zn、Cu 、Mg变化趋势各具特点;在结束后大鼠血清Fe、Zn、Cu、Mg总体趋势是呈现下降,与实验前相比血清Fe、Zn、Mg明显减少(P＜0.05). 建议长期运动训练期间机体应及时补充Fe、Zn、Mg,尤其在递增负荷训练后两周后就应该加强Mg元素的补充.  相似文献   

智利玛丽娜铜矿床的地质特征及找矿标志     

高海欧  奚小双  杨兵  李建旭  张积斌 《黑龙江科技信息》2015,(15)

玛丽娜铜矿区位于智利中生代陆相-湖泊相拉伸拗陷带,形成于中酸性火山岩中,多条平行或网脉状矿体赋存在下白垩统拉斯契加斯(Las Chilcas)组岩层,受断裂控制,矿体切穿多种赋矿围岩,矿石矿物呈细粒浸染状和脉状,矿种以铜为主,伴生银。矿物分带从浅到深呈现出辉铜矿-斑铜矿-黄铁矿的分带特征。近矿围岩蚀变以泥化-青磐岩化-绢云母化为主,深部见钾长石化蚀变。通过对成矿地质条件和矿化特征研究认为玛丽娜铜矿床上部为曼陀型矿床,深部为斑岩型铜矿床。本文在总结项目组勘查和综合研究的基础上,对矿区火山岩的地球物理特征进行研究,探讨其地质意义。  相似文献   

用于吸附Cu(Ⅱ)材料的研究进展     

陈研研 《毕节学院学报》2011,29(4):95-99

二价铜离子作为水体中的主要污染物之一,一直是人们研究的焦点。通过对近几年来用于吸附二价铜离子的材料研究,并对影响其吸附的主要因素进行了阐述。结果表明,天然材料(如香蕉皮、谷壳等)在此领域具有价格低廉、操作简单的优势,极具开发前景。  相似文献   

双波长双指示剂催化光度法同时测定锰和铜     

余骏 《安徽教育学院学报》2011,(6):67-69

研究了在pH4．5的HAc-NaAc缓冲溶液介质中,利用痕量铜和锰同时催化高碘酸钾氧化亚甲基蓝和罗丹明B的褪色的指示反应,分别在660nrn和540nm波长下测量催化体系和非催化体系的吸光度,建立了双指示剂、双波长催化动力学光度法下测定痕量铜和锰的新方法。在最佳实验条件下,用固定时间法,测得的铜和锰线性范围分别为：0．0050～0．025μg／mL,0．0010~0．020μg／mL;检出限分别为：3．3×10^-10g／mL,7．6×10^-11g／mL。该法操作简单,灵敏度高,选择性好,可用于实际样品头发和大米中痕量铜和锰的测定,结果令人满意。  相似文献