| Synthesis of Novel Ionic Liquid （[C4CNmim]^＋PF6^-） and Application to Preparation of Polyketone |
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| 引用本文： | 郭锦棠,胡光,高珊.Synthesis of Novel Ionic Liquid （[C4CNmim]^＋PF6^-） and Application to Preparation of Polyketone[J].天津大学学报(英文版),2011,17(2):107-110. |
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| 作者姓名： | 郭锦棠 胡光 高珊 |
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| 作者单位： | School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China |
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| 基金项目： | Supported by National Natural Science Foundation of China (No.20476080); Tianjin Natural Science Foundation (No.07JCYBJC00600) |
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| 摘 要： | N-valeronitrile-N’-methylimidazolium hexafluorophosphate (C 4 CNmim]+ PF 6),as a novel ionic liquid with polar nitrile functional group,was prepared.The structure of the ionic liquid was characterized by using IR and 1 H NMR.As a medium,the ionic liquid plays an important role in copolymerization of carbon monoxide (CO) with styrene (St).Some synthetic conditions were determined,including the usage of ionic liquid,palladium composite catalyst and methanol,CO pressure,reaction time and reaction temperature.The influence of these factors on catalytic activity was analyzed.The results show that the catalytic activity has reached 1 724.1 gStCO/(gPd·h) and the catalyst could be reused 5 times under the optimal condition:composite catalyst 0.015 mmol,ionic liquid 3 mL,methanol 0.75 mL,CO pressure 2MPa,reaction time 2 h and reaction temperature 70℃.This CO/St copolymerization within C 4 CNmim]+ PF 6 system could facilitate ionic liquids with efficient and economical applications to polymeric materials.
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| 关 键 词： | 离子液体 合成条件 应用 复合催化剂 制备 聚酮 反应时间 反应温度 |
| 收稿时间： | 8 May 2007 |
Synthesis of Novel Ionic Liquid ([C4CNmim]+PF6-) and Application to Preparation of Polyketone |
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| GUO Jintang,HU Guang,GAO Shan.Synthesis of Novel Ionic Liquid ([C4CNmim]+PF6-) and Application to Preparation of Polyketone[J].Transactions of Tianjin University,2011,17(2):107-110. |
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| Authors: | GUO Jintang HU Guang GAO Shan |
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| Institution: | School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China |
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| Abstract: | N-valeronitrile-N′-methylimidazolium hexafluorophosphate (C4CNmim]+PF6
−), as a novel ionic liquid with polar nitrile functional group, was prepared. The structure of the ionic liquid was characterized
by using IR and 1H NMR. As a medium, the ionic liquid plays an important role in copolymerization of carbon monoxide (CO) with styrene (St).
Some synthetic conditions were determined, including the usage of ionic liquid, palladium composite catalyst and methanol,
CO pressure, reaction time and reaction temperature. The influence of these factors on catalytic activity was analyzed. The
results show that the catalytic activity has reached 1 724.1 gStCO/(gPd·h) and the catalyst could be reused 5 times under
the optimal condition: composite catalyst 0.015 mmol, ionic liquid 3 mL, methanol 0.75 mL, CO pressure 2 MPa, reaction time
2 h and reaction temperature 70 °C. This CO/St copolymerization within C4CNmim]+PF6
− system could facilitate ionic liquids with efficient and economical applications to polymeric materials. |
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| Keywords: | nitrile ionic liquid polyketone synthetic condition carbon monoxide styrene |
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