| Photochemical reactions of poly（3-butoxythiophene-2,5-diyl） with chloroform |
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| 作者姓名： | Imit M Yamamoto T Imin P |
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| 作者单位： | School of Chemistry and Chemical Engineering,Xinjiang University,Urumqi 830046,China Chemical Resources Laboratory,Tokyo Institute of Technology,Yokohama 226-8503,Japan,Chemical Resources Laboratory,Tokyo Institute of Technology,Yokohama 226-8503,Japan,School of Chemistry and Chemical Engineering,Xinjiang University,Urumqi 830046,China |
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| 摘 要： | INTRODUCTION π-conjugated polymers have received a great deal of attention because of their unique chemical and physical properties, including electrochromism, electrically conducting properties, chemical sensing ability, and electroluminescent properties. Their structures, synthetic methodologies, and physical and chemical properties were intensely studied in the past two decades (Friend et al., 1999; Heeger, 2001; Ya-mamoto, 2002). Especially, processable derivatives of polythiophene …
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| 关 键 词： | 光化学反应 聚乙烯 动力学 氯仿 空间温度 |
| 收稿时间： | 2005-05-08 |
| 修稿时间： | 2005-06-28 |
Photochemical reactions of poly(3-butoxythiophene-2,5-diyl) with chloroform |
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| Imit M,Yamamoto T,Imin P.Photochemical reactions of poly(3-butoxythiophene-2,5-diyl) with chloroform[J].Journal of Zhejiang University Science,2005,6(8):722-724. |
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| Authors: | Imit Mokhtar Yamamoto Takakazu Imin Patigul |
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| Institution: | (1) School of Chemistry and Chemical Engineering, Xinjiang University, 830046 Urumai, China;(2) Chemical Resources Laboratory, Tokyo Institute of Technology, 226-8503 Yokohama, Japan |
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| Abstract: | Photochemical reactions of poly(3-butoxythiophene-2,5-diyl) with chloroform under irradiation with light were studied. The reactions were separately carried out under air, oxygen, and nitrogen. The obtained results showed that this reaction belongs to the pseudo-first-order reaction with a rate constant kobs of 1.4× 10-5 s-1 at room temperature. The presence or absence of air, oxygen, and nitrogen did not have obvious effects on the reaction rate under irradiation with light. |
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| Keywords: | Poly(3-butoxythiophene-2 5-diyl) Photochemical reaction Kinetics |
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