Polychlorinated dibenzo-p-dioxins and dibenzofurans in flue gas emissions from municipal solid waste incinerators in China |
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| Authors: | Tong CHEN Yue-ling GU Jian-hua YAN Xiao-dong LI Sheng-yong LU Hui-fen DAI Ke-fa CEN |
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| Institution: | [1]State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China [2]School of Medicine, Zhejiang University, Hangzhou 310058, China |
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| Abstract: | Polychlorinated dibenzo-p-dioxins and furalls(PCDD/Fs)emissions in flue gas from two types of municipal solid waste incinerators(MSWIs)most commonly used in China were investigated in this study.The selected incinerators include two grate-type MSWIs:MSWl-A(350 t/d)and MSWI-B(150 t/d),and two fluidized bed MSWIs:MSWI-C(400 t/d) and MSWI-D (400 t/d),which are all equipped with semi-dry lime scrubber and bag filter except MSWI-D equipped with cyclone and wet scrubber(WS)as air pollutant conffol device(APCD).Results indicated that the emission concentration and the international toxic equivalents(I-TEQs)of the PCDD/Fs from the stacks were in the range of 1.210～10.273 ng/Nm3 and 0.019～0.201 ngI-TEQ/Nm3,respectively.They were greatly lower than the emission regulation standard of PCDD/FS in China(1.0 ng I-TEQ/Nm3).However,only the PCDD/Fs emission Ievel from MSWI-C Was below 0.1 ng I-TEQ/Nm3.Although the homologue profiles were distinct,the contributions of the 2,3,7,8-subsituted congenem to the total I-TEQ were similar among all the investigated MSWIs.Two major 2,3,7,8-substituted congeners,2,3,4,7,8-PeCDF and 1,2,3,7,8-PeCDD,account for 47% and 9%(average values)of the total I-TEQ values,respectively.The correlation between PCDD/Fs levels and composition of flue gas Was also discussed. |
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| Keywords: | Polychlorinated dibenzo-p-dioxins and dibenzofurans(PCDD/Fs) Municipal solid waste incinerator(MSWI) Grate Fluidized bed |
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