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几种离子对光催化降解罗丹明B的影响
引用本文:黄雅丽,徐清艳.几种离子对光催化降解罗丹明B的影响[J].闽江学院学报,2013(5):129-133.
作者姓名:黄雅丽  徐清艳
作者单位:闽江学院化学与化学工程系,福建福州350121
基金项目:福建省教育厅科技项目(JA11198,JB10123,JB11140)
摘    要:采用罗丹明B作为目标降解物,考察了几种离子对光催化降解罗丹明B脱色率的影响.结果显示,低浓度的Ca2+和Al3+对罗丹明B的脱色率影响不明显,但是当它们的浓度增加到一定值后,则脱色率明显下降;当Fe3+的浓度为0.2 ~0.5 mmol·L-1时,其对光催化降解罗丹明B有一定的促进作用,继续增加Fe3+的浓度,反而起到明显的抑制作用;Cu2+对光催化降解罗丹明B具有显著的抑制作用;Na+、Cl-、NO3-、SO42-对光催化降解的影响均不明显,有些离子的影响机制有待进一步研究.

关 键 词:光催化降解  罗丹明B  离子  脱色率

Effect of several ions on photocatalytic degradation of Rhodamine B
HUANG Ya-li,XU Qing-yan.Effect of several ions on photocatalytic degradation of Rhodamine B[J].Journal of Minjiang University,2013(5):129-133.
Authors:HUANG Ya-li  XU Qing-yan
Institution:( Department of Chemistry and Chemical Engineering, Minjiang University, Fuzhou, Fujian 350121, China)
Abstract:This paper adopted Rhodamine B as a target degradation material. The effects on the decoloriza- tion rate of photocatalytic degradation of Rhodamine B of some irons have been studied. The results showed that the low concentration of Ca2+ and AI3. had unobvious effect on the decolorization rate. But when their concentration increased to a certain value, the decolorization rate decreased evidently. When the content of Fe3 + ranged from 0.2 mmol ·L-1 to 0.5 mmol ·L-1, the decolorization rate increased. However,Fe3+ showed significantly inhibition with further raising the concentration. Cu2. had strongly negative influence on the photocatalytic reaction. Na+ ,CI- , NO3 and SO42- had little impact on catalytic degradation. The mechanisms of the effect of some ions need further study.
Keywords:photocatalytic degradation  Rhodamine B  ions  decolorization rate
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