| 甘油水体系中碳酸钙的水热合成 |
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| 引用本文： | 吴刚,鲜华,王小锋,俞力.甘油水体系中碳酸钙的水热合成[J].南京晓庄学院学报,2010,26(3):6-8. |
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| 作者姓名： | 吴刚 鲜华 王小锋 俞力 |
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| 作者单位： | 1. 滁州学院化学和生命科学系,安徽,滁州,239012
2. 南京晓庄学院生物化工与环境工程学院,江苏,南京,211171 |
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| 基金项目： | 安徽省教育厅自然科学基金，安徽省应化学重点建设学科 |
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| 摘 要： | 在120℃下,分别在超纯水、甘油-水混合溶剂条件下水热合成了CaCO3晶体,用粉末XRD衍射方法和红外光谱对合成的晶体进行了表征,用扫描电子显微镜观察分析了生成的CaCO3晶体的形貌,研究甘油-水体积比对CaCO3晶体的晶型和形貌的影响.结果发现,在甘油-水体积比2/5,4/5中得到的是文石和方解石的混合物,但主要是文石晶体;在甘油-水体积比是7/5和纯甘油中得到的是球霰石和方解石晶体的混合物.
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| 关 键 词： | 甘油 方解石 文石 球霰石 |
Synthesis of Calcium Carbona under Hydrothermial Condition in the System of Glycerol and Water |
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| WU Gang,XIAN Hua,WANG Xiao-feng,YU Li.Synthesis of Calcium Carbona under Hydrothermial Condition in the System of Glycerol and Water[J].Journal of Nanjing Xiaozhuang College,2010,26(3):6-8. |
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| Authors: | WU Gang XIAN Hua WANG Xiao-feng YU Li |
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| Institution: | 1.Dept.of Chemistry and Life and Science,Chuzhou University,Chuzhou 239012,Anhui;2.School of Biochemistry and Environmental Engineering,Nanjing Xiaozhuang University,Nanjing 211171,Jiangsu) |
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| Abstract: | Calcium carbonate particles were prepared by a precipitation reaction of urea with calcium acetate from water and organic solvents in the system of glycerol-water at 120℃.The as-prepared products were characterized by X-ray diffraction and FT-IR.The shapes were observed by scanning electron microscopy.The effects of different solvents on the crystal shape and morphology of the as-prepared CaCO3 were investigated and discussed.The results show that solvent can have a great influence on the shapes of CaCO3 at relative higher temperature. |
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| Keywords: | glycerol calcite aragonite vaterite |
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