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硼对金属间化合物Ni3Fe氢气诱发环境氢脆的影响
引用本文:石丹丹,陈业新,万晓景,LIU Chain Tsuan.硼对金属间化合物Ni3Fe氢气诱发环境氢脆的影响[J].上海大学学报(英文版),2007,11(2):102-105.
作者姓名:石丹丹  陈业新  万晓景  LIU Chain Tsuan
作者单位:[1]Institute of Materials Science, Shanghai University, Shanghai 200072, P. R. China [2]Department of Materials Science and Engineering, University of Tennessee, TN37996-2200, USA
摘    要:In this paper the tensile properties of both ordered and disordered Ni-24Fe and Ni-24Fe-0.03%B (wt%) alloys in gaseous hydrogen was investigated. The result shows that the ductility of the disordered Ni3Fe is significantly larger than that of ordered material in gaseous hydrogen. However, the ductility of ordered Ni3Fe doped with 0.03%B is nearly the same as that of disordered one indicating the obvious suppressing effect of boron on the H2-induced embrittlement. Based on the segregation behavior of boron in Ni3A1, it is proposed that the suppressing effect of boron in Ni3Fe on the H2-induced embrittlement is attributed to the segregation of boron on grain boundaries, thereby reducing the hydrogen diffusivity along the grain boundaries.

关 键 词:镍铁金属间化合物  氢气诱发  环境氢脆  硼掺杂
收稿时间:2006-10-24
修稿时间:2006-11-09

Influence of boron-doping on the H2-induced environmental embrittlement of Ni3Fe intermetallics
SHI Dan-dan,CHEN Ye-xin,WAN Xiao-jing,LIU Chain Tsuan.Influence of boron-doping on the H2-induced environmental embrittlement of Ni3Fe intermetallics[J].Journal of Shanghai University(English Edition),2007,11(2):102-105.
Authors:SHI Dan-dan  CHEN Ye-xin  WAN Xiao-jing  LIU Chain Tsuan
Institution:1. Institute of Materials Science, Shanghai University, Shanghai 200072, P. R. China
2. Department of Materials Science and Engineering, University of Tennessee, TN37996-2200, USA
Abstract:In this paper the tensile properties of both ordered and disordered Ni-24Fe and Ni-24Fe-0.03%B (wt%) alloys in gaseous hydrogen was investigated. The result shows that the ductility of the disordered Ni3Fe is significantly larger than that of ordered material in gaseous hydrogen. However, the ductility of ordered Ni3Fe doped with 0.03%B is nearly the same as that of disordered one indicating the obvious suppressing effect of boron on the H2-induced embrittlement. Based on the segregation behavior of boron in Ni3Al, it is proposed that the suppressing effect of boron in Ni3Fe on the H2-induced embrittlement is attributed to the segregation of boron on grain boundaries, thereby reducing the hydrogen diffusivity along the grain boundaries. Project supported by the National Natural Science Foundation of China (Grant Nos. 50371050, 50671057)
Keywords:hydrogen embrittlement  Ni3Fe alloy  boron addition
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