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锂离子电池负极材料Sb2O3-x/rGO的氧缺陷构建及其电化学性能研究
引用本文:韩正思,王浩,何晓蕾,孔凡军,陶石,钱斌,江学范.锂离子电池负极材料Sb2O3-x/rGO的氧缺陷构建及其电化学性能研究[J].常熟理工学院学报,2020(2):19-23.
作者姓名:韩正思  王浩  何晓蕾  孔凡军  陶石  钱斌  江学范
作者单位:常熟理工学院电子信息工程学院;常熟理工学院江苏省新型功能材料重点建设实验室;中国矿业大学材料科学与工程学院
基金项目:苏州市绿色储能电池及系统技术重点实验室,苏州市2017年度第十批科技发展计划(科技设施)项目(SZS201710);高安全性高性能三元动力锂电池模组的研发及产业化,江苏省科技厅成果转化专项资金项目(BA2016041)。
摘    要:成功制备了氧缺陷型Sb2O3-x/rGO复合材料.与纯Sb2O3材料相比,Sb2O3-x/rGO复合材料颗粒尺寸大大减小,导电性能得到提高,作为锂离子电池的负极材料,具有更高的可逆能力、更好的循环稳定性和良好的倍率性能.在电流密度为100 mAh·g^-1的情况下,Sb2O3-x/rGO复合材料的初始放电容量可达1336.6 mAh·g^-1.即使经过50次充放电循环后,其充放电容量依然可以保持在405.8 mAh·g^-1.

关 键 词:氧缺陷  Sb2O3-x/rGO  负极材料  锂离子电池

Oxidation Defect Construction and Electrochemical Performance of Sb2O3-x/rGO as Anode Materials for Lithium Ion Batteries
HAN Zhengsi,WANG Hao,HE Xiaolei,KONG Fanjun,TAO Shi,QIAN Bin,JIANG Xuefan.Oxidation Defect Construction and Electrochemical Performance of Sb2O3-x/rGO as Anode Materials for Lithium Ion Batteries[J].Journal of Changshu Institute of Technology,2020(2):19-23.
Authors:HAN Zhengsi  WANG Hao  HE Xiaolei  KONG Fanjun  TAO Shi  QIAN Bin  JIANG Xuefan
Institution:(School of Electronic and Information Engineering,Changshu Institute of Technology,Changshu 215500;Jiangsu Laboratory of Advanced Functional Materials,Changshu Institute of Technology,Changshu 215500;School of Materials Science and Engineering,China University of Mining and Technology,Xuzhou 221116,China)
Abstract:Oxygen-defect Sb2O3-x/rGO composites were successfully prepared in this paper.Compared with pure Sb2O3 material,Sb2O3-x/rGO composite material has greatly reduced particle size and improved electrical conductivity.As the anode material of lithium ion battery,it has a higher reversibility,better cycle stability and greater magnification performance.When the current density is 100 mA·g^-1,the initial discharge capacity of Sb2O3-x/rGO composite material can reach 1336.6 mAh·g^-1.Even after 50 charging and discharging cycles,its capacity can still remain at 405.8 mAh·g^-1.
Keywords:oxygen-defect  Sb2O3-x/rGO  anode material  lithium ion battery
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