Study of the stability of a series of synthetic colorants applied with styrene-acrylic copolymer, widely used in contemporary paintings, concerning the effects of accelerated ageing     

Zoe Eirini Papliaka  Konstantinos S. Andrikopoulos  Evangelia A. Varella 《Journal of Cultural Heritage》2010,11(4):381-391

This study examines the materials of a contemporary pictorial artwork, belonging to the Macedonian Museum of Contemporary Art in Thessaloniki (Greece), and needing conservation. The combined use of micro-FTIR and micro-Raman spectroscopy allowed the identification of almost all painting materials. Moreover, the stability of a series of synthetic pigments towards accelerated ageing is investigated in applications using the contemporary binding medium styrene-acrylic copolymer. The pigments in question are: Hansa yellow PY3 and PY74, quinacridone PV19 and PR122, naphthol AS PR112, phthalocyanine green PG7 and blue PB15, dioxazine PV37, van Dyck brown PBk11, ivory black PBk9, and titanium dioxide PW6. The organic pigments were applied alone or mixed with titanium dioxide, in rutile form or as a mixture of rutile/anatase. The experimental swatches were subjected to ageing tests, and subsequently studied as to colour changes by means of colorimetric measurements, and as to the molecular structure differentiations by infrared spectroscopy in reflectance mode. The ageing tests included exposure to high temperature and humidity (90 °C, 60% RH) and to ultraviolet radiation (350 nm, 30 °C and 50% RH, with a substantial temperature increase at 90 °C for 3 days). The greater colour difference is caused by high temperature and humidity, whereas paint layers containing TiO₂, and especially the mixture of the forms rutile/anatase, prove very susceptible to ultraviolet radiation, demonstrating a significant colour difference and extended molecular changes.  相似文献   

New insights into brazilwood lake pigments manufacture through the use of historically accurate reconstructions     

Tatiana Vitorino  Leslie Carlyle  Vanessa Otero 《文物保护研究》2016,61(5):255-273

A multi-analytical approach for the study of brazilwood and its lake pigments was carried out based on historically accurate reconstructions. Recipes for brazilwood lakes from the fifteenth century technical text Livro de como se fazem as cores and the Winsor & Newton nineteenth century colourman's archive were reproduced and compared. Both primary sources allowed for the successful preparation of brazilwood lake pigments with colours that vary from light pink to dark red. The main steps and ingredients for the manufacture of these pigments were common in both sources, particularly the addition of Al³⁺ in the form of alum, and calcium carbonate (chalk). Reconstructions revealed that the latter acts as a pH buffer and filler, controlling the pH at which the lake pigment precipitates. The main difference between the two sources is that the nineteenth century recipes give the quantities for all ingredients, the precise temperatures and time, and achieved higher relative pigment yields (75% versus 45%). Full chemical characterisation of the reconstructions provided detailed information on the individual steps in the pigment manufacture and revealed that the presence of calcium sulphate dihydrate (gypsum) in the final pigment was a result of its formation in situ. Infrared, reflectance, and fluorescence spectroscopy proved to be essential and complementary techniques: while infrared was used to characterise additives and binders, reflectance and fluorescence data were fundamental for identifying the chromophore. The pigments and paints produced can now be used as standards for the identification and investigation of brazilwood lake pigments found in artworks.  相似文献   

Technical analysis of a Central Asian wall painting detached from a Buddhist cave temple on the northern Silk Road     

Birgit Angelika Schmidt  Martin Andreas Ziemann  Simone Pentzien  Toralf Gabsch  Werner Koch  Jörg Krüger 《文物保护研究》2016,61(2):113-122

A great number of Central Asian wall paintings, archeological materials, architectural fragments, and textiles, as well as painting fragments on silk and paper, make up the so called Turfan Collection at the Asian Art Museum in Berlin. The largest part of the collection comes from the Kucha region, a very important cultural center in the third to ninth centuries. Between 1902 and 1914, four German expeditions traveled along the northern Silk Road. During these expeditions, wall paintings were detached from their original settings in Buddhist cave complexes. This paper reports a technical study of a wall painting, existing in eight fragments, from the Buddhist cave no. 40 (Ritterhöhle). Its original painted surface is soot blackened and largely illegible. Grünwedel, leader of the first and third expeditions, described the almost complete destruction of the rediscovered temple complex and evidence of fire damage. The aim of this case study is to identify the materials used for the wall paintings. Furthermore, soot deposits as well as materials from conservation interventions were of interest. Non-invasive analyses were preferred but a limited number of samples were taken to provide more precise information on the painting technique. By employing optical and scanning electron microscopy, energy dispersive X-ray spectroscopy, micro X-ray fluorescence spectroscopy, X-ray diffraction analysis, and Raman spectroscopy, a layer sequence of earthen render, a ground layer made of gypsum, and a paint layer containing a variety of inorganic pigments were identified.  相似文献   

Active recovery of the finger flexors enhances intermittent handgrip performance in rock climbers     

Jiří Baláš  David Giles  Jan Kodejška  Michaela Panáčková  Simon Fryer 《European Journal of Sport Science》2016,16(7):764-772

