| 醇溶剂对吡啶鎓-N-苯氧内盐跃迁能的定量影响 |
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| 引用本文： | 曹晨忠.醇溶剂对吡啶鎓-N-苯氧内盐跃迁能的定量影响[J].湘潭师范学院学报(社会科学版),1997(6). |
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| 作者姓名： | 曹晨忠 |
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| 作者单位： | 湘潭师范学院化学系!湘潭，411201 |
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| 摘 要： | 讨论了以各种醇为溶剂测定的吡啶-N-苯氧内盐的跃迁能ET与醇分子结构的关系．结果表明ET与醇分子中烷基的极化效应指数PEI有良好的线性关系：ET=793682－24．4852PEI
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| 关 键 词： | 吡啶■-N-苯氧内盐 跃迁能 醇 烷基 极化效应指数 |
THE QUANTIFIED EFFECTING OF ALCOHOL SOLVENT ON THE TRANSITION ENERGY OF PRIDINIUM-1-PHENOLATE |
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| Cao Chenzhong.THE QUANTIFIED EFFECTING OF ALCOHOL SOLVENT ON THE TRANSITION ENERGY OF PRIDINIUM-1-PHENOLATE[J].Journal of Xiangtan Normal University(Social Science Edition),1997(6). |
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| Authors: | Cao Chenzhong |
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| Institution: | Cao Chenzhong |
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| Abstract: | The relation between the transition energy ET of pridinium-1-phenolate measured in deferent alcohol and the molecular structure of solvent alcohols were discussed. The obtained results showed that there is a good linear relation between the ET value and the alkyl polarizability effect index PEI value of alcoholmolecule, that is ET= 79.3682 -24.4852PEI. |
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| Keywords: | Pridinium-I-phenolate Transition energy Alcohol Alkyl polarizability effect index |
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