| ESR法表征12-钼磷酸对苯乙烯自由基聚合反应的阻聚作用 |
| |
| 引用本文： | 陈奠宇,宋静辉.ESR法表征12-钼磷酸对苯乙烯自由基聚合反应的阻聚作用[J].常熟理工学院学报,2004,18(2):27-28,33. |
| |
| 作者姓名： | 陈奠宇 宋静辉 |
| |
| 作者单位： | 常熟高等专科学校化学系,江苏,常熟,215500;无锡职业技术学院基础部,江苏,无锡,214000 |
| |
| 摘 要： | 通过使用电子顺磁共振仪(ESR)对苯乙烯自由基聚合体系中自由基的跟踪测试,进一步证实12-钼磷酸确实能够在自由基聚合体系中起到阻聚剂的作用,而且更加明确地提出其阻聚机理:通过捕获体系中的电子达到抑制自由基聚合反应的发生.
|
| 关 键 词： | 12-钼磷酸 苯乙烯 聚合 |
| 文章编号： | 1008-2794(2004)02-0027-02 |
| 修稿时间： | 2003年11月4日 |
ESR Method for Characterizing Inhibition role of 12 - Molybdophosphoric Acid in Styrene Radical Polymerization |
| |
| CHEN Dian-yu,SONG Jing-hui.ESR Method for Characterizing Inhibition role of 12 - Molybdophosphoric Acid in Styrene Radical Polymerization[J].Journal of Changshu Institute of Technology,2004,18(2):27-28,33. |
| |
| Authors: | CHEN Dian-yu SONG Jing-hui |
| |
| Institution: | CHEN Dian-yu~1,SONG Jing-hui~2 |
| |
| Abstract: | ESR method was employed in this paper to characterize the inhibition role of 12-Molybdophosphoric acid in styrene radical polymerization. The results shown that 12-molybdophosphoric acid did play inhibition in radical reactions, and the mechanism was conformed as electron capture theory. |
| |
| Keywords: | 12-molybdophosphoric acid styrene polymerization |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
