| 离子液体中水溶性催化剂催化长链烯烃氢甲酰化反应 |
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| 引用本文： | 林棋,郑惠榕,黄晓东.离子液体中水溶性催化剂催化长链烯烃氢甲酰化反应[J].闽江学院学报,2007,28(5):88-96. |
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| 作者姓名： | 林棋 郑惠榕 黄晓东 |
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| 作者单位： | 闽江学院化学与化学工程系.福建福州,350108 |
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| 基金项目： | 福建省青年人才创新基金(2006F3099)，福建省教育厅A类科技项目(A2006054)，闽江学院科研启动项目(YKQ06003) |
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| 摘 要： | 从离子液体/有机两相催化体系、固定化离子液体多相催化体系、离子液体/超临界二氧化碳催化体系等,总结了离子液体在水溶性铑膦络合物催化长链烯烃氢甲酰化反应的应用.与传统溶剂相比,离子液体不仅是传统意义上的反应介质,而且还具有促进反应活性和选择性、简化催化剂与产物的分离等功能.
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| 关 键 词： | 离子液体 烯烃 氢甲酰化反应 水溶性催化剂 |
| 文章编号： | 1009-7821(2007)05-0088-09 |
| 修稿时间： | 2007年6月18日 |
Hydroformylation of higher olefin catalyzed by water-soluble rhodium-phosphine catalyst in ionic liquid |
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| LIN Qi,ZHENG Hui-long,HUANG Xiao-dong.Hydroformylation of higher olefin catalyzed by water-soluble rhodium-phosphine catalyst in ionic liquid[J].Journal of Minjiang University,2007,28(5):88-96. |
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| Authors: | LIN Qi ZHENG Hui-long HUANG Xiao-dong |
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| Institution: | LIN Qi, ZHENG Hui-long, HUANG Xiao-dong ( Department of Chemistry and Chemical Engineering, Minjiang University, Fuzhou Fujian 350108, China) |
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| Abstract: | As novel environmentally friendly solvents and catalysts,ionic liquids have been received increasing recognition and acceptance.They exhibited great potential advantages in the development of novel catalytic technologies of organic synthesis with better yield and selectivity.The applications of ionic liquids in the hydroformylation of higher olefins were summarized,which included ionic liquid-organic biphasic system,supported ionic liquid-phase catalytic system,ionic liquid-scCO2 biphasic system.In the hydroformylation of higher olefins,ionic liquid can not only exert the effects as the traditional reaction medium,but also can achieve the functions such as enhance reaction activity and selectivity,simplify separation of catalyst from product,support and activate catalyst. |
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| Keywords: | ionic liquid olefin hydroformylation water-soluble catalyst |
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