This study aimed to (1) evaluate the effect of hand shaking during recovery phases of intermittent testing on the time–force characteristics of performance and muscle oxygenation, and (2) assess inter-individual variability in the time to achieve the target force during intermittent testing in rock climbers. Twenty-two participants undertook three finger flexor endurance tests at 60% of their maximal voluntary contraction until failure. Performances of a sustained contraction and two intermittent contractions, each with different recovery strategies, were analysed by time–force parameters and near-infrared spectroscopy. Recovery with shaking of the forearm beside the body led to a significantly greater intermittent test time (↑ 22%, P?P?P?相似文献   

太赫兹时域光谱技术   总被引：1，自引：0，他引：1  

孟田华  赵国忠 《雁北师范学院学报》2007,23(3):14-17

介绍了太赫兹时域光谱技术的优势,太赫兹时域光谱系统及太赫兹时域光谱技术的原理和应用.  相似文献   

溴化（E）-1,1′-（六烷-1,6-二甲氨基）二（4-（E）-2-（噻吩基）乙烯基吡啶的合成、表征及光电性质的研究     

王志平  曹宝亮 《集宁师专学报》2011,33(4):18-21

合成和表征了一个新的吡啶衍生物溴化（E）-1,1′-（六烷-1,6-二甲氨基）二（4-（E）-2-（噻吩基）乙烯基吡啶,这是一种自组装膜合成的中间配体,具有特殊的结构特征和氧化还原性,以其为配体继续合成自组装膜材料,在共价和静电自组装膜研究的领域有很高的研究价值,本文对它的合成、表征及其紫外可见光谱和荧光光谱等的性质作一研究。  相似文献   

Case Report:Lance-Adams syndrome:a report of two cases     

ZHANG Yan-xing    LIU Jian-ren  JIANG biao  LIU Hui-qin  DING Mei-ping  SONG Shui-jiang  ZHANG Bao-rong  ZHANG Hong  XU Bin  CHEN Huai-hong  WANG Zhong-jin  HUANG Jian-zheng 《Journal of Zhejiang University. Science. B》2007,(10)

Chronic post-hypoxic myoclonus, also known as Lance-Adams syndrome (LAS), is a rare complication of successful cardiopulmanry resuscitation often accompanied by action myoclonus and cerebellar ataxia. It is seen in patients who have un-dergone a cardiorespiratory arrest, regained consciousness afterwards, and then developed myoclonus days or weeks after the event. Worldwide, 122 cases have been reported in the literature so far, including 1 case of Chinese. Here we report 2 Chinese LAS patients with detailed neuroimagings. Cranial single photon emission computed tomography (SPECT) of patient 1, a 52-year-old woman, showed a mild hypoperfusion in her left temporal lobe, whereas patient 2, a 54-year-old woman, manifested a mild bilateral decrease of glucose metabolism in the frontal lobes and a mild to moderate decrease of the N-acetyl aspartate (NAA) peak in the bilateral hippocampi by cranial [18F]-fluorodeoxyglucose positron emission tomographic (PET) scan and cranial magnetic resonance spectroscopy (MRS), respectively. We also review the literature on the neuroimaging, pathogenesis, and treatment of LAS.  相似文献   

不同品种黄瓜幼苗光合机构对盐胁迫的响应   总被引：26，自引：0，他引：26  

钱琼秋  魏国强  朱祝军  李娟 《科技通报》2004,20(5):459-463

研究了盐胁迫(0、25、50mmol／L)对不同品种黄瓜幼苗生长、光合作用和叶绿素荧光的影响．结果表明，盐胁迫，尤其是高浓度NaCl(50mmol／L)的胁迫，显著降低黄瓜幼苗生长量、叶绿素含量、光系统Ⅱ光合电子传递量子效率(φPSⅡ)、净光合速率(Pn)、气孔导度(Gs)以及气孔限制值(Ls)，同时显著提高叶片相对电导率、丙二醛、脯氨酸含量和细胞间CO2浓度(Ci)，光系统Ⅱ的光化学效率(Fv／Fm)变化不大．盐胁迫对耐盐黄瓜‘津研4号’幼苗生长的影响小于盐敏感黄瓜‘津绿4号’，这可能与耐盐黄瓜在盐胁迫下较高的净光合速率、光系统Ⅱ光合电子传递量子效率和较低的丙二醛(MDA)含量、相对电导率有关。  相似文献   

实验教材中“荧光光谱法测定水杨酸”的讨论     

徐彦芹  曹渊  张光辉  陈昌国  鲜晓红 《实验室研究与探索》2011,(7):340-341

为改进教材《荧光光谱法测定水杨酸》,寻找实验所需溶剂CHCl3的替代药品。通过实验,采用1%HAc-CHCl3、1%HAc-C2H5OH、1%HAc-H2O对荧光光谱法测定水杨酸的影响进行比较,并确定1%HAc-C2H5OH为其中最佳溶剂。  相似文献   

氢原子光谱同位素谱线位移实验的参数优化     

张萍  袁学德  刘力军  曲艳玲 《实验室研究与探索》2011,30(10)

讨论了氢原子光谱实验中狭缝宽度、采集次数和负高压对氢原子光谱同位素位移谱线的影响,优化了氢原子光谱同位素位移实验的工作参数,获得了清晰的氢原子同位素位移光谱。通过该实验让学生掌握实验中多参数优化的方法,有利于加深学生对光谱理论的理解,有利于提高学生分析问题解决问题的能力。  相似文献