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Pigments and binders in “Madonna col Bambino e S. Giovannino” by Botticelli investigated by micro-Raman and GC/MS
Authors:Danilo Bersani  Pier Paolo Lottici  Antonella Casoli  Diego Cauzzi
Institution:aDipartimento di Fisica, Università di Parma, Viale G.P. Usberti 7/a, 43100 Parma, Italy;bDipartimento di Chimica Generale e Inorganica, Chimica Analitica, Chimica Fisica, Università di Parma, Viale G.P. Usberti 17/a, 43100 Parma, Italy;cSoprintendenza per il Patrimonio Storico Artistico e Demoetnoantropologico, via Belle Arti, 56, 40126 Bologna, Italy
Abstract:During the restoration plan of the famous painting “Madonna col Bambino e S. Giovannino” by Sandro Botticelli, located in the Museo Civico of Piacenza (Italy), a study on painting materials was carried out. The pigments, the binders and the materials used for the application of ground and priming layers were studied using micro-Raman spectroscopy, gas chromatography coupled with mass spectrometry (GC/MS), optical and electronic microscopies. Gypsum and anhydrite were found in the ground layer, while carbon black and lead white were used in the priming layers. The precious pigments of the artist's palette and the binders used (egg and animal glue) were determined.
Keywords:Pigments  Binders  Micro-Raman  GC-MS  Botticelli  Paintings
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