| 制备双羟基四配位硅化合物的动力学探讨 |
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| 引用本文： | 王小芳,宋建华.制备双羟基四配位硅化合物的动力学探讨[J].天水师范学院学报,2003,23(5):26-28. |
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| 作者姓名： | 王小芳 宋建华 |
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| 作者单位： | 1. 天水师范学院,化学系,甘肃,天水,741001
2. 广州大学,化学系,广东,广州,510405 |
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| 摘 要： | 高反应活性的五配位硅钾化合物与2-氯乙醇反应制备双羟基四配位硅化合物及动力学行为，如温度、不同反应物摩尔比、催化剂等因数对该反应平衡常数和速率常数有影响，并选择出该反应的最佳合成条件。
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| 关 键 词： | 配位硅 合成 化学动力学 |
| 文章编号： | 1371-1351(2003)05-0026-03 |
| 修稿时间： | 2003年5月18日 |
The Chemical Kinetics Study of Synthesizing Di-hydroxyl Tetracoordinated Silicon |
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| Wang Xiao-fang,Song Jian-hua.The Chemical Kinetics Study of Synthesizing Di-hydroxyl Tetracoordinated Silicon[J].Journal of Tianshui Normal University,2003,23(5):26-28. |
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| Authors: | Wang Xiao-fang Song Jian-hua |
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| Institution: | Wang Xiao-fang1,Song Jian-hua2 |
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| Abstract: | The chemical kinetics of synthesizing dihydroxyl tetracoordinated silicon was studied, which was prepared by the reaction of a high reactive pentacoordinated silicon with ClCH2CH2OH,the influence of reaction condition including(temperature, concentration, solvents, PH, catalyst)was investigated. The reasonable route and mechanism for the preparation of dihydroxyl tetracoordinated silicon was put forward. |
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| Keywords: | Pentacoodinated oraganic silicon Compose Chemical kinetics |
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