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Fenton氧化工艺在处理炼化废水中苯酚的应用研究
引用本文:李锐.Fenton氧化工艺在处理炼化废水中苯酚的应用研究[J].兰州石化职业技术学院学报,2014(4):8-10.
作者姓名:李锐
作者单位:兰州石化职业技术学院 人事处,甘肃 兰州,730060
摘    要:通过正交实验和单因素实验探索了Fenton氧化炼化废水中苯酚的最佳工艺条件。实验结果表明,Fenton试剂处理苯酚废水时,各影响因素的作用大小顺序是:p H反应温度H2O2投加量反应时间Fe SO4·7H2O投加量;最佳氧化反应条件为:p H=3.5,反应温度为20℃,H2O2投加量为12 m L·L-1,反应时间为30min,Fe SO4·7H2O投加量为450 mg·L-1,此时废水中苯酚的去除率为89.26%,残余苯酚含量为11.76 mg·L-1。因此,用Fenton氧化法处理含苯酚废水是一种非常有效的方法。

关 键 词:Fenton试剂  苯酚  炼化废水

Study on Treatment of Phenol in Petroleum Refining Industry Wastewater by Fenton Reagent
LI Rui.Study on Treatment of Phenol in Petroleum Refining Industry Wastewater by Fenton Reagent[J].Journal of Lanzhou Petrochemical Vocational College of Technology,2014(4):8-10.
Authors:LI Rui
Institution:LI Rui (Lanzhou petrochemical college of vocational technology, Lanzhou Gansu 730060, China)
Abstract:Removal of phenol in petroleum refining industry wastewater by Fenton reagent oxidation was examined. The optimal operating conditions were determined by orthogonal experiments and single factor experiments.The ex-periment results indicated that the order of effects was pH〉reaction temperature〉H2 O2 dosage 〉reaction time〉FeSO4 7H2O dosage.After 30min,the removal rate of phenol in petroleum refining industry wastewater reaches 89.26% and the residual phenol in wastewater is 11.76 mg·L^-1 when pH value is 3.5,temperature is 20 ℃, H2 O2 and FeSO4 dosage is 12 mL·L^-1 and 450mg/L,respectively.So it is a very effective way to treat petroleum refining industry wastewater containing phenol using Fenton method.
Keywords:fenton reagent  phenol  petroleum refining wastewater
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