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噻吩修饰的四苯乙烯衍生物的合成
引用本文:王静,余欢,刘澜涛.噻吩修饰的四苯乙烯衍生物的合成[J].商丘师范学院学报,2014(6):39-41.
作者姓名:王静  余欢  刘澜涛
作者单位:商丘师范学院化学化工学院;商丘市第二高级中学;
基金项目:国家自然科学基金资助项目(21302120);河南省教育厅科学技术研究重点项目(13A150826)
摘    要:以4-溴二苯甲酮为起始原料,经McMurry反应和Suzuki偶联反应,合成出新型噻吩修饰的四苯乙烯衍生物TPE-T(a-b)和TPE-2T(a-b).新化合物的结构经1H NMR,13C NMR,MS及元素分析表征.新化合物表现出独特的聚集诱导发光现象.

关 键 词:四苯乙烯  噻吩  聚集诱导发光

Synthesis of tetraphenylethene derivatives modified by thiophene
Institution:WANG Jing , YU Huan, LIU Lantao(1. College of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu 476000, China; 2. Shangqiu Second Senior High School, Shangqiu 476000, China)
Abstract:Tetraphenylethene derivatives TPE - T ( a - b) and TPE - 2T ( a - b ) were successfully synthesized by McMurry and Suzuki coupling reaction from 4 - bromobenzophenone. The structures of new compounds were characterized by 1 H NMR, 13C NMR, MS and elemental analysis. The new compounds exhibit the novel feature of aggregation - induced emission.
Keywords:tetraphenylethene  thiophene  aggregation - induced emission
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