| 1-甲基-1-苯乙基过氧化氢衍生物的合成 |
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| 引用本文： | 吴强,覃雯,覃慈.1-甲基-1-苯乙基过氧化氢衍生物的合成[J].桂林师范高等专科学校学报,2011,25(2):141-143. |
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| 作者姓名： | 吴强 覃雯 覃慈 |
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| 作者单位： | 广西师范大学化学化工学院;桂林师范高等专科学校;广西贵港市港北区人民医院; |
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| 基金项目： | 广西教育厅科研基金资助项目(200911MS281200911MS282) |
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| 摘 要： | 分别以溴苯、对溴甲苯为起始原料,通过格氏反应、亲核取代反应以及氧化反应后得到目标产物1-甲基-1-苯乙基过氧化氢衍生物（4a-4b）,通过核磁共振、质谱和元素分析等表征手段对化合物的结构进行了表征,并对目标化合物的合成条件进行了优化。
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| 关 键 词： | 1-甲基-1-苯乙基过氧化氢衍生物 合成 格氏反应 亲核取代反应 氧化 |
Synthesis of the Derivatives of 1-methyl-1-Phenylethyl Hydroperoxide |
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| Wu Qiang,Qin Wen,Qin Ci.Synthesis of the Derivatives of 1-methyl-1-Phenylethyl Hydroperoxide[J].Journal of Guilin College of Education,2011,25(2):141-143. |
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| Authors: | Wu Qiang Qin Wen Qin Ci |
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| Institution: | Wu Qiang1,Qin Wen2,Qin Ci3(1.School of Chemistry and Chemical Engineering,Guangxi Normal University,Guilin,Guangxi 541004,China,2.Dept.of Chemistry and Engineering Technology,Guilin Normal College,Guilin Guangxi 541001,3.The People's Hospital of Gangbei,Guigang,Guangxi 537100,China) |
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| Abstract: | Starting from bromobenzene and parabromotoluene,1-methyl-1-phenylethyl hydroperoxide(4a-4b) were synthesized through grignard,nucleophilic substitution and oxidation reaction,respectively.Their structures were well characterizationed by 1H NMR,MS and elemental analysis,and the synthetic factors were then optimized. |
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| Keywords: | 1-methyl-1-phenylethyl hydroperoxide derivatives synthesis Grignard reaction nucleophilic substitution reaction oxidation reaction |
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