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间苯三酚Williamson烷基化反应研究
引用本文:孙祥玉,黄玉梅,赵瑶兴,樊平,樊美公.间苯三酚Williamson烷基化反应研究[J].中国科学院研究生院学报,1998(2).
作者姓名:孙祥玉  黄玉梅  赵瑶兴  樊平  樊美公
作者单位:中国科学院感光化学所
摘    要:考察了间苯三酚在不同介质中的烷基化反应及其不正常反应产物.研究了在非质子极性溶剂中,18-冠醚-6用作催化剂的Wiliamson烷基化反应,成功地合成了间苯三酚的单辛基、二辛基和三辛基醚,并对反应条件和产物组成关系进行了讨论.

关 键 词:Williamson烷基化,间苯三酚醚,相转移催化剂

Williamson Alkylation of Phloroglucin
Sun Xiangyu\ Huang Yumei\ Zhao Yaoxing.Williamson Alkylation of Phloroglucin[J].Journal of the Graduate School of the Chinese Academy of Sciences,1998(2).
Authors:Sun Xiangyu\ Huang Yumei\ Zhao Yaoxing
Abstract:The alkylation of phloroglucin in varied media and the products of irregular reaction have been examined The Williamson alkylation of phloroglucin in non protonic polar solvents and catalysis by 18 Crown 6 was investigated The mono ,di and trioctyl ether of phloroglucin have been synthesized successfully The relation between reaction condition and composition of products were also discussed
Keywords:williamson alkylation  ether of phloroglucin  phase transfer catalysis  
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