Stoichiometric evolutions of PH3 under high pressure: implication for high-Tc superconducting hydrides |
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| Authors: | Ye Yuan Yinwei Li Guoyong Fang Guangtao Liu Cuiying Pei Xin Li Haiyan Zheng Ke Yang Lin Wang |
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| Institution: | 1.Center for High Pressure Science and Technology Advanced Research, Shanghai 201203, China;2.School of Physics and Electronic Engineering, Jiangsu Normal University, Xuzhou 221116, China;3.Key Laboratory of Carbon Materials of Zhejiang Province, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China;4.Department of Physics, Fudan University, Shanghai 200433, China;5.Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201203, China |
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| Abstract: | The superconductivity of hydrides under high pressure has attracted a great deal of attention since the recent observation of the superconducting transition at 203 K in strongly compressed H2S. It has been realized that the stoichiometry of hydrides might change under high pressure, which is crucial in understanding the superconducting mechanism. In this study, PH3 was studied to understand its superconducting transition and stoichiometry under high pressure using Raman, IR and X-ray diffraction measurements, as well as theoretical calculations. PH3 is stable below 11.7 GPa and then it starts to dehydrogenate through two dimerization processes at room temperature and pressures up to 25 GPa. Two resulting phosphorus hydrides, P2H4 and P4H6, were verified experimentally and can be recovered to ambient pressure. Under further compression above 35 GPa, the P4H6 directly decomposed into elemental phosphorus. Low temperature can greatly hinder polymerization/decomposition under high pressure and retains P4H6 up to at least 205 GPa. The superconductivity transition temperature of P4H6 is predicted to be 67 K at 200 GPa, which agrees with the reported result, suggesting that it might be responsible for superconductivity at higher pressures. Our results clearly show that P2H4 and P4H6 are the only stable P–H compounds between PH3 and elemental phosphorus, which is helpful for shedding light on the superconducting mechanism. |
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| Keywords: | high pressure hydrides superconductivity stoichiometric evolution |
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