| 硫醇引发MMA和AN共聚的溶剂效应 |
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| 引用本文： | 夏平,王康成,冯明明.硫醇引发MMA和AN共聚的溶剂效应[J].湖州师范学院学报,1991(6). |
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| 作者姓名： | 夏平 王康成 冯明明 |
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| 作者单位： | 湖州师专化学系
(夏平，王康成)，千金中学(冯明明) |
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| 摘 要： | 本文研究了叔十二烷基硫醇引发甲基丙烯酸甲酯与丙烯腈共聚在三种不同溶剂中反应的动力学有关问题.发现硫醇引发该共聚反应中,聚合反应速率随单体中甲基丙烯酸甲酯的组分增大而提高,及与溶剂的极性成正比关系.
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| 关 键 词： | 电子转移络合体 溶剂极性 |
Solvet Effects on Copolymerization of Methyl Methacrylate With Acrylonitrile Initiated by 2-Methyl-2-Undecanethiol |
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| Xia Ping,Wang Kangcheng,Feng Mingming.Solvet Effects on Copolymerization of Methyl Methacrylate With Acrylonitrile Initiated by 2-Methyl-2-Undecanethiol[J].Journal of Huzhou Teachers College,1991(6). |
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| Authors: | Xia Ping Wang Kangcheng Feng Mingming |
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| Institution: | Department of Chemistry |
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| Abstract: | This paper studies problems of lunatics about polymerization reaction of methyl methacrylate with acrylonitrile initiated by 2-methyl-2-undecanetlliol in three different solvents. Describes that the rate of the copolymerization increases with the increase of the value of methyl methacrylate in monone rand the polar of the solvent . |
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| Keywords: | electron-transfer complex polar of the solent |
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