| 异丁烯酸甲酯/氰酸酯树脂半互穿聚合物的合成与表征 |
| |
| 引用本文： | 祝保林.异丁烯酸甲酯/氰酸酯树脂半互穿聚合物的合成与表征[J].渭南师范学院学报,2012(2):61-66. |
| |
| 作者姓名： | 祝保林 |
| |
| 作者单位： | 渭南师范学院化学与生命科学学院,陕西渭南,714000 |
| |
| 基金项目： | 陕西省自然科学专项基金项目(2010K06-07);陕西省教育厅科研资助项目(2010JK546,2010JK547);西安市工业科技攻关项目(YF07058) |
| |
| 摘 要： | 于加热熔融的氰酸酯树脂(BACDy)中加入异丁烯酸甲酯(MMA),在引发剂存在下,引发单体及预聚体MMA发生本体聚合,采用同步合成法和异步合成法分别制备互穿聚合物网络氰酸酯树脂/聚异丁烯酸甲酯(BACDy/MMA-SIPN)高分子材料,研究了几种不同配比的SIPN体系.结果表明,BACDy/MMA-SIPN网络形成的反应条件对体系的力学性能和耐热性能都有较大提高.给出了较合理的制备工艺条件.
|
| 关 键 词： | 氰酸酯树脂 异丁烯酸甲酯 同步/异步合成法 半互穿聚合物网络 |
Preparation and Characterization of Methyl Ester/BADCy SIPN |
| |
| ZHU Bao-lin.Preparation and Characterization of Methyl Ester/BADCy SIPN[J].Journal of Weinan Teachers College,2012(2):61-66. |
| |
| Authors: | ZHU Bao-lin |
| |
| Institution: | ZHU Bao-lin(School of Chemistry and Life Science,Weinan Normal University,Weinan 714000,China) |
| |
| Abstract: | methyl ester(MMA) was added into melting cyanate ester resin(BACDy) with the presence of initiator.Bulk polymerization occurred via monomer and prepolymer MMA reaction.Semi-interpenetrating polymer network-cyanate ester resin / PMMA(BACDy / MMA-SIPN) polymer material were prepared by synchronous and asynchronous synthesis.Meanwhile,several different components of SIPN system were discussed.The results show that,the formation of BACDy/MMA-SIPN network reaction conditions are greatly improved the mechanical properties and heat resistance.An optimal preparation conditions was proposed. |
| |
| Keywords: | BADCy methyl ester synchronization/asynchronism synthesize SIPN |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
