| 硫属化合物[dienH_2]Hg_2Sb_2S_6(dien=diethylenetriamine)的溶剂热合成及其晶体结构 |
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| 引用本文： | 雷晓武,赵建强,王晨,巩亚苹,刘新月,巴忠仁,刘新颖.硫属化合物[dienH_2]Hg_2Sb_2S_6(dien=diethylenetriamine)的溶剂热合成及其晶体结构[J].济宁师范专科学校学报,2014(3):36-38,42. |
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| 作者姓名： | 雷晓武 赵建强 王晨 巩亚苹 刘新月 巴忠仁 刘新颖 |
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| 作者单位： | 山东省高校无机化学重点实验室、济宁学院化学与化工系,山东曲阜273155 |
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| 基金项目： | 国家自然科学基金青年基金（21101075和21201081）;山东省优秀中青年科学家科研奖励基金（博士基金,BS2011CL009和BS2012CL00）;山东省高等学校科技计划项目（Jl1LB52）. |
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| 摘 要： | 在400K温度下,以HgCl2,Sb粉和S粉为原料,将其按化学计量比进行混合,在二乙烯三胺和水混合溶剂的条件下,通过溶剂热合成方法反应得到了一个新的硫属化合物dienH2]Hg2Sb2S6.通过元素分析和X-射线单晶衍射仪对此化合物进行结构表征,该晶体属于正交晶系,空间群为Cmca.该化合物由二维层状的Hg2Sb2S6]2-阴离子和质子化的dienH2]2+阳离子组成,两种结构通过氢键相互连接形成二维层状结构.
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| 关 键 词： | 硫属化合物 溶剂热合成 晶体结构 |
Solvothermal Synthesis and Crystal Structure of [dienH2]Hg2Sb2S6 |
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| LEI Xiaowu,ZHAO Jianqiang,WANG Chen,GONG Yaping,LIU Xinyue,BA Zhongren,LIU Xinying.Solvothermal Synthesis and Crystal Structure of [dienH2]Hg2Sb2S6[J].Journal of Jining Teachers College,2014(3):36-38,42. |
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| Authors: | LEI Xiaowu ZHAO Jianqiang WANG Chen GONG Yaping LIU Xinyue BA Zhongren LIU Xinying |
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| Institution: | (Key Laboratory of Inorganic Chemistry in Universities of Shandong, Department of Chemistry and Chemical Engineering, Jining University, Qufu 273155, China) |
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| Abstract: | A new transition metal complex directedmercury thioantimonate, dienH2]Hg2Sb2S6（dien = diethylenetriamine）, has been synthesized by solvothermal reaction of HgCl2, Sb and S in diethylenetriamine solution at 400 K. The crystal structure was characterized by elemental analysis and single-crystal X-ray diffraction. The title compound crystallizes in the orthorhombic system （Cmca）. The structure consists of two-dimensional （2D） Hg2Sb2S6]2 -layer and protonated diethylenetriamine cationdienH2]2＋. These two types of units are interlinked via various hydrogen-bonding interactions to from a two-dimensional （3D） framework. |
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| Keywords: | mercury thioantimonate solvothermal synthesis crystal structure |
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