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Ni对CO高变催化剂结构和性能影响
引用本文:林茹.Ni对CO高变催化剂结构和性能影响[J].泉州师范学院学报,2000,18(4):28-31.
作者姓名:林茹
作者单位:福建农业大学基础部化学组,福建,福州,350002
摘    要:用XRD,FT-IR,XPD和Mossbauer对样品进行表征。Ni的加入有2/3以氢氧化物型态存在,增加了催化剂表面ON∧-的浓度,使催化剂在较低汽气比条件下具有较高催化活性,Ni不可能进入Fe3O4尖晶石晶格的A位,从而改变催化剂的电子结构和几何结构,起结构助剂作用。

关 键 词:高变催化剂  低汽气比    一氧化碳  结构  性能  合成氨
文章编号:1008-4924(2000)04-0028-04
修稿时间:2000年3月6日

Effect of Ni on the Structure and Property of the Catalyst for Co High Temperature Shifting Reaction
Lin Ru.Effect of Ni on the Structure and Property of the Catalyst for Co High Temperature Shifting Reaction[J].Journal of Quanzhou Normal College,2000,18(4):28-31.
Authors:Lin Ru
Abstract:Catalysts were characterized by XRD,FT-IR,XPS and Mssbauer.The addition of Ni,2/3 of which exit with hydroxide which raises denity OH - on the surface of the catalyst improved the catalytic activity under the low vap./gas ratio condition.Ni may enter A space of Fe 3O 4 spine lattice.It is guide to change electronic and geometric structure and to act the effect of framework auxiliary.
Keywords:Ni  high-temperature-shifting of catalyst  low vap  /gas
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