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生物乙醇重整制氢技术挑战与产业化发展机遇
引用本文:韩雪,贺泓,岳国君,林海龙,刘劲松,于斌.生物乙醇重整制氢技术挑战与产业化发展机遇[J].中国科学院院刊,2023,38(1):134-144.
作者姓名:韩雪  贺泓  岳国君  林海龙  刘劲松  于斌
作者单位:中国科学院生态环境研究中心 北京 100085;有研工程技术研究院有限公司 北京 101407;国投生物科技投资有限公司 北京 100034
基金项目:中国工程院战略研究与咨询项目(2022-XY-15),中国科学院生态环境研究中心“碳达峰碳中和生态环境技术专项”(RCEES-TDZ-2021-6)
摘    要:生物乙醇重整制氢是氢能绿色供应的重要途径,其采用可再生能源为原料,运用成熟、高效的化工工艺,积极助力碳达峰、碳中和目标的实现。生物乙醇是已被广泛应用的化石燃料替代品,随着纤维素乙醇技术不断进步,生物乙醇生产不再受限于淀粉基原料。目前,生物乙醇重整能够以制氢和生物乙醇已有的产业化成果为基础,实现与现有氢能产业的快速链接。然而,乙醇中碳碳单键的存在对制氢催化剂开发提出了新的挑战。同时,钯膜反应器生产水平的显著提高又为制氢设备小型化和在线应用创造了机遇。未来,生物乙醇可通过加油站供应,氢气随产随用能够避免储运的安全隐患,生物乙醇重整燃料电池车有望在产业化的过程中实现对燃油车的无缝替代,具有广阔的市场前景和重大的战略意义。

关 键 词:生物乙醇重整  燃料电池车  在线制氢  产业化  机遇与挑战
收稿时间:2022/10/17 0:00:00

Development Opportunities and Technical Challenges of Industrialization for Hydrogen Production from Bio-ethanol Reforming
HAN Xue,HE Hong,YUE Guojun,LIN Hailong,LIU Jinsong,YU bin.Development Opportunities and Technical Challenges of Industrialization for Hydrogen Production from Bio-ethanol Reforming[J].Bulletin of the Chinese Academy of Sciences,2023,38(1):134-144.
Authors:HAN Xue  HE Hong  YUE Guojun  LIN Hailong  LIU Jinsong  YU bin
Institution:Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China;GRIMAT Engineering Institute Co. Ltd., Beijing 101407, China;SDIC Biotech Investment Co. Ltd., Beijing 100034, China
Abstract:Bio-ethanol reforming for hydrogen production, using renewable raw materials and adopting mature and efficient chemical processes, is an important source of green hydrogen supply to achieve the goals of carbon peaking and carbon neutrality. Bio-ethanol is a widely used substitute for fossil fuels. With the continuous progress of cellulosic ethanol technology in recent years, bio-ethanol will gradually break through the constraints of starch-based raw material supply. Based on the industrialization achievements of hydrogen production and bio-ethanol, bio-ethanol reforming can realize a rapid linkage with the existing hydrogen energy industry. However, the existence of a carbon-carbon signal bond in ethanol poses new challenges to the development of hydrogen production catalysts, and production technology for the palladium membrane reactor has been significantly improved, creating an opportunity for the miniaturization of equipment and on-line application of bio-ethanol reforming. Bio-ethanol can be supplied through gas stations, and online hydrogen production can avoid the potential safety hazards of hydrogen storage and transportation. Bio-ethanol reforming for online hydrogen production is expected to achieve a seamless replacement of fuel vehicles in the process of industrialization, which has broad market prospects and great strategic significance.
Keywords:bio-ethanol reforming  fuel cell vehicle  on-board hydrogen production  industrialization  opportunities and challenges
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