| Pd/Fe与Fe~0催化还原降解酸性紫红B的动力学比较 |
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| 引用本文： | 裴婕,贾颖萍,房成岳.Pd/Fe与Fe~0催化还原降解酸性紫红B的动力学比较[J].大连大学学报,2004,25(2):60-61,69. |
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| 作者姓名： | 裴婕 贾颖萍 房成岳 |
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| 作者单位： | 1. 大连大学,化学与化学工程系,辽宁,大连,116622
2. 大连第一互感器厂,辽宁,大连,116200 |
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| 基金项目： | 辽宁省高等学校优秀青年教师教学和科研奖励基金，， |
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| 摘 要： | 采用Fe0还原、钯催化法对偶氮染料———酸性紫红B进行还原脱色研究,测定了钯/铁及普通铁粉在相同条件下对酸性紫红B的还原降解反应速率常数.实验表明,酸性紫红B的零价铁及钯/铁催化还原降解均遵守一级动力学,且钯/铁的反应速率常数较普通铁粉有明显增大.
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| 关 键 词： | 反应速率常数 Pd/Fe Fe0 还原 酸性紫红B |
| 文章编号： | 1008-2395(2004)02-0060-03 |
| 修稿时间： | 2003年10月23 |
Comparison of kinetics of acid violet red B reduced by Pd/Fe and normal Fe0 |
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| PEIJie.Comparison of kinetics of acid violet red B reduced by Pd/Fe and normal Fe0[J].Journal of Dalian University,2004,25(2):60-61,69. |
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| Authors: | PEIJie |
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| Abstract: | The reductive degradation of acid violet red B by palladium/iron(Pd/Fe)is measured.The degradation of acid violet red B on the Pd/Fe and that on the conventional iron powder are compared. It was found that the catalytic degradation of acid violet red B on the Pd/Fe and the zero-valent iron follow the first-order kinetics and the rate constant on Pd/Fe is higher than that on the conventional iron powder, |
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| Keywords: | first-order kinetics constant Pd/Fe Fe~(0) reduce acid violet red B |
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