一种新的含三氟甲基氨基甲酸酯的合成 |
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引用本文: | 陈荣祥,;孔伟光,;孟团结,;赵文献.一种新的含三氟甲基氨基甲酸酯的合成[J].商丘师范学院学报,2014(9):27-29. |
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作者姓名: | 陈荣祥 ;孔伟光 ;孟团结 ;赵文献 |
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作者单位: | [1]郑州大学化学与分子工程学院,河南郑州450052; [2]商丘师范学院化学化工学院,有机新材料合成重点实验室,河南商丘476000 |
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基金项目: | 国家自然科学基金(No,21172139)资助项目 |
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摘 要: | 以三氟苯乙酮、溴代烃和异氰酸酯为原料,在金属锌的促进下,室温条件下通过三组分"一锅法"反应合成了新型的含三氟甲基氨基甲酸酯类化合物.产品结构经过IR、H1NMR、C13NMR和HRMS进行了确认.
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关 键 词: | 氨基甲酸酯 三氟甲基 锌 三组分 一锅法 |
Synthesis of a new carbamates containing trifluoromethyl |
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Institution: | CHEN Rongxiang, KONG Weiguang, MENG Tuanjie, ZHAO Wenxian (1. The College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450052, China; 2. Key Laboratory of New Organic Materials Synthesis, School of Chemistry and Chemical Engeniring, Sbangqiu Normal University, Shangqiu 476000, China ) |
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Abstract: | In the promotion of metallic zinc, a novel carbamate containing trifluoromethy was synthesised by 2,2,2-Trifluoroacetophenone , brominated hydrocarbons and isocyanate in “one pot” at room temperature .The structure of the new carbamate were confirmed by IR , 1H NMR, 13 C NMR, HRMS. |
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Keywords: | carbamate trifluoromethyl zinc three-component one pot |
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