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Gold coated optical fibers as three-dimensional electrodes for microfluidic enzymatic biofuel cells: Toward geometrically enhanced performance
Authors:Denis Desma?le  Louis Renaud  Sophie Tingry
Institution:1Institut Européen des Membranes, UMR 5635, ENSCM-UMII-CNRS, place Eugène Bataillon, 34095 Montpellier, France;2Université de Lyon, Institut des Nanotechnologies de Lyon INL-UMR5270, CNRS, Université Lyon 1, Villeurbanne F-69622, France
Abstract:For the first time, we report on the preliminary evaluation of gold coated optical fibers (GCOFs) as three-dimensional (3D) electrodes for a membraneless glucose/O2 enzymatic biofuel cell. Two off-the-shelf 125 μm diameter GCOFs were integrated into a 3D microfluidic chip fabricated via rapid prototyping. Using soluble enzymes and a 10 mM glucose solution flowing at an average velocity of 16 mm s−1 along 3 mm long GCOFs, the maximum power density reached 30.0 ± 0.1 μW cm−2 at a current density of 160.6 ± 0.3 μA cm−2. Bundles composed of multiple GCOFs could further enhance these first results while serving as substrates for enzyme immobilization.
